Safety Data Sheet - Allyl chloride

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Allyl chloride

Product Form Substance

Catalogue No. AL0176

CAS Number 107-05-1

EC Number 203-457-6

EC Index Number 603-007-00-4

Grade 98% For Synthesis

HSN Code 29032900

Molecular Formula C3H5Cl

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Allyl chloride

Catalogue No. AL0176

Product form Substance

CAS Number 107-05-1

EC Number 203-457-6

Grade 98% For Synthesis

EC Index Number 603-007-00-4

Chemical Formula C3H5Cl

HSN Code 29032900

Synonyms 3-Chloropropene

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Used as an allylating agent in organic synthesis and as an intermediate in the production of epichlorohydrin.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Flam. Liq. 2; Acute Tox. 3; Skin Irrit. 2; Eye Dam. 1; STOT SE 3; Muta. 2; Carc. 2; STOT RE 2; Aquatic Acute 1

Classification source ECHA C&L Inventory via PubChem CID 7850 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Flammable, Corrosive, Acute Toxic, Health Hazard

Signal word Danger

Hazard statements H225: Highly Flammable liquid and vapor; H301+H311+H331: Toxic if swallowed, in contact with skin or if inhaled; H301: Toxic if swallowed; H311: Toxic in contact with skin; H315: Causes skin irritation; H318: Causes serious eye damage; H331: Toxic if inhaled; H335: May cause respiratory irritation; H341: Suspected of causing genetic defects; H351: Suspected of causing cancer; H373: May causes damage to organs through prolonged or repeated exposure

2.3 Other hazards

Other hazards Highly flammable; may cause respiratory irritation.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Allyl chloride

CAS No. 107-05-1

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.

First-aid measures after eye contact If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion If this chemical has been swallowed, get medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Irritation of the respiratory tract, skin, and eyes; headache; dizziness; nausea.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Vapor is heavier than air (vapor-air density at 100 °F, 2.2) and may travel considerable distance to source of ignition and flash back.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area. Ventilate. Use appropriate protective equipment. Prevent entry into waterways.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Use in a fume hood. Wear appropriate personal protective equipment (PPE). Avoid contact with skin and eyes.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Fireproof. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Dry.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection (1 ppm to 2% for 0.5 hr or less) full face mask and canister; (greater concentrations) self-contained breathing apparatus or its equivalent. Rubber or neoprene gloves, apron, boots; clean body-covering clothes; chemical goggles, gas-tight goggles, or equivalent; full face shield.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless to pale yellow

Odour Pungent, unpleasant odor.

Odour threshold Not specified

pH value Not applicable

Relative evaporation rate (butylacetate=1) Not specified

Melting point -134.5 °C

Freezing point Not specified

Boiling point 44-45 °C

Flash point -32 °C

Auto-ignition temperature Ignition temp, 737 °F (392 °C)

Decomposition temperature Not specified

Flammability (solid, gas) Highly flammable liquid and vapor

Vapour pressure 368 mm Hg at 25 °C

Relative vapour density at 20°C 2.64 (Air= 1)

Density 0.938 at 20 °C/4 °C

Solubility Miscible with alcohol, chloroform, ether, petrol ether

Log Pow 2.1

Viscosity, kinematic Not specified

Viscosity, dynamic Not specified

Explosive properties Not specified

Oxidising properties Not specified

Explosive limits Not specified

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Reacts with strong oxidizing agents and bases.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions The substance polymerizes under the influence of acids, heat and peroxides. This generates fire or explosion hazard. On combustion, forms toxic and corrosive fumes of hydrogen chloride (see ICSC 0163).

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizers, strong bases, and amines.

10.6 Hazardous decomposition products

Hazardous decomposition products Not specified

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rabbit dermal 2066 mg/kg; LD50 Dog iv 7.15 mg/kg; LD50 Mouse ip 155 mg/kg

Skin corrosion/irritation H315: Causes skin irritation

Serious eye damage/irritation H318: Causes serious eye damage

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity H341: Suspected of causing genetic defects

Carcinogenicity H351: Suspected of causing cancer

Specific target organ toxicity (single exposure) H335: May cause respiratory irritation

Specific target organ toxicity (repeated exposure) H373: May causes damage to organs through prolonged or repeated exposure

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 1100

UN-No. (IMDG) UN 1100

UN-No. (IATA) UN 1100

UN-No. (ADN) UN 1100

UN-No. (RID) UN 1100

14.2 UN proper shipping name

Proper Shipping Name (ADR) Allyl chloride

Proper Shipping Name (IMDG) Allyl chloride

Proper Shipping Name (IATA) Allyl chloride

Proper Shipping Name (ADN) Allyl chloride

Proper Shipping Name (RID) Allyl chloride

14.3 Transport hazard class(es)

Transport hazard class(es) 3 (6.1)

14.4 Packing group

Packing group (ADR) I

Packing group (IMDG) I

Packing group (IATA) I

Packing group (ADN) I

Packing group (RID) I

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.