Diethylene Glycol
Synonyms: Diglycol, 2,2'-Oxybisethanol
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Diethylene Glycol
Product Form
Substance
Catalogue No.
AL1755
CAS Number
111-46-6
EC Number
203-872-2
EC Index Number
603-140-00-6
Grade
AR grade
HSN Code
29094100
Molecular Formula
C4H10O3
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Diethylene Glycol
Catalogue No.
AL1755
Product form
Substance
CAS Number
111-46-6
EC Number
203-872-2
Grade
AR grade
EC Index Number
603-140-00-6
Chemical Formula
C4H10O3
HSN Code
29094100
Synonyms
Diglycol, 2,2'-Oxybisethanol
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used as a solvent and in chemical synthesis.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute Tox. 4
Classification source
ECHA C&L Inventory via PubChem CID 8117 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Irritant
Signal word
Warning
Hazard statements
H302: Harmful if swallowed
Precautionary statements
P264, P270, P301+P317, P330, P501
2.3 Other hazards
Other hazards
Toxic if ingested; may cause skin and eye irritation.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Diethylene Glycol
CAS No.
111-46-6
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.
First-aid measures after eye contact
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Nausea, headache, dizziness, and irritation of skin and eyes.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Combustible liquid; may produce toxic fumes in a fire.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Contain spill and absorb with inert material. Dispose of in accordance with local regulations.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking and spilled liquid in sealable containers as far as possible. Wash away remainder with plenty of water.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Avoid contact with skin and eyes. Use gloves and safety goggles when handling.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Dry. Well closed. Separated from strong oxidants.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use in a well-ventilated area. If exposure limits are exceeded, use appropriate respiratory protection.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless
Odour
Practically odorless
Odour threshold
No data available
pH value
No data available
Relative evaporation rate (butylacetate=1)
<1
Melting point
-10.4 °C
Freezing point
No data available
Boiling point
245.8 °C
Flash point
143 °C
Auto-ignition temperature
229 °C
Decomposition temperature
No data available
Flammability (solid, gas)
Not applicable
Vapour pressure
VP: 1 mm Hg at 91.8 °C
Relative vapour density at 20°C
3.66 (Air = 1)
Density
1.1197 g/cu cm at 15 °C
Solubility
Immiscible with toluene, petroleum, linseed or castor oil
Log Pow
-1.47
Viscosity, kinematic
No data available
Viscosity, dynamic
No data available
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions. Reacts with strong oxidizing agents.
10.2 Chemical stability
Chemical stability
Low volatility.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Reacts violently with strong oxidants. This generates fire and explosion hazard. Attacks some forms of plastic.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizing agents, strong acids.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomposition it emits acrid smoke and irritating fumes.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 15.6 g/kg; LD50 Mouse oral 13.3 g/kg; LD50 Rabbit oral 26.9 g/kg
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
Not assigned
UN-No. (IMDG)
Not assigned
UN-No. (IATA)
Not assigned
UN-No. (ADN)
Not assigned
UN-No. (RID)
Not assigned
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Not regulated
Proper Shipping Name (IMDG)
Not regulated
Proper Shipping Name (IATA)
Not regulated
Proper Shipping Name (ADN)
Not regulated
Proper Shipping Name (RID)
Not regulated
14.3 Transport hazard class(es)
Transport hazard class(es)
Not applicable
14.4 Packing group
Packing group (ADR)
Not applicable
Packing group (IMDG)
Not applicable
Packing group (IATA)
Not applicable
Packing group (ADN)
Not applicable
Packing group (RID)
Not applicable
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.