4,4'-Diaminodiphenyl ether
Synonyms: 4,4'-Diaminodiphenyl oxide, DAPO
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
4,4'-Diaminodiphenyl ether
Product Form
Substance
Catalogue No.
AL1657
CAS Number
101-80-4
EC Number
202-977-0
EC Index Number
612-100-00-0
Grade
98%
HSN Code
29222900
Molecular Formula
C12H12N2O
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
4,4'-Diaminodiphenyl ether
Catalogue No.
AL1657
Product form
Substance
CAS Number
101-80-4
EC Number
202-977-0
Grade
98%
EC Index Number
612-100-00-0
Chemical Formula
C12H12N2O
HSN Code
29222900
Synonyms
4,4'-Diaminodiphenyl oxide, DAPO
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Monomer for polyimide synthesis
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity - category 3; Carcinogenicity - category 1B; Germ cell mutagenicity - category 1B; Reproductive toxicity - category 2; Skin sensitisation - category 1; Hazardous to the aquatic environment (chronic) - category 2
Classification source
Safe Work Australia HCIS via PubChem CID 7579 - government classification; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Acute Toxic, Health Hazard, Environmental Hazard
Signal word
Danger
Hazard statements
H301: Toxic if swallowed; H311: Toxic in contact with skin; H317: May cause an allergic skin reaction; H331: Toxic if inhaled; H340: May cause genetic defects; H350: May cause cancer; H361f: Suspected of damaging fertility; H411: Toxic to aquatic life with long lasting effects
Precautionary statements
P203, P261, P262, P264, P270, P271, P272, P273, P280, P301+P316, P302+P352, P304+P340, P316, P318, P321, P330, P333+P317, P361+P364, P362+P364, P391, P403+P233, P405, P501
2.3 Other hazards
Other hazards
May cause respiratory irritation.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
4,4'-Diaminodiphenyl ether
CAS No.
101-80-4
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.
First-aid measures after eye contact
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Toxic if swallowed, inhaled, or absorbed through skin. May cause skin and eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Toxic fumes may be released in a fire.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area. Wear appropriate protective equipment. Contain and collect spillage.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Collect spillage in suitable containers for disposal. Avoid release to the environment.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Handle in a fume hood. Use gloves and protective eyewear.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Stable under recommended storage conditions.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Solid
Colour
White to pale tan
Odour
Odourless
Odour threshold
Not applicable
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
189 °C (decomposes
Freezing point
Not applicable
Boiling point
>300 °C
Flash point
219 °C (closed cup)
Auto-ignition temperature
490 °C
Decomposition temperature
Not applicable
Flammability (solid, gas)
Not flammable
Vapour pressure
10 mmHg at 464 °F ; 15 mmHg at 482 °F
Relative vapour density at 20°C
Not applicable
Density
1.18 g/cm³
Solubility
Insoluble in water, benzene, carbon tetrachloride and ethanol; soluble in acetone
Log Pow
1.36
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive
Oxidising properties
Not oxidising
Explosive limits
Not applicable
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizing agents.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomposition it emits toxic fumes of nitrogen oxides.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 725 mg/kg; LD50 Rat intragastric 725 (+ or - 50) mg/kg; LD50 Rat ip 365 (+ or - 25) mg/kg
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
H317: May cause an allergic skin reaction
Germ cell mutagenicity
H340: May cause genetic defects
Carcinogenicity
H350: May cause cancer
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
2811
UN-No. (IMDG)
2811
UN-No. (IATA)
2811
UN-No. (ADN)
2811
UN-No. (RID)
2811
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Toxic solid, organic, n.o.s.
Proper Shipping Name (IMDG)
Toxic solid, organic, n.o.s.
Proper Shipping Name (IATA)
Toxic solid, organic, n.o.s.
Proper Shipping Name (ADN)
Toxic solid, organic, n.o.s.
Proper Shipping Name (RID)
Toxic solid, organic, n.o.s.
14.3 Transport hazard class(es)
Transport hazard class(es)
6.1
14.4 Packing group
Packing group (ADR)
III
Packing group (IMDG)
III
Packing group (IATA)
III
Packing group (ADN)
III
Packing group (RID)
III
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.