Benzoic Acid
Synonyms: Carboxybenzene, Benzenecarboxylic acid
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Benzoic Acid
Product Form
Substance
Catalogue No.
AL0621
CAS Number
65-85-0
EC Number
200-618-2
EC Index Number
607-004-00-4
Grade
AR
HSN Code
29163110
Molecular Formula
C7H6O2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Benzoic Acid
Catalogue No.
AL0621
Product form
Substance
CAS Number
65-85-0
EC Number
200-618-2
Grade
AR
EC Index Number
607-004-00-4
Chemical Formula
C7H6O2
HSN Code
29163110
Synonyms
Carboxybenzene, Benzenecarboxylic acid
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used in analytical chemistry and as a preservative.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Skin Irrit. 2; Eye Dam. 1
Classification source
ECHA C&L Inventory via PubChem CID 243 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Corrosive
Signal word
Danger
Hazard statements
H315: Causes skin irritation; H318: Causes serious eye damage
2.3 Other hazards
Other hazards
None identified.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Benzoic Acid
CAS No.
65-85-0
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.
First-aid measures after eye contact
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
First-aid measures after ingestion
Rinse mouth. Do not induce vomiting. Seek medical attention if symptoms occur.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Irritation of eyes, skin, and respiratory tract.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Dust explosion possible if in powder or granular form, mixed with air.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Contain spill and collect using appropriate methods. Dispose of in accordance with local regulations.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Personal protection: protective clothing and face shield. Do NOT let this chemical enter the environment. Sweep spilled substance into covered plastic containers. Carefully collect remainder in covered containers.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Avoid contact with skin and eyes. Use in a well-ventilated area.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Store only in original container. Separated from incompatible materials. See Chemical Dangers. Fireproof. Store in an area without drain or sewer access.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Solid
Colour
White
Odour
Odorless or with a slight benzaldehyde odor
Odour threshold
Not determined
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not determined
Melting point
122 °C
Freezing point
Not determined
Boiling point
249.2 °C at 760 mm Hg
Flash point
250 °F (121 °C) (closed cup)
Auto-ignition temperature
570 °C (1058 °F)
Decomposition temperature
Not determined
Flammability (solid, gas)
Flammable solid
Vapour pressure
7.0X10-4 mm Hg at 25 °C
Relative vapour density at 20°C
4.21 (Air = 1)
Density
1.2659 g/cu cm at 15 °C
Solubility
Slightly soluble in cold water, soluble in hot water, ethanol, and ether
Log Pow
1.87
Viscosity, kinematic
Not determined
Viscosity, dynamic
Not determined
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not determined
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions.
10.2 Chemical stability
Chemical stability
A 0.1% w/v aqueous solution of benzoic acid has been reported to be stable for at least 8 weeks when stored in polyvinyl chloride bottels, at room temperature.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
The solution in water is a weak acid. Reacts with strong oxidants, strong reducing agents and strong bases. This generates fire and explosion hazard.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizing agents, strong bases.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomp it emits acrid smoke and irritating fumes.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Cat oral 2000 mg/kg; LD50 Dog oral 2000 mg/kg; LD50 Mouse intraperitoneal 1460 mg/kg
Skin corrosion/irritation
H315: Causes skin irritation
Serious eye damage/irritation
H318: Causes serious eye damage
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
Not assigned
UN-No. (IMDG)
Not assigned
UN-No. (IATA)
Not assigned
UN-No. (ADN)
Not assigned
UN-No. (RID)
Not assigned
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Benzoic Acid
Proper Shipping Name (IMDG)
Benzoic Acid
Proper Shipping Name (IATA)
Benzoic Acid
Proper Shipping Name (ADN)
Benzoic Acid
Proper Shipping Name (RID)
Benzoic Acid
14.3 Transport hazard class(es)
Transport hazard class(es)
Not classified
14.4 Packing group
Packing group (ADR)
Not classified
Packing group (IMDG)
Not classified
Packing group (IATA)
Not classified
Packing group (ADN)
Not classified
Packing group (RID)
Not classified
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.