Safety Data Sheet - 3,4-Dichloronitrobenzene

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name 3,4-Dichloronitrobenzene

Product Form Substance

Catalogue No. AL1720

CAS Number 99-54-7

EC Number 202-764-2

EC Index Number 606-007-00-4

Grade For Synthesis

HSN Code 29049010

Molecular Formula C6H3Cl2NO2

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name 3,4-Dichloronitrobenzene

Catalogue No. AL1720

Product form Substance

CAS Number 99-54-7

EC Number 202-764-2

Grade For Synthesis

EC Index Number 606-007-00-4

Chemical Formula C6H3Cl2NO2

HSN Code 29049010

Synonyms 3,4-Dichloronitrobenzene

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Intermediate in the synthesis of dyes and pharmaceuticals.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Acute Tox. 4; Skin Sens. 1; Eye Irrit. 2A

Classification source ECHA C&L Inventory via PubChem CID 7443 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Irritant

Signal word Warning

Hazard statements H302: Harmful if swallowed; H317: May cause an allergic skin reaction; H319: Causes serious eye irritation

2.3 Other hazards

Other hazards Toxic if inhaled or absorbed through skin.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name 3,4-Dichloronitrobenzene

CAS No. 99-54-7

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If symptoms persist, seek medical attention.

First-aid measures after skin contact IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.

First-aid measures after eye contact First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.

First-aid measures after ingestion Do not induce vomiting. Rinse mouth and seek medical attention.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Headache, dizziness, nausea, skin irritation.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures May emit toxic fumes in a fire.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and ventilate. Wear appropriate protective equipment.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting. Do NOT let this chemical enter the environment.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Use in a fume hood. Wear gloves and safety goggles.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Separated from strong oxidants, strong bases and food and feedstuffs. Provision to contain effluent from fire extinguishing.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Solid

Colour Pale yellow

Odour Slightly aromatic

Odour threshold No data available

pH value No data available

Relative evaporation rate (butylacetate=1) No data available

Melting point 43 °C

Freezing point No data available

Boiling point 255-256 °C

Flash point 124 °C

Auto-ignition temperature 420 °C

Decomposition temperature No data available

Flammability (solid, gas) Not flammable under normal conditions

Vapour pressure 1.03X10-2 mm Hg at 25 °C

Relative vapour density at 20°C 6.63

Density 1.4558 at 75 °C/4 °C

Solubility Soluble in ether, alcohol; slightly soluble in carbon tetrachloride

Log Pow 3.12

Viscosity, kinematic No data available

Viscosity, dynamic No data available

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits No data available

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions, but may react with strong oxidizing agents.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on heating and on burning. This produces toxic fumes of nitrogen oxides and hydrogen chloride (see ICSC 0163). Reacts violently with oxidants and strong bases.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizing agents, strong bases.

10.6 Hazardous decomposition products

Hazardous decomposition products Not specified

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat Wistar male oral 625 mg/kg bw; LD50 Rat Sprague-Dawley oral 800 mg/kg bw; LD50 Rat Wistar female dermal >2000 mg/kg bw

Skin corrosion/irritation Not classified (based on available data)

Serious eye damage/irritation H319: Causes serious eye irritation

Respiratory or skin sensitisation H317: May cause an allergic skin reaction

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) Not assigned

UN-No. (IMDG) Not assigned

UN-No. (IATA) Not assigned

UN-No. (ADN) Not assigned

UN-No. (RID) Not assigned

14.2 UN proper shipping name

Proper Shipping Name (ADR) 3,4-Dichloronitrobenzene

Proper Shipping Name (IMDG) 3,4-Dichloronitrobenzene

Proper Shipping Name (IATA) 3,4-Dichloronitrobenzene

Proper Shipping Name (ADN) 3,4-Dichloronitrobenzene

Proper Shipping Name (RID) 3,4-Dichloronitrobenzene

14.3 Transport hazard class(es)

Transport hazard class(es) 6.1

14.4 Packing group

Packing group (ADR) III

Packing group (IMDG) III

Packing group (IATA) III

Packing group (ADN) III

Packing group (RID) III

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.