Allylamine
Synonyms: 2-Propen-1-amine
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Allylamine
Product Form
Substance
Catalogue No.
AL0173
CAS Number
107-11-9
EC Number
203-463-9
EC Index Number
612-005-00-5
Grade
99% For Synthesis
HSN Code
29211990
Molecular Formula
C3H7N
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Allylamine
Catalogue No.
AL0173
Product form
Substance
CAS Number
107-11-9
EC Number
203-463-9
Grade
99% For Synthesis
EC Index Number
612-005-00-5
Chemical Formula
C3H7N
HSN Code
29211990
Synonyms
2-Propen-1-amine
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used in the synthesis of specialty polymers and pharmaceuticals.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flam. Liq. 2; Acute Tox. 3; Acute Tox. 1; Skin Corr. 1A; Eye Dam. 1; Acute Tox. 2; Aquatic Chronic 2
Classification source
ECHA C&L Inventory via PubChem CID 7853 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Flammable, Corrosive, Acute Toxic, Environmental Hazard
Signal word
Danger
Hazard statements
H225: Highly Flammable liquid and vapor; H301: Toxic if swallowed; H310: Fatal in contact with skin; H314: Causes severe skin burns and eye damage; H318: Causes serious eye damage; H330: Fatal if inhaled; H411: Toxic to aquatic life with long lasting effects
2.3 Other hazards
Other hazards
Highly toxic and corrosive; may cause severe burns.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Allylamine
CAS No.
107-11-9
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If breathing is difficult, give oxygen. Seek medical attention immediately.
First-aid measures after skin contact
Remove contaminated clothing and wash skin thoroughly with soap and water. Seek medical attention if irritation persists.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Symptoms of exposure may include respiratory distress, skin burns, and eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Vapor/air mixtures are explosive.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and ventilate. Wear appropriate protective equipment. Contain and absorb spill with inert material.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Remove all ignition sources. Evacuate danger area! Consult an expert! Personal protection: gas-tight chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use in a fume hood with appropriate PPE including gloves and goggles. Avoid contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Provision to contain effluent from fire extinguishing. Fireproof. Separated from strong oxidants, strong acids and food and feedstuffs. Well closed. Store in an area without drain or sewer access.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Handle with gloves.
Eye protection
Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless
Odour
Strong ammonia odor causing sneezing and tears
Odour threshold
Not specified
pH value
Not specified
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
-88.2 °C
Freezing point
Not specified
Boiling point
53.5 °C
Flash point
-29 °C (-20 °F) - closed cup
Auto-ignition temperature
705 °F (374 °C)
Decomposition temperature
Not specified
Flammability (solid, gas)
Flammable liquid
Vapour pressure
242 mm Hg at 25 °C
Relative vapour density at 20°C
2.0 (Air = 1)
Density
0.760 at 20 °C/20 °C
Solubility
In water, 1X10+6 mgL at 20 °C miscible/
Log Pow
0.03
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Reacts with strong oxidizing agents and acids.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Decomposes on burning. This produces toxic fumes including nitrogen oxides. The solution in water is a medium strong base.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, acids, and bases.
10.6 Hazardous decomposition products
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions - Carbon oxides, nitrogen oxides (NOx).
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 102 mg/kg; LD50 Rat oral 106 mg/kg; LC50 Rat inhalation 286 ppm/4 hr
Skin corrosion/irritation
H314: Causes severe skin burns and eye damage
Serious eye damage/irritation
H318: Causes serious eye damage
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
2334
UN-No. (IMDG)
2334
UN-No. (IATA)
2334
UN-No. (ADN)
2334
UN-No. (RID)
2334
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Allylamine
Proper Shipping Name (IMDG)
Allylamine
Proper Shipping Name (IATA)
Allylamine
Proper Shipping Name (ADN)
Allylamine
Proper Shipping Name (RID)
Allylamine
14.3 Transport hazard class(es)
Transport hazard class(es)
6.1
14.4 Packing group
Packing group (ADR)
I
Packing group (IMDG)
I
Packing group (IATA)
I
Packing group (ADN)
I
Packing group (RID)
I
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.