Acrylic Acid

Synonyms: 2-Propenoic acid, Prop-2-enoic acid

SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name Acrylic Acid
Product Form Substance
Catalogue No. AL0110
CAS Number 79-10-7
EC Number 201-177-9
EC Index Number 607-042-00-9
Grade 99% For Synthesis
HSN Code 29161100
Molecular Formula C3H4O2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name Acrylic Acid
Catalogue No. AL0110
Product form Substance
CAS Number 79-10-7
EC Number 201-177-9
Grade 99% For Synthesis
EC Index Number 607-042-00-9
Chemical Formula C3H4O2
HSN Code 29161100
Synonyms 2-Propenoic acid, Prop-2-enoic acid
Chemical Structure -
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture Monomer for the production of polyacrylates and superabsorbent polymers.
Uses advised against Not specified
1.3 Details of the supplier of the safety data sheet
Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 Flam. Liq. 3; Acute Tox. 4; Skin Corr. 1A; STOT SE 3; Aquatic Acute 1
Classification source ECHA C&L Inventory via PubChem CID 6581 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms Flammable, Corrosive, Irritant, Environmental Hazard
Signal word Danger
Hazard statements H226: Flammable liquid and vapor; H302: Harmful if swallowed; H312: Harmful in contact with skin; H314: Causes severe skin burns and eye damage; H332: Harmful if inhaled; H335: May cause respiratory irritation; H400: Very toxic to aquatic life
2.3 Other hazards
Other hazards Corrosive to metals; may cause skin and eye irritation.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name Acrylic Acid
CAS No. 79-10-7
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact If this chemical contacts the skin, immediately flush the contaminated skin with water. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water. Get medical attention promptly.
First-aid measures after eye contact If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion If this chemical has been swallowed, get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use Irritation of the respiratory tract, skin, and eyes; potential for burns on contact.
4.3 Indication of any immediate medical attention and special treatment needed
General information Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures Flash back possible over considerable distance.
5.3 Advice for firefighters
Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures Evacuate area. Contain spill and absorb with inert material. Dispose of in accordance with local regulations.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers.
6.4 Reference to other sections
Reference Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling Use in a fume hood. Wear appropriate personal protective equipment (PPE). Avoid contact with skin and eyes.
Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions Fireproof. Separated from strong oxidants, strong bases, strong acids and food and feedstuffs. Keep in the dark. Store only if stabilized. Store in an area without drain or sewer access. Storage conditions may vary according to the type of inhibitor used. Refer to the manufacturer's instructions for proper storage conditions.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection Protective gloves (e.g. nitrile rubber)
Eye protection Chemical safety goggles or safety glasses
Skin and body protection Wear suitable protective clothing
Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state Liquid
Colour Colorless
Odour Acrid odor and fumes
Odour threshold Not specified
pH value Not specified
Relative evaporation rate (butylacetate=1) Not specified
Melting point 13.56 °C
Freezing point Not specified
Boiling point 142 °C
Flash point 54 °C (open cup)
Auto-ignition temperature 438 °C; 820 °F
Decomposition temperature Not specified
Flammability (solid, gas) Flammable liquid
Vapour pressure 3.97 mm Hg at 25 °C
Relative vapour density at 20°C 2.5 (Air = 1)
Density 1.0511 g/cu cm at 20 °C
Solubility Miscible with alcohol, and ether
Log Pow 0.35
Viscosity, kinematic Not specified
Viscosity, dynamic Not specified
Explosive properties Not explosive
Oxidising properties Not oxidizing
Explosive limits Lower: 2.1% vol, Upper: 12.5% vol
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity Reacts violently with strong oxidizers and bases; polymerizes readily.
10.2 Chemical stability
Chemical stability Stable under recommended storage conditions. Contains the following stabilizer(s): Mequinol (>=0.018 - <=0.02%).
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions The substance readily polymerizes due to heating, under the influence of light, oxygen, oxidizing agents such as peroxides or other activators (acid, iron salts). This generates fire or explosion hazard. Decomposes on heating.
10.4 Conditions to avoid
Conditions to avoid Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials Strong oxidizers, strong bases, amines, and alcohols.
10.6 Hazardous decomposition products
Hazardous decomposition products Not specified
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity LD50 Rat oral 193 mg/kg; LD50 Rat oral 340 mg/kg; LD50 Rat oral 1500 mg/kg
Skin corrosion/irritation H314: Causes severe skin burns and eye damage
Serious eye damage/irritation Not classified (based on available data)
Respiratory or skin sensitisation Not classified (based on available data)
Germ cell mutagenicity Not classified (based on available data)
Carcinogenicity Not classified (based on available data)
Specific target organ toxicity (single exposure) H335: May cause respiratory irritation
Specific target organ toxicity (repeated exposure) Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information Not specified
12.2 Persistence - degradability
Persistence - degradability Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential Not specified
12.4 Mobility in soil
Mobility in soil Not specified
12.6 Other adverse effects
Environmental precautions Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR) UN 2218
UN-No. (IMDG) UN 2218
UN-No. (IATA) UN 2218
UN-No. (ADN) UN 2218
UN-No. (RID) UN 2218
14.2 UN proper shipping name
Proper Shipping Name (ADR) Acrylic Acid
Proper Shipping Name (IMDG) Acrylic Acid
Proper Shipping Name (IATA) Acrylic Acid
Proper Shipping Name (ADN) Acrylic Acid
Proper Shipping Name (RID) Acrylic Acid
14.3 Transport hazard class(es)
Transport hazard class(es) 8 (3)
14.4 Packing group
Packing group (ADR) II
Packing group (IMDG) II
Packing group (IATA) II
Packing group (ADN) II
Packing group (RID) II
14.5 Environmental hazards
Dangerous for the environment Not specified
Marine pollutant Not specified
Other information No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations Not specified
SECTION 16: Other Information
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.