Safety Data Sheet

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Aniline

Product Form Substance

Catalogue No. AL0433

CAS Number 62-53-3

EC Number 200-539-3

EC Index Number 612-005-00-5

Grade 99% For Synthesis

HSN Code 29214110

Molecular Formula C6H5NH2

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Aniline

Catalogue No. AL0433

Product form Substance

CAS Number 62-53-3

EC Number 200-539-3

Grade 99% For Synthesis

EC Index Number 612-005-00-5

Chemical Formula C6H5NH2

HSN Code 29214110

Synonyms Phenylamine, Aminobenzene

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Intermediate in the synthesis of dyes, pharmaceuticals, and other chemicals.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Acute Tox. 3; Skin Sens. 1; Eye Dam. 1; Muta. 2; Carc. 2; STOT RE 1; Aquatic Acute 1

Classification source ECHA C&L Inventory via PubChem CID 6115 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Corrosive, Acute Toxic, Health Hazard, Environmental Hazard

Signal word Danger

Hazard statements H301: Toxic if swallowed; H311: Toxic in contact with skin; H317: May cause an allergic skin reaction; H318: Causes serious eye damage; H331: Toxic if inhaled; H341: Suspected of causing genetic defects; H351: Suspected of causing cancer; H372: Causes damage to organs through prolonged or repeated exposure; H400: Very toxic to aquatic life

2.3 Other hazards

Other hazards May cause respiratory irritation; harmful to aquatic life with long lasting effects.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Aniline

CAS No. 62-53-3

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing, promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.

First-aid measures after eye contact If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion If this chemical has been swallowed, get medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Headache, dizziness, nausea, skin irritation, respiratory distress.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Vapors are heavier than air and will collect in low areas. Vapors may travel long distances to ignition sources and flashback.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area. Ventilate. Contain spill and absorb with inert material.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Evacuate danger area! Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Use in a fume hood. Wear appropriate personal protective equipment (PPE).

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Separated from strong oxidants, strong acids and food and feedstuffs. Well closed. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Handle with gloves.

Eye protection Tightly fitting safety goggles. Faceshield (8-inch minimum).

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless to pale yellow

Odour Hedonic tone; pungent

Odour threshold Not available

pH value Not applicable

Relative evaporation rate (butylacetate=1) Not available

Melting point -6.0 °C

Freezing point -6 °C

Boiling point 184.1 °C

Flash point 70 °C (158 °F) - closed cup

Auto-ignition temperature 1139 °F (615 °C)

Decomposition temperature Not available

Flammability (solid, gas) Not applicable

Vapour pressure 6.67X10-1 mm Hg at 25 °C

Relative vapour density at 20°C 3.3 (Air = 1)

Density 1.0217 at 20 °C/20 °C

Solubility In water, 36,000 mg/L at 25 °C

Log Pow 0.90

Viscosity, kinematic Not available

Viscosity, dynamic 0.89 mPa·s at 20 °C

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits 1.2 - 7.0 vol% in air

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions. Reacts with strong oxidizing agents.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes above 190 °C . This produces toxic and corrosive fumes of nitrogen oxides and ammonia and flammable vapours. Reacts with strong acids and strong oxidants. This generates fire and explosion hazard.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizers, strong acids, and bases.

10.6 Hazardous decomposition products

Hazardous decomposition products Hazardous decomposition products formed under fire conditions - Carbon oxides, nitrogen oxides (NOx).

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 250 mg/kg; LD50 Rat dermal 1400 mg/kg; LD50 Rat ip 420 mg/kg

Skin corrosion/irritation Not classified (based on available data)

Serious eye damage/irritation H318: Causes serious eye damage

Respiratory or skin sensitisation H317: May cause an allergic skin reaction

Germ cell mutagenicity H341: Suspected of causing genetic defects

Carcinogenicity H351: Suspected of causing cancer

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) H372: Causes damage to organs through prolonged or repeated exposure

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 1547

UN-No. (IMDG) UN 1547

UN-No. (IATA) UN 1547

UN-No. (ADN) UN 1547

UN-No. (RID) UN 1547

14.2 UN proper shipping name

Proper Shipping Name (ADR) Aniline

Proper Shipping Name (IMDG) Aniline

Proper Shipping Name (IATA) Aniline

Proper Shipping Name (ADN) Aniline

Proper Shipping Name (RID) Aniline

14.3 Transport hazard class(es)

Transport hazard class(es) 6.1

14.4 Packing group

Packing group (ADR) II

Packing group (IMDG) II

Packing group (IATA) II

Packing group (ADN) II

Packing group (RID) II

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.