Safety Data Sheet - N,N-Diethylaniline

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name N,N-Diethylaniline

Product Form Substance

Catalogue No. AL1748

CAS Number 91-66-7

EC Number 202-088-8

EC Index Number 612-002-00-4

Grade For Synthesis

HSN Code 29252990

Molecular Formula C10H15N

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name N,N-Diethylaniline

Catalogue No. AL1748

Product form Substance

CAS Number 91-66-7

EC Number 202-088-8

Grade For Synthesis

EC Index Number 612-002-00-4

Chemical Formula C10H15N

HSN Code 29252990

Synonyms N,N-Diethylaminobenzene

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Synthetic intermediate and acid scavenger in organic reactions.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Acute Tox. 3; STOT RE 2; Aquatic Chronic 2

Classification source ECHA C&L Inventory via PubChem CID 7061 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Acute Toxic, Health Hazard, Environmental Hazard

Signal word Danger

Hazard statements H301: Toxic if swallowed; H311: Toxic in contact with skin; H331: Toxic if inhaled; H373: May causes damage to organs through prolonged or repeated exposure; H411: Toxic to aquatic life with long lasting effects

Precautionary statements P260, P261, P262, P264, P270, P271, P273, P280, P301+P316, P302+P352, P304+P340, P316, P319, P321, P330, P361+P364, P391, P403+P233, P405, P501

2.3 Other hazards

Other hazards May cause respiratory irritation. Harmful to aquatic life with long lasting effects.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name N,N-Diethylaniline

CAS No. 91-66-7

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If symptoms persist, seek medical attention.

First-aid measures after skin contact IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.

First-aid measures after eye contact First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.

First-aid measures after ingestion Do not induce vomiting. Rinse mouth and seek medical attention.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Headache, dizziness, nausea, and respiratory irritation.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Toxic fumes may be released in a fire. Use water spray to cool containers.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area. Wear appropriate protective equipment. Contain and collect spillage.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Avoid contact with skin and eyes. Use in a fume hood with appropriate PPE.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Store in an area without drain or sewer access. Well closed. Separated from food and feedstuffs.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless to pale yellow

Odour Amine

Odour threshold Not available

pH value Not applicable

Relative evaporation rate (butylacetate=1) Not available

Melting point -38.8 °C

Freezing point Not available

Boiling point 216.3 °C

Flash point 79 °C c.c.

Auto-ignition temperature 1166 °F(630 °C)

Decomposition temperature Not available

Flammability (solid, gas) Not flammable

Vapour pressure 0.14 mm Hg @ 25 °C

Relative vapour density at 20°C 1.0 (AIR= 1)

Density 0.9307 @ 20 °C/4 °C

Solubility 1 g dissolves in 70 ml of water at 12 °C; slightly sol in alcohol, chloroform and ether

Log Pow log Kow= 3.31

Viscosity, kinematic Not available

Viscosity, dynamic Not available

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits Not available

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions. Reacts with strong oxidizing agents.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on heating. This produces toxic fumes including nitrogen oxides.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizing agents, strong acids.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomposition it emits toxic fumes of nitroxides.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 782 mg/kg; LD50 Rat ip 420 mg/kg

Skin corrosion/irritation Not classified (based on available data)

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) H373: May causes damage to organs through prolonged or repeated exposure

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 2432

UN-No. (IMDG) UN 2432

UN-No. (IATA) UN 2432

UN-No. (ADN) UN 2432

UN-No. (RID) UN 2432

14.2 UN proper shipping name

Proper Shipping Name (ADR) N,N-Diethylaniline

Proper Shipping Name (IMDG) N,N-Diethylaniline

Proper Shipping Name (IATA) N,N-Diethylaniline

Proper Shipping Name (ADN) N,N-Diethylaniline

Proper Shipping Name (RID) N,N-Diethylaniline

14.3 Transport hazard class(es)

Transport hazard class(es) 6.1

14.4 Packing group

Packing group (ADR) III

Packing group (IMDG) III

Packing group (IATA) III

Packing group (ADN) III

Packing group (RID) III

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.