1,4-Diaminobutane
Synonyms: Putrescine
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
1,4-Diaminobutane
Product Form
Substance
Catalogue No.
AL1656
CAS Number
110-60-1
EC Number
203-782-3
EC Index Number
612-005-00-4
Grade
98.5%
HSN Code
29212900
Molecular Formula
C4H12N2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
1,4-Diaminobutane
Catalogue No.
AL1656
Product form
Substance
CAS Number
110-60-1
EC Number
203-782-3
Grade
98.5%
EC Index Number
612-005-00-4
Chemical Formula
C4H12N2
HSN Code
29212900
Synonyms
Putrescine
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Intermediate in chemical synthesis and research applications.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute Tox. 4; Acute Tox. 3; Skin Corr. 1B; Eye Dam. 1; Acute Tox. 2
Classification source
ECHA C&L Inventory via PubChem CID 1045 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Corrosive, Acute Toxic
Signal word
Danger
Hazard statements
H302: Harmful if swallowed; H311: Toxic in contact with skin; H314: Causes severe skin burns and eye damage; H318: Causes serious eye damage; H330: Fatal if inhaled
2.3 Other hazards
Other hazards
Corrosive to metals; may cause skin and eye burns.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
1,4-Diaminobutane
CAS No.
110-60-1
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. Seek medical attention if irritation develops.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention.
First-aid measures after ingestion
Rinse mouth. Do NOT induce vomiting. Seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Toxic effects may include irritation of the respiratory tract, skin, and eyes; nausea; and vomiting.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Toxic fumes may be released in a fire. Use water spray to cool containers.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area. Wear appropriate protective equipment. Contain and collect spillage.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Absorb spillage with non-combustible material and place in a suitable container for disposal.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Handle in a fume hood. Use gloves and protective clothing. Avoid contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Hygroscopic. Keep tightly closed. 1,4-Diaminobutane dihydrochloride 97%.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless to pale yellow
Odour
Strong piperidine-like odor
Odour threshold
Not specified
pH value
Not specified
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
27.5 °C
Freezing point
Not specified
Boiling point
158.5 °C
Flash point
Not specified
Auto-ignition temperature
Not specified
Decomposition temperature
Not specified
Flammability (solid, gas)
Not flammable
Vapour pressure
Not specified
Relative vapour density at 20°C
Not specified
Density
0.877 g/cu cm at 25 °C
Solubility
Soluble in water with strongly basic reaction
Log Pow
-3.42
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Reacts with strong oxidizing agents and acids.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizing agents, strong acids.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomposition it emits toxic fumes of nitroxides.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat sc 1625 mgkg 1,4-Diaminobutane dihydrochloride 97%/; LD50 Rat iv 760 mgkg 1,4-Diaminobutane dihydrochloride 97%/; LD50 Mouse ip 1400 mgkg 1,4-Diaminobutane dihydrochloride 97%/
Skin corrosion/irritation
H314: Causes severe skin burns and eye damage
Serious eye damage/irritation
H318: Causes serious eye damage
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
2928
UN-No. (IMDG)
2928
UN-No. (IATA)
2928
UN-No. (ADN)
2928
UN-No. (RID)
2928
14.2 UN proper shipping name
Proper Shipping Name (ADR)
1,4-Diaminobutane
Proper Shipping Name (IMDG)
1,4-Diaminobutane
Proper Shipping Name (IATA)
1,4-Diaminobutane
Proper Shipping Name (ADN)
1,4-Diaminobutane
Proper Shipping Name (RID)
1,4-Diaminobutane
14.3 Transport hazard class(es)
Transport hazard class(es)
6.1 (8)
14.4 Packing group
Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.