Benzoyl Peroxide
Synonyms: Benzoyl peroxide, Peroxybenzoic acid
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Benzoyl Peroxide
Product Form
Substance
Catalogue No.
AL0640
CAS Number
94-36-0
EC Number
202-327-6
EC Index Number
617-008-00-0
Grade
75%
HSN Code
29163200
Molecular Formula
C14H10O4
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Benzoyl Peroxide
Catalogue No.
AL0640
Product form
Substance
CAS Number
94-36-0
EC Number
202-327-6
Grade
75%
EC Index Number
617-008-00-0
Chemical Formula
C14H10O4
HSN Code
29163200
Synonyms
Benzoyl peroxide, Peroxybenzoic acid
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Radical initiator, acne treatment
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Org. Perox. B; Skin Sens. 1; Eye Irrit. 2; Aquatic Acute 1
Classification source
ECHA C&L Inventory via PubChem CID 7187 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Explosive, Flammable, Irritant, Environmental Hazard
Signal word
Danger
Hazard statements
H241: Heating may cause a fire or explosion; H317: May cause an allergic skin reaction; H319: Causes serious eye irritation; H400: Very toxic to aquatic life
2.3 Other hazards
Other hazards
Organic peroxide; may cause skin and eye irritation.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Benzoyl Peroxide
CAS No.
94-36-0
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact
If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing, promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Irritation of skin, eyes, and respiratory tract.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Vapors are heavier than air and will collect in low areas. Vapors may travel long distances to ignition sources and flashback.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area. Avoid dust formation. Use appropriate protective equipment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Evacuate danger area! Remove all ignition sources. Wash away remainder with plenty of water. Do NOT absorb in saw-dust or other combustible absorbents.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Avoid contact with skin and eyes. Use personal protective equipment as required.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Fireproof. Separated from combustible substances and reducing agents. Store only in original packaging. See Chemical Dangers.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Handle with gloves.
Eye protection
Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use in a well-ventilated area. If exposure limits are exceeded, use appropriate respiratory protection.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Solid
Colour
White
Odour
Faint, benzaldehyde-like odor.
Odour threshold
Not determined
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
104.5 °C
Freezing point
Not applicable
Boiling point
Not applicable
Flash point
80 °C
Auto-ignition temperature
80 °C
Decomposition temperature
> 100 °C
Flammability (solid, gas)
Not flammable under normal conditions
Vapour pressure
VP: < 0.1 torr at 20 °C
Relative vapour density at 20°C
Not applicable
Density
1.3340 at 25 °C
Solubility
In water, 9.10 mg/L at 25 °C
Log Pow
3.46
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive under normal conditions
Oxidising properties
Strong oxidizer
Explosive limits
Not applicable
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under recommended storage conditions; may decompose upon heating.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
May decompose explosively on shock, friction or concussion. May explode on heating above 103-105 °C. On combustion, forms irritating and toxic fumes and gases of benzoic acid (see ICSC 0103) and carbon monoxide (see ICSC 0023). The substance is a strong oxidant.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Reducing agents, strong acids, strong bases, and heat sources.
10.6 Hazardous decomposition products
Hazardous decomposition products
Explosive decomposition above the melting point (103 °C) forms flammable products.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 7710 mg/kg; LD50 Mouse oral 5700 mg/kg; LD50 Mouse ip 206-242 mg/kg body weight
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
H319: Causes serious eye irritation
Respiratory or skin sensitisation
H317: May cause an allergic skin reaction
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
3104
UN-No. (IMDG)
3104
UN-No. (IATA)
3104
UN-No. (ADN)
3104
UN-No. (RID)
3104
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Benzoyl peroxide, moist
Proper Shipping Name (IMDG)
Benzoyl peroxide, moist
Proper Shipping Name (IATA)
Benzoyl peroxide, moist
Proper Shipping Name (ADN)
Benzoyl peroxide, moist
Proper Shipping Name (RID)
Benzoyl peroxide, moist
14.3 Transport hazard class(es)
Transport hazard class(es)
5.2
14.4 Packing group
Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.