Safety Data Sheet - 2-bromo-2-nitropropane-1,3-diol

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name 2-bromo-2-nitropropane-1,3-diol

Product Form Substance

Catalogue No. AL0901

CAS Number 52-51-7

EC Number 200-143-0

EC Index Number 603-058-00-2

Grade 98%

HSN Code 29053990

Molecular Formula C3H6BrNO4

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name 2-bromo-2-nitropropane-1,3-diol

Catalogue No. AL0901

Product form Substance

CAS Number 52-51-7

EC Number 200-143-0

Grade 98%

EC Index Number 603-058-00-2

Chemical Formula C3H6BrNO4

HSN Code 29053990

Synonyms Bronopol, 2-bromo-2-nitropropane-1,3-diol

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Antimicrobial preservative in cosmetics and personal care products.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Acute Tox. 4; Skin Irrit. 2; Eye Dam. 1; STOT SE 3; Aquatic Acute 1

Classification source ECHA C&L Inventory via PubChem CID 2450 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Corrosive, Irritant, Environmental Hazard

Signal word Danger

Hazard statements H302: Harmful if swallowed; H312: Harmful in contact with skin; H315: Causes skin irritation; H318: Causes serious eye damage; H335: May cause respiratory irritation; H400: Very toxic to aquatic life

2.3 Other hazards

Other hazards May cause skin sensitization.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name 2-bromo-2-nitropropane-1,3-diol

CAS No. 52-51-7

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If symptoms persist, seek medical attention.

First-aid measures after skin contact IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.

First-aid measures after eye contact First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.

First-aid measures after ingestion Rinse mouth. Do not induce vomiting. Seek medical attention if symptoms occur.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Irritation of skin, eyes, and respiratory tract; potential allergic reactions.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Dust explosion possible if in powder or granular form, mixed with air.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and ventilate. Use appropriate protective equipment.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Avoid contact with skin and eyes. Use personal protective equipment as required.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Fireproof. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Dry. Well closed. Keep in a well-ventilated room. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Handle with gloves.

Eye protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin and body protection Wear suitable protective clothing

Respiratory protection Use in a well-ventilated area. If exposure limits are exceeded, use appropriate respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Solid

Colour White

Odour Odorless

Odour threshold No data available

pH value No data available

Relative evaporation rate (butylacetate=1) No data available

Melting point 131.5 °C

Freezing point No data available

Boiling point 152 °C at 760 mmHg

Flash point 167 °C

Auto-ignition temperature No data available

Decomposition temperature No data available

Flammability (solid, gas) Flammable solid

Vapour pressure 1.26X10-5 mm Hg at 20 °C

Relative vapour density at 20°C No data available

Density Relative density (water = 1): 1.9

Solubility In water, 2.5X10+5 mg/L at 22 °C

Log Pow 0.18

Viscosity, kinematic No data available

Viscosity, dynamic No data available

Explosive properties No data available

Oxidising properties No data available

Explosive limits No data available

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions. Avoid strong oxidizing agents.

10.2 Chemical stability

Chemical stability Slightly hygroscopic. Stable under normal storage conditions, but unstable in aluminum containers.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on heating and on burning. This produces toxic and corrosive fumes including hydrogen bromide and nitrogen oxides. Reacts with some metals, amines and alkaline compounds.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizing agents, strong acids, strong bases.

10.6 Hazardous decomposition products

Hazardous decomposition products The substance decomposes on heating or on burning producing toxic and corrosive fumes, including hydrogen bromide and nitrogen oxides.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Mouse oral 350 mg/kg; LD50 Rat (female) oral 342 mg/kg; LD50 Rat (male) oral 307 mg/kg

Skin corrosion/irritation H315: Causes skin irritation

Serious eye damage/irritation H318: Causes serious eye damage

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) H335: May cause respiratory irritation

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 3241

UN-No. (IMDG) UN 3241

UN-No. (IATA) UN 3241

UN-No. (ADN) UN 3241

UN-No. (RID) UN 3241

14.2 UN proper shipping name

Proper Shipping Name (ADR) 2-Bromo-2-nitropropane-1,3-diol

Proper Shipping Name (IMDG) 2-Bromo-2-nitropropane-1,3-diol

Proper Shipping Name (IATA) 2-Bromo-2-nitropropane-1,3-diol

Proper Shipping Name (ADN) 2-Bromo-2-nitropropane-1,3-diol

Proper Shipping Name (RID) 2-Bromo-2-nitropropane-1,3-diol

14.3 Transport hazard class(es)

Transport hazard class(es) 4.1

14.4 Packing group

Packing group (ADR) III

Packing group (IMDG) III

Packing group (IATA) III

Packing group (ADN) III

Packing group (RID) III

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.