Dichloromethane
Synonyms: Methylene chloride
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Dichloromethane
Product Form
Substance
Catalogue No.
AL1713
CAS Number
75-09-2
EC Number
200-838-9
EC Index Number
602-004-00-3
Grade
98%
HSN Code
29031200
Molecular Formula
CH2Cl2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Dichloromethane
Catalogue No.
AL1713
Product form
Substance
CAS Number
75-09-2
EC Number
200-838-9
Grade
98%
EC Index Number
602-004-00-3
Chemical Formula
CH2Cl2
HSN Code
29031200
Synonyms
Methylene chloride
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Solvent in organic chemistry and extraction processes.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Eye Irrit. 2; Carc. 2
Classification source
ECHA C&L Inventory via PubChem CID 6344 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Irritant, Health Hazard
Signal word
Warning
Hazard statements
H319: Causes serious eye irritation; H351: Suspected of causing cancer
2.3 Other hazards
Other hazards
Suspected carcinogen; may cause respiratory irritation.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Dichloromethane
CAS No.
75-09-2
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If breathing is difficult, give oxygen. Seek medical attention if symptoms persist.
First-aid measures after skin contact
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.
First-aid measures after eye contact
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Headache, dizziness, nausea, and respiratory distress.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
The vapour is heavier than air. As a result of flow, agitation, etc., electrostatic charges can be generated.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area. Ventilate and contain spill. Use appropriate protective equipment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Evacuate danger area! Consult an expert! Personal protection: self-contained breathing apparatus. Ventilation. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use in a fume hood. Wear appropriate personal protective equipment (PPE).
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Well closed. Cool. Ventilation along the floor.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection when ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless
Odour
Sweet, pleasant odor, like chloroform
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
-95 °C
Freezing point
Not specified
Boiling point
39.75 °C at 760 mm Hg
Flash point
12 °C
Auto-ignition temperature
1033 °F (556 °C)
Decomposition temperature
Not specified
Flammability (solid, gas)
Not applicable
Vapour pressure
435 mm Hg at 25 °C
Relative vapour density at 20°C
2.93 (Air = 1.02)
Density
1.3255 20 °C/4 °C
Solubility
In water, 13,200 mg/L at 25 °C
Log Pow
1.25
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions. Reacts with strong oxidizing agents.
10.2 Chemical stability
Chemical stability
In the absence of moisture at ordinary temp, dichloromethane is relatively stable when compared with its congeners, chloroform and carbon tetrachloride.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Decomposes on heating or on burning and on contact with hot surfaces. This produces toxic and corrosive fumes including hydrogen chloride (see ICSC 0163), phosgene (see ICSC 0007) and carbon monoxide (see ICSC 0023). Reacts violently with strong oxidants, strong bases and metals such as aluminium powder and magnesium powder.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, strong bases, and amines.
10.6 Hazardous decomposition products
Hazardous decomposition products
It can be decomposed by contact with hot surfaces and open flame, and then yield toxic fumes that are irritating and give warning of their presence.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 1600 mg/kg; LC50 Mouse inhalation 16000 ppm/7 hr plus 1 hr observation; LC50 Rat inhalation 2,000,000 mgcu m15 min
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
H319: Causes serious eye irritation
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
H351: Suspected of causing cancer
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
1593
UN-No. (IMDG)
1593
UN-No. (IATA)
1593
UN-No. (ADN)
1593
UN-No. (RID)
1593
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Dichloromethane
Proper Shipping Name (IMDG)
Dichloromethane
Proper Shipping Name (IATA)
Dichloromethane
Proper Shipping Name (ADN)
Dichloromethane
Proper Shipping Name (RID)
Dichloromethane
14.3 Transport hazard class(es)
Transport hazard class(es)
6.1
14.4 Packing group
Packing group (ADR)
III
Packing group (IMDG)
III
Packing group (IATA)
III
Packing group (ADN)
III
Packing group (RID)
III
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.