Safety Data Sheet - Copper(II) Sulfate Anhydrous

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Copper(II) Sulfate Anhydrous

Product Form Substance

Catalogue No. AL1526

CAS Number 7758-98-7

EC Number 231-847-6

EC Index Number 029-004-00-0

Grade AR grade, anhydrous

HSN Code 28332500

Molecular Formula CuSO4

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Copper(II) Sulfate Anhydrous

Catalogue No. AL1526

Product form Substance

CAS Number 7758-98-7

EC Number 231-847-6

Grade AR grade, anhydrous

EC Index Number 029-004-00-0

Chemical Formula CuSO4

HSN Code 28332500

Synonyms Cupric sulfate, Blue vitriol (anhydrous)

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Analytical reagent, desiccant, and reference compound.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Acute Tox. 4; Skin Irrit. 2; Eye Irrit. 2; Aquatic Acute 1; Aquatic Chronic 1

Classification source ECHA C&L Inventory via PubChem CID 24462 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Irritant, Environmental Hazard

Signal word Warning

Hazard statements H302: Harmful if swallowed; H315: Causes skin irritation; H319: Causes serious eye irritation; H400: Very toxic to aquatic life; H410: Very toxic to aquatic life with long lasting effects

2.3 Other hazards

Other hazards Hygroscopic; may cause irritation to skin and eyes.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Copper(II) Sulfate Anhydrous

CAS No. 7758-98-7

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If symptoms persist, seek medical attention.

First-aid measures after skin contact Wash with soap and water. Seek medical attention if irritation develops.

First-aid measures after eye contact Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention.

First-aid measures after ingestion Induce vomiting and administer gastric lavage; give a saline cathartic, fluid therapy, and transfusions if required; calcium disodium EDTA has been found moderately effective.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Nausea, vomiting, abdominal pain, and diarrhea upon ingestion; irritation of skin and eyes.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Non-flammable, but may emit toxic fumes in a fire.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Contain spill and collect using appropriate protective equipment. Dispose of in accordance with local regulations.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: particulate filter respirator adapted to the airborne concentration of the substance, protective clothing, protective gloves and safety goggles. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Avoid contact with skin and eyes. Use gloves and protective eyewear.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Well closed. Dry. Store only in original container. Store in an area without drain or sewer access.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use in a well-ventilated area. If exposure limits are exceeded, use appropriate respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Solid

Colour White to pale gray

Odour Pleasant odor

Odour threshold Not applicable

pH value Not applicable

Relative evaporation rate (butylacetate=1) Not applicable

Melting point 590 °C decomp

Freezing point Not applicable

Boiling point 650 °C (decomp to cupric oxide)

Flash point Not applicable

Auto-ignition temperature Not applicable

Decomposition temperature > 600 °C

Flammability (solid, gas) Non-flammable

Vapour pressure Negligible

Relative vapour density at 20°C Not applicable

Density 3.6

Solubility Soluble in water (approximately 24 g/100 mL at 20 °C)

Log Pow Not applicable

Viscosity, kinematic Not applicable

Viscosity, dynamic Not applicable

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits Not applicable

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions. Reacts with strong acids and bases.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions The solution in water is a weak acid. Decomposes at 650 °C. This produces toxic fumes of sulfur oxides (see ICSC 0074). Reacts violently with hydroxylamine.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong acids, strong bases, and reducing agents.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomposition it emits toxic fumes of sulfur oxides.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 300 mgkg body weight LD50 Rabbit Oral 125 mgkg body weight LD100 Mouse Oral 50 mgkg body weight from table/

Skin corrosion/irritation H315: Causes skin irritation

Serious eye damage/irritation H319: Causes serious eye irritation

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) 3077

UN-No. (IMDG) 3077

UN-No. (IATA) 3077

UN-No. (ADN) 3077

UN-No. (RID) 3077

14.2 UN proper shipping name

Proper Shipping Name (ADR) Copper(II) Sulfate, Anhydrous

Proper Shipping Name (IMDG) Copper(II) Sulfate, Anhydrous

Proper Shipping Name (IATA) Copper(II) Sulfate, Anhydrous

Proper Shipping Name (ADN) Copper(II) Sulfate, Anhydrous

Proper Shipping Name (RID) Copper(II) Sulfate, Anhydrous

14.3 Transport hazard class(es)

Transport hazard class(es) 9

14.4 Packing group

Packing group (ADR) III

Packing group (IMDG) III

Packing group (IATA) III

Packing group (ADN) III

Packing group (RID) III

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.