Safety Data Sheet - n-Butyl methacrylate

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name n-Butyl methacrylate

Product Form Substance

Catalogue No. AL0987

CAS Number 97-88-1

EC Number 202-615-1

EC Index Number 607-095-00-7

Grade 99%, stabilized

HSN Code 29161290

Molecular Formula C8H14O2

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name n-Butyl methacrylate

Catalogue No. AL0987

Product form Substance

CAS Number 97-88-1

EC Number 202-615-1

Grade 99%, stabilized

EC Index Number 607-095-00-7

Chemical Formula C8H14O2

HSN Code 29161290

Synonyms Butyl methacrylate, n-Butyl methacrylate

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Used as a monomer in the production of acrylic polymers and coatings.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Flam. Liq. 3; Skin Irrit. 2; Skin Sens. 1; Eye Irrit. 2; STOT SE 3

Classification source ECHA C&L Inventory via PubChem CID 7354 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Flammable, Irritant

Signal word Warning

Hazard statements H226: Flammable liquid and vapor; H315: Causes skin irritation; H317: May cause an allergic skin reaction; H319: Causes serious eye irritation; H335: May cause respiratory irritation

Precautionary statements P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P272, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, P501

2.3 Other hazards

Other hazards May cause respiratory irritation and skin sensitization.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name n-Butyl methacrylate

CAS No. 97-88-1

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Remove to fresh air, give oxygen or artificial respiration as required.

First-aid measures after skin contact Wash with soap and water.

First-aid measures after eye contact Flush with copious amounts of water for 15 min. and consult physician.

First-aid measures after ingestion Induce vomiting; call a physician.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Irritation of eyes, skin, and respiratory tract; headache; dizziness.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures As a result of flow, agitation, etc., electrostatic charges can be generated.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and eliminate all ignition sources. Ventilate area.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Use in a well-ventilated area. Avoid contact with skin and eyes. Keep away from heat and ignition sources.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Fireproof. Separated from oxidants. Cool. Dry. Keep in the dark. Store only if stabilized. Store in an area without drain or sewer access.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless

Odour Faint characteristic odor of esters

Odour threshold Not specified

pH value Not applicable

Relative evaporation rate (butylacetate=1) Not specified

Melting point freezing point: less than -75 °C

Freezing point Not specified

Boiling point 160 °C

Flash point 126 °F (52 °C) (open cup)

Auto-ignition temperature 290 °C

Decomposition temperature Not specified

Flammability (solid, gas) Flammable liquid

Vapour pressure 2.12 mm Hg at 25 °C

Relative vapour density at 20°C 4.8 (Air = 1)

Density 0.8936 g/cu cm at 20 °C

Solubility Very soluble in ethyl ether, ethanol

Log Pow 2.88

Viscosity, kinematic Not specified

Viscosity, dynamic Not specified

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits Lower: 1.2 vol%, Upper: 7.5 vol%

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions, but may polymerize under heat or light.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions The substance may polymerize due to heating, under the influence of moisture, oxidants or light. This generates fire or explosion hazard.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizing agents, strong acids, and bases.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomp it emits acrid smoke and irritating fumes.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 16,000 mg/kg; LD50 Mouse oral 15,800 mg/kg; LD50 Mouse sc 2,600 mg/kg

Skin corrosion/irritation H315: Causes skin irritation

Serious eye damage/irritation H319: Causes serious eye irritation

Respiratory or skin sensitisation H317: May cause an allergic skin reaction

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) H335: May cause respiratory irritation

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 2227

UN-No. (IMDG) UN 2227

UN-No. (IATA) UN 2227

UN-No. (ADN) UN 2227

UN-No. (RID) UN 2227

14.2 UN proper shipping name

Proper Shipping Name (ADR) n-Butyl methacrylate

Proper Shipping Name (IMDG) n-Butyl methacrylate

Proper Shipping Name (IATA) n-Butyl methacrylate

Proper Shipping Name (ADN) n-Butyl methacrylate

Proper Shipping Name (RID) n-Butyl methacrylate

14.3 Transport hazard class(es)

Transport hazard class(es) 3

14.4 Packing group

Packing group (ADR) III

Packing group (IMDG) III

Packing group (IATA) III

Packing group (ADN) III

Packing group (RID) III

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.