Safety Data Sheet - Benzaldehyde

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Benzaldehyde

Product Form Substance

Catalogue No. AL0597

CAS Number 100-52-7

EC Number 202-860-4

EC Index Number 605-006-00-4

Grade AR

HSN Code 29122100

Molecular Formula C6H5CHO

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Benzaldehyde

Catalogue No. AL0597

Product form Substance

CAS Number 100-52-7

EC Number 202-860-4

Grade AR

EC Index Number 605-006-00-4

Chemical Formula C6H5CHO

HSN Code 29122100

Synonyms Benzenecarbaldehyde, Phenylaldehyde

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Used in organic synthesis and as a solvent in laboratories.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Acute Tox. 4

Classification source ECHA C&L Inventory via PubChem CID 240 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Irritant

Signal word Warning

Hazard statements H302: Harmful if swallowed

2.3 Other hazards

Other hazards None identified beyond standard handling precautions.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Benzaldehyde

CAS No. 100-52-7

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If symptoms persist, seek medical attention.

First-aid measures after skin contact IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.

First-aid measures after eye contact First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.

First-aid measures after ingestion Rinse mouth. Do not induce vomiting. Seek medical attention if symptoms occur.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Mild irritation to skin, eyes, and respiratory tract.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Under fire conditions, material may decompose to form flammable and/or explosive mixtures in air. Use water spray to cool unopened containers.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and ventilate. Contain spill and absorb with inert material.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Avoid contact with skin and eyes. Use in a well-ventilated area.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Separated from incompatible materials. See Chemical Dangers. Well closed. Ventilation along the floor. Cool. Store in an area without drain or sewer access. Keep in the dark.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Handle with gloves.

Eye protection Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless to pale yellow

Odour Characteristic odor or volatile oil of almond

Odour threshold 0.05 ppm

pH value Not applicable

Relative evaporation rate (butylacetate=1) 0.5

Melting point -57.12 °C

Freezing point Not applicable

Boiling point 178.7 °C

Flash point 145 °F, 63 °C (Closed cup)

Auto-ignition temperature 377 °F, 192 °C

Decomposition temperature Not available

Flammability (solid, gas) Not flammable

Vapour pressure 1.27 mm Hg at 25 °C

Relative vapour density at 20°C 3.66 (Air = 1)

Density 1.050 at 15 °C/4 °C

Solubility In water, 6950 mg/L at 25 °C

Log Pow 1.48

Viscosity, kinematic Not available

Viscosity, dynamic Not available

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits Not applicable

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions. Reacts with strong oxidizing agents.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions The substance can form explosive peroxides under special conditions. Reacts violently with aluminium, bases, iron, oxidants and phenol. This generates fire and explosion hazard.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizing agents, strong bases.

10.6 Hazardous decomposition products

Hazardous decomposition products Not specified

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 1300 mg/kg; LD50 Guinea pig oral 1000 mg/kg; LD50 Rabbit dermal >1250 mg/kg

Skin corrosion/irritation Not classified (based on available data)

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) 1990

UN-No. (IMDG) 1990

UN-No. (IATA) 1990

UN-No. (ADN) 1990

UN-No. (RID) 1990

14.2 UN proper shipping name

Proper Shipping Name (ADR) Benzaldehyde

Proper Shipping Name (IMDG) Benzaldehyde

Proper Shipping Name (IATA) Benzaldehyde

Proper Shipping Name (ADN) Benzaldehyde

Proper Shipping Name (RID) Benzaldehyde

14.3 Transport hazard class(es)

Transport hazard class(es) 9

14.4 Packing group

Packing group (ADR) III

Packing group (IMDG) III

Packing group (IATA) III

Packing group (ADN) III

Packing group (RID) III

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.