Safety Data Sheet - n-Butylamine

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name n-Butylamine

Product Form Substance

Catalogue No. AL0961

CAS Number 109-73-9

EC Number 203-699-2

EC Index Number 612-005-00-5

Grade AR

HSN Code 29211990

Molecular Formula C4H11N

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name n-Butylamine

Catalogue No. AL0961

Product form Substance

CAS Number 109-73-9

EC Number 203-699-2

Grade AR

EC Index Number 612-005-00-5

Chemical Formula C4H11N

HSN Code 29211990

Synonyms Butylamine, 1-Butanamine

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Used as a reagent in organic synthesis and analytical chemistry.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Flam. Liq. 2; Acute Tox. 4; Skin Corr. 1A

Classification source ECHA C&L Inventory via PubChem CID 8007 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Flammable, Corrosive, Irritant

Signal word Danger

Hazard statements H225: Highly Flammable liquid and vapor; H302: Harmful if swallowed; H312: Harmful in contact with skin; H314: Causes severe skin burns and eye damage; H332: Harmful if inhaled

2.3 Other hazards

Other hazards Corrosive to metals; may cause skin and eye irritation.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name n-Butylamine

CAS No. 109-73-9

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact If this chemical contacts the skin, immediately flush the contaminated skin with water. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water. Get medical attention promptly.

First-aid measures after eye contact If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion If this chemical has been swallowed, get medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Irritation of the respiratory tract, skin, and eyes; headache; nausea.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures The vapour is heavier than air and may travel along the ground; distant ignition possible.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area. Remove sources of ignition. Contain spill and absorb with inert material.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Evacuate danger area! Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Ventilation. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Use in a fume hood. Wear gloves and eye protection. Avoid contact with skin and eyes.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Fireproof. Separated from food and feedstuffs. See Chemical Dangers.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless

Odour Amine odor

Odour threshold Not specified

pH value Not specified

Relative evaporation rate (butylacetate=1) Not specified

Melting point -50 °C

Freezing point Not specified

Boiling point 78 °C

Flash point 30 °F (-1 °C) (Open Cup)

Auto-ignition temperature 594 °F (312 °C)

Decomposition temperature Not specified

Flammability (solid, gas) Flammable liquid

Vapour pressure 92.9 mm Hg at 25 °C

Relative vapour density at 20°C 2.5 (AIR = 1)

Density 0.7327 at 25 °C/4 °C

Solubility Miscible with alcohol, ether

Log Pow 0.97

Viscosity, kinematic Not specified

Viscosity, dynamic Not specified

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits 1.2 - 8.0 vol%

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Reacts with strong oxidizing agents and acids.

10.2 Chemical stability

Chemical stability n-Butylamine is stable in closed containers at room temperature under normal storage and handling conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on heating and on burning. This produces toxic fumes including nitrogen oxides. The substance is a weak base.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizers, acids, and bases.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomposition it emits toxic fumes of nitrogen oxides.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 500 mg/kg; LD50 Rat oral 366 mg/kg; LD50 Rat ip 48 mg/kg

Skin corrosion/irritation H314: Causes severe skin burns and eye damage

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 1125

UN-No. (IMDG) UN 1125

UN-No. (IATA) UN 1125

UN-No. (ADN) UN 1125

UN-No. (RID) UN 1125

14.2 UN proper shipping name

Proper Shipping Name (ADR) n-Butylamine

Proper Shipping Name (IMDG) n-Butylamine

Proper Shipping Name (IATA) n-Butylamine

Proper Shipping Name (ADN) n-Butylamine

Proper Shipping Name (RID) n-Butylamine

14.3 Transport hazard class(es)

Transport hazard class(es) 3 (8)

14.4 Packing group

Packing group (ADR) II

Packing group (IMDG) II

Packing group (IATA) II

Packing group (ADN) II

Packing group (RID) II

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.