Safety Data Sheet - Diacetone Alcohol

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Diacetone Alcohol

Product Form Substance

Catalogue No. AL1648

CAS Number 123-42-2

EC Number 204-626-7

EC Index Number 606-022-00-7

Grade 98% For Synthesis

HSN Code 29144000

Molecular Formula C6H12O2

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Diacetone Alcohol

Catalogue No. AL1648

Product form Substance

CAS Number 123-42-2

EC Number 204-626-7

Grade 98% For Synthesis

EC Index Number 606-022-00-7

Chemical Formula C6H12O2

HSN Code 29144000

Synonyms 4-Hydroxy-4-methylpentan-2-one

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Solvent in coatings and cleaning formulations.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Eye Irrit. 2

Classification source ECHA C&L Inventory via PubChem CID 31256 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Irritant

Signal word Warning

Hazard statements H319: Causes serious eye irritation

2.3 Other hazards

Other hazards May form explosive peroxides upon prolonged storage.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Diacetone Alcohol

CAS No. 123-42-2

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact If this chemical contacts the skin, flush the contaminated skin with water promptly. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water promptly. If irritation persists after washing, get medical attention.

First-aid measures after eye contact If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion If this chemical has been swallowed, get medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Headache, dizziness, nausea, and irritation of the eyes and skin.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Flashback along vapor trail may occur.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and eliminate all ignition sources. Ventilate area.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Remove all ignition sources. Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Cover the spilled material with inert absorbent. Carefully collect remainder.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Use in a well-ventilated area. Avoid contact with skin and eyes. Keep away from heat and open flames.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Fireproof. Separated from acids, bases, amines and oxidants.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless

Odour Minty odor

Odour threshold No data available

pH value No data available

Relative evaporation rate (butylacetate=1) 0.5

Melting point -44 °C

Freezing point No data available

Boiling point 164 °C at 760 mmHg

Flash point 52 °C

Auto-ignition temperature 640 °C

Decomposition temperature No data available

Flammability (solid, gas) Flammable liquid

Vapour pressure 0.97 MM HG AT 20 °C

Relative vapour density at 20°C 4.0 (AIR= 1.00)

Density 0.938 at 68 °F - Less dense than water; will float

Solubility Water solubility of 1.0X10+6 mg/l

Log Pow -0.14 - 1.03 (calculated)

Viscosity, kinematic No data available

Viscosity, dynamic No data available

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits 1.1 - 7.0 vol% in air

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions. Avoid heat, sparks, and open flames.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on heating or on burning or on contact with acids, bases and amines. This produces acetone and mesityl alcohol. Reacts violently with oxidants.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizing agents, strong acids, and bases.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomp it emits acrid smoke and fumes.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 4.0 g/kg; LD50 Mouse ip 933 mg/kg; LD50 Rabbit dermal 14.5 ml/kg

Skin corrosion/irritation Not classified (based on available data)

Serious eye damage/irritation H319: Causes serious eye irritation

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 1148

UN-No. (IMDG) UN 1148

UN-No. (IATA) UN 1148

UN-No. (ADN) UN 1148

UN-No. (RID) UN 1148

14.2 UN proper shipping name

Proper Shipping Name (ADR) Diacetone Alcohol

Proper Shipping Name (IMDG) Diacetone Alcohol

Proper Shipping Name (IATA) Diacetone Alcohol

Proper Shipping Name (ADN) Diacetone Alcohol

Proper Shipping Name (RID) Diacetone Alcohol

14.3 Transport hazard class(es)

Transport hazard class(es) 3

14.4 Packing group

Packing group (ADR) III

Packing group (IMDG) III

Packing group (IATA) III

Packing group (ADN) III

Packing group (RID) III

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.