Chloroform
Synonyms: Trichloromethane
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Chloroform
Product Form
Substance
Catalogue No.
AL1296
CAS Number
67-66-3
EC Number
200-663-8
EC Index Number
602-006-00-4
Grade
99% For Synthesis
HSN Code
29031300
Molecular Formula
CHCl3
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Chloroform
Catalogue No.
AL1296
Product form
Substance
CAS Number
67-66-3
EC Number
200-663-8
Grade
99% For Synthesis
EC Index Number
602-006-00-4
Chemical Formula
CHCl3
HSN Code
29031300
Synonyms
Trichloromethane
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Solvent in organic synthesis and extraction processes.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute Tox. 4; Skin Irrit. 2; Eye Irrit. 2; Acute Tox. 3; Carc. 2; Repr. 2; STOT RE 1; STOT RE 2
Classification source
ECHA C&L Inventory via PubChem CID 6212 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Acute Toxic, Health Hazard
Signal word
Danger
Hazard statements
H302: Harmful if swallowed; H315: Causes skin irritation; H319: Causes serious eye irritation; H331: Toxic if inhaled; H351: Suspected of causing cancer; H361: Suspected of damaging fertility or the unborn child; H372: Causes damage to organs through prolonged or repeated exposure; H373: May causes damage to organs through prolonged or repeated exposure
2.3 Other hazards
Other hazards
Suspected carcinogen; may cause reproductive toxicity.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Chloroform
CAS No.
67-66-3
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact
If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing, promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Headache, dizziness, nausea, vomiting, and potential central nervous system effects.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Advice for firefighters: Wear self-contained breathing apparatus for firefighting if necessary.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
The vapour is heavier than air and may accumulate in lowered spaces causing a deficiency of oxygen.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and ventilate. Contain spill and absorb with inert material.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use in a fume hood. Wear appropriate personal protective equipment (PPE).
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Store only in original container. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Ventilation along the floor. Store in an area without drain or sewer access.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless
Odour
Pleasant, etheric, nonirritating
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
-63.47 °C
Freezing point
Not specified
Boiling point
61.12 °C
Flash point
No data available
Auto-ignition temperature
Not specified
Decomposition temperature
Not specified
Flammability (solid, gas)
Not applicable
Vapour pressure
VP: 100 mm Hg at 10.4 °C
Relative vapour density at 20°C
4.12 (Air = 1)
Density
1.4788 g/cu cm at 25 °C
Solubility
In water, 7.95X10+3 mg/L at 25 °C
Log Pow
1.97
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions; reacts with strong oxidizing agents.
10.2 Chemical stability
Chemical stability
Decomposes at ordinary temp in sunlight in the absence of air, and in the dark in the presence of air.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Decomposes on heating. This produces toxic and corrosive fumes of hydrogen chloride (see ICSC 0163), phosgene (see ICSC 0007) and chlorine (see ICSC 0126). Reacts violently with strong bases, strong oxidants, alkalis, acetone and some metals such as aluminium, magnesium and zinc.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, strong bases, and amines.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomposition forms phosgene gas.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 2180 mg/kg; LD50 Rabbit oral 9827 mg/kg; LD50 Rat intragastric 2000 mg/kg
Skin corrosion/irritation
H315: Causes skin irritation
Serious eye damage/irritation
H319: Causes serious eye irritation
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
H351: Suspected of causing cancer
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
H372: Causes damage to organs through prolonged or repeated exposure; H373: May causes damage to organs through prolonged or repeated exposure
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
1888
UN-No. (IMDG)
1888
UN-No. (IATA)
1888
UN-No. (ADN)
1888
UN-No. (RID)
1888
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Chloroform
Proper Shipping Name (IMDG)
Chloroform
Proper Shipping Name (IATA)
Chloroform
Proper Shipping Name (ADN)
Chloroform
Proper Shipping Name (RID)
Chloroform
14.3 Transport hazard class(es)
Transport hazard class(es)
6.1
14.4 Packing group
Packing group (ADR)
III
Packing group (IMDG)
III
Packing group (IATA)
III
Packing group (ADN)
III
Packing group (RID)
III
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.