Safety Data Sheet - Benzyl bromide

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Benzyl bromide

Product Form Substance

Catalogue No. AL0652

CAS Number 100-39-0

EC Number 202-847-3

EC Index Number 603-004-00-6

Grade 98%

HSN Code 29039990

Molecular Formula C7H7Br

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Benzyl bromide

Catalogue No. AL0652

Product form Substance

CAS Number 100-39-0

EC Number 202-847-3

Grade 98%

EC Index Number 603-004-00-6

Chemical Formula C7H7Br

HSN Code 29039990

Synonyms Benzylbromid, Benzylbromide

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Benzylating agent in organic synthesis.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Skin Irrit. 2; Eye Irrit. 2; STOT SE 3

Classification source ECHA C&L Inventory via PubChem CID 7498 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Irritant

Signal word Warning

Hazard statements H315: Causes skin irritation; H319: Causes serious eye irritation; H335: May cause respiratory irritation

Precautionary statements P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, P501

2.3 Other hazards

Other hazards Lachrymator; may cause respiratory irritation.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Benzyl bromide

CAS No. 100-39-0

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If breathing is difficult, give oxygen. Seek medical attention.

First-aid measures after skin contact IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.

First-aid measures after eye contact First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.

First-aid measures after ingestion Do not induce vomiting. Rinse mouth. Seek medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Irritation of eyes, skin, and respiratory tract; may cause nausea and vomiting.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Toxic fumes may be released in a fire. Use water spray to cool containers.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area. Wear appropriate protective equipment. Contain spill and absorb with inert material.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Personal protection: chemical protection suit including self-contained breathing apparatus.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Use in a fume hood. Wear gloves and goggles. Avoid contact with skin and eyes.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Separated from strong oxidants, strong bases and food and feedstuffs. Dry. Well closed.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless to pale yellow

Odour Pungent

Odour threshold No data available

pH value No data available

Relative evaporation rate (butylacetate=1) No data available

Melting point -20 °C

Freezing point No data available

Boiling point 188 °C

Flash point 70 °C

Auto-ignition temperature No data available

Decomposition temperature No data available

Flammability (solid, gas) Not flammable

Vapour pressure 0.5 mmHg at 20 °C

Relative vapour density at 20°C No data available

Density 1.44 g/mL

Solubility Soluble in organic solvents, insoluble in water

Log Pow No data available

Viscosity, kinematic No data available

Viscosity, dynamic No data available

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits No data available

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Reacts with strong oxidizing agents and bases.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions On combustion, forms toxic fumes including hydrogen bromide. Decomposes slowly on contact with water. This produces hydrogen bromide.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizers, strong bases, and amines.

10.6 Hazardous decomposition products

Hazardous decomposition products Not specified

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity Toxic if swallowed, inhaled, or absorbed through skin.

Skin corrosion/irritation H315: Causes skin irritation

Serious eye damage/irritation H319: Causes serious eye irritation

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) H335: May cause respiratory irritation

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) 1737

UN-No. (IMDG) 1737

UN-No. (IATA) 1737

UN-No. (ADN) 1737

UN-No. (RID) 1737

14.2 UN proper shipping name

Proper Shipping Name (ADR) Benzyl bromide

Proper Shipping Name (IMDG) Benzyl bromide

Proper Shipping Name (IATA) Benzyl bromide

Proper Shipping Name (ADN) Benzyl bromide

Proper Shipping Name (RID) Benzyl bromide

14.3 Transport hazard class(es)

Transport hazard class(es) 6.1 (8)

14.4 Packing group

Packing group (ADR) II

Packing group (IMDG) II

Packing group (IATA) II

Packing group (ADN) II

Packing group (RID) II

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.