Safety Data Sheet - Antimony(III) chloride

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Antimony(III) chloride

Product Form Substance

Catalogue No. AL0468

CAS Number 10025-91-9

EC Number 233-047-2

EC Index Number 051-002-00-3

Grade 98.5%

HSN Code 28273990

Molecular Formula SbCl3

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Antimony(III) chloride

Catalogue No. AL0468

Product form Substance

CAS Number 10025-91-9

EC Number 233-047-2

Grade 98.5%

EC Index Number 051-002-00-3

Chemical Formula SbCl3

HSN Code 28273990

Synonyms Antimony trichloride, Stibine chloride

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Catalyst, mordant, and chemical intermediate

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Skin Corr. 1B; Aquatic Chronic 2

Classification source ECHA C&L Inventory via PubChem CID 24814 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Corrosive, Environmental Hazard

Signal word Danger

Hazard statements H314: Causes severe skin burns and eye damage; H411: Toxic to aquatic life with long lasting effects

2.3 Other hazards

Other hazards Corrosive to metals; may cause respiratory irritation.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Antimony(III) chloride

CAS No. 10025-91-9

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move victim at once to fresh air and keep him warm, but not hot; call a physician immediately; nasal passages may be irrigated from a gently flowing hose.

First-aid measures after skin contact Flush with large quantities of flowing water followed by washing of skin surfaces with soap and water; remove all contaminated clothing promptly.

First-aid measures after eye contact Flush with copious amounts of water for at least 15 min.; call a physician at once.

First-aid measures after ingestion Induce vomiting by giving large quantities of warm salt water; have a physician see the patient at once.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Corrosive effects on skin and eyes; respiratory irritation; nausea if ingested.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Advice for firefighters: Wear self-contained breathing apparatus for firefighting if necessary.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures May emit toxic fumes of antimony and chlorine when heated.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and ventilate. Wear appropriate protective equipment.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Sweep spilled substance into covered sealable containers. Carefully collect remainder.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Handle in a fume hood. Wear gloves and eye protection. Avoid contact with skin and eyes.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Separated from food and feedstuffs. Dry. Well closed.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Handle with gloves.

Eye protection Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Solid

Colour White to pale yellow

Odour Acrid pugent odor

Odour threshold Not applicable

pH value Not applicable

Relative evaporation rate (butylacetate=1) Not applicable

Melting point 73.4 °C

Freezing point Not applicable

Boiling point 220.3 °C

Flash point Not applicable

Auto-ignition temperature Not applicable

Decomposition temperature > 130 °C

Flammability (solid, gas) Not flammable

Vapour pressure 1 mm Hg at 49.2 °C (sublimes)

Relative vapour density at 20°C Not applicable

Density 3.14 g/cu cm

Solubility In water, 987 g/100 g water at 25 °C

Log Pow Not applicable

Viscosity, kinematic Not applicable

Viscosity, dynamic Not applicable

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits Not applicable

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Reacts with water to produce hydrochloric acid and antimony oxide.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on heating. This produces toxic fumes including chlorine and antimony oxides. Reacts with water.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong bases, strong oxidizing agents, and moisture.

10.6 Hazardous decomposition products

Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Hydrogen chloride gas, Antimony oxide.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 525 mg/kg; LD50 Guinea pigs oral 574 mg/kg; LD50 Mice ip 13 mg/kg

Skin corrosion/irritation H314: Causes severe skin burns and eye damage

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 1733

UN-No. (IMDG) UN 1733

UN-No. (IATA) UN 1733

UN-No. (ADN) UN 1733

UN-No. (RID) UN 1733

14.2 UN proper shipping name

Proper Shipping Name (ADR) Antimony(III) chloride

Proper Shipping Name (IMDG) Antimony(III) chloride

Proper Shipping Name (IATA) Antimony(III) chloride

Proper Shipping Name (ADN) Antimony(III) chloride

Proper Shipping Name (RID) Antimony(III) chloride

14.3 Transport hazard class(es)

Transport hazard class(es) 8

14.4 Packing group

Packing group (ADR) II

Packing group (IMDG) II

Packing group (IATA) II

Packing group (ADN) II

Packing group (RID) II

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.