Safety Data Sheet - Cobalt(II) nitrate hexahydrate

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Cobalt(II) nitrate hexahydrate

Product Form Substance

Catalogue No. AL1437

CAS Number 10026-22-9

EC Number 233-402-1

EC Index Number 647-001-00-0

Grade 97%

HSN Code 28342990

Molecular Formula Co(NO3)2·6H2O

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Cobalt(II) nitrate hexahydrate

Catalogue No. AL1437

Product form Substance

CAS Number 10026-22-9

EC Number 233-402-1

Grade 97%

EC Index Number 647-001-00-0

Chemical Formula Co(NO3)2·6H2O

HSN Code 28342990

Synonyms Cobalt dinitrate hexahydrate

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Used in the synthesis of cobalt oxide catalysts and pigments.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Acute toxicity - category 4; Carcinogenicity - category 1B; Skin corrosion - category 1B; Specific target organ toxicity (repeated exposure) - category 1; Reproductive toxicity - category 1B; Respiratory sensitisation - category 1; Skin sensitisation - category 1

Classification source Safe Work Australia HCIS via PubChem CID 24821 - government classification; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Corrosive, Irritant, Health Hazard

Signal word Danger

Hazard statements H302: Harmful if swallowed; H314: Causes severe skin burns and eye damage; H317: May cause an allergic skin reaction; H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled; H350i: May cause cancer by inhalation; H360F: May damage fertility; H372: Causes damage to organs through prolonged or repeated exposure

Precautionary statements P203, P233, P260, P261, P264, P270, P271, P272, P280, P284, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P318, P319, P321, P330, P333+P317, P342+P316, P362+P364, P363, P403, P405, P501

2.3 Other hazards

Other hazards May cause respiratory irritation; may cause skin and eye irritation.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Cobalt(II) nitrate hexahydrate

CAS No. 10026-22-9

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If symptoms persist, seek medical attention.

First-aid measures after skin contact Wash with soap and water. If irritation occurs, seek medical attention.

First-aid measures after eye contact Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. If irritation persists, seek medical attention.

First-aid measures after ingestion Rinse mouth. Do not induce vomiting. Seek medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Symptoms of exposure may include irritation of the respiratory tract, skin, and eyes.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Oxidizer; may cause or enhance combustion of other materials.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Contain spill and prevent entry into waterways. Use appropriate personal protective equipment.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Handle with gloves and avoid contact with skin and eyes. Use in a well-ventilated area.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Separated from combustible substances and reducing agents. Well closed.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Solid

Colour Red

Odour Odourless

Odour threshold Not applicable

pH value Not applicable

Relative evaporation rate (butylacetate=1) Not applicable

Melting point 55 °C

Freezing point Not applicable

Boiling point Not applicable

Flash point Not applicable

Auto-ignition temperature Not applicable

Decomposition temperature Decomposes above 56 °C

Flammability (solid, gas) Not flammable

Vapour pressure Not applicable

Relative vapour density at 20°C Not applicable

Density 1.88 g/cm³

Solubility Solubility in water, g/100ml at 0 °C: 133.8

Log Pow Not applicable

Viscosity, kinematic Not applicable

Viscosity, dynamic Not applicable

Explosive properties Not explosive

Oxidising properties Oxidizer

Explosive limits Not applicable

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions; may react with strong reducing agents.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on heating. This produces toxic gases including nitrogen oxides. Reacts with combustible substances.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong reducing agents, organic materials.

10.6 Hazardous decomposition products

Hazardous decomposition products Not specified

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity Toxic if swallowed; may cause respiratory irritation.

Skin corrosion/irritation H314: Causes severe skin burns and eye damage

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation H317: May cause an allergic skin reaction; H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity H350i: May cause cancer by inhalation

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) H372: Causes damage to organs through prolonged or repeated exposure

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 1477

UN-No. (IMDG) UN 1477

UN-No. (IATA) UN 1477

UN-No. (ADN) UN 1477

UN-No. (RID) UN 1477

14.2 UN proper shipping name

Proper Shipping Name (ADR) Cobalt(II) nitrate, hydrated

Proper Shipping Name (IMDG) Cobalt(II) nitrate, hydrated

Proper Shipping Name (IATA) Cobalt(II) nitrate, hydrated

Proper Shipping Name (ADN) Cobalt(II) nitrate, hydrated

Proper Shipping Name (RID) Cobalt(II) nitrate, hydrated

14.3 Transport hazard class(es)

Transport hazard class(es) 5.1

14.4 Packing group

Packing group (ADR) II

Packing group (IMDG) II

Packing group (IATA) II

Packing group (ADN) II

Packing group (RID) II

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.