Diethyl Ether
Synonyms: Ethyl ether, Diethyl oxide
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Diethyl Ether
Product Form
Substance
Catalogue No.
AL1767
CAS Number
60-29-7
EC Number
200-467-2
EC Index Number
603-019-00-2
Grade
HPLC & Spectroscopy
HSN Code
29091100
Molecular Formula
C4H10O
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Diethyl Ether
Catalogue No.
AL1767
Product form
Substance
CAS Number
60-29-7
EC Number
200-467-2
Grade
HPLC & Spectroscopy
EC Index Number
603-019-00-2
Chemical Formula
C4H10O
HSN Code
29091100
Synonyms
Ethyl ether, Diethyl oxide
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Solvent for chromatography and spectroscopy
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flam. Liq. 1; Acute Tox. 4; STOT SE 3
Classification source
ECHA C&L Inventory via PubChem CID 3283 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Flammable, Irritant
Signal word
Danger
Hazard statements
H224: Extremely flammable liquid and vapor; H302: Harmful if swallowed; H336: May cause drowsiness or dizziness
Precautionary statements
P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+P317, P303+P361+P353, P304+P340, P319, P330, P370+P378, P403+P233, P403+P235, P405, P501
2.3 Other hazards
Other hazards
Forms explosive peroxides upon prolonged storage.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Diethyl Ether
CAS No.
60-29-7
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.
First-aid measures after eye contact
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Dizziness, headache, nausea, respiratory irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
The vapour is heavier than air and may travel along the ground; distant ignition possible. As a result of flow, agitation, etc., electrostatic charges can be generated.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and eliminate all ignition sources. Ventilate area.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Remove all ignition sources. Evacuate danger area! Consult an expert! Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use in a well-ventilated area. Avoid contact with skin and eyes. Keep away from heat and open flames.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Fireproof. Separated from oxidants and other incompatible materials. See Chemical Dangers. Cool. Keep in the dark. Store only if stabilized. Ventilation along the floor.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless
Odour
Sweetish, pungent odor
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
-116.3 °C (stable crystals); -123.3 °C (metastable crystals)
Freezing point
Not specified
Boiling point
34.6 °C at 760 mm Hg; 17.9 °C at 400 mm Hg; 2.2 °C at 200 mm Hg
Flash point
-45 °C
Auto-ignition temperature
356 °F (180 °C)
Decomposition temperature
Not specified
Flammability (solid, gas)
Flammable liquid
Vapour pressure
538 mm Hg at 25 °C
Relative vapour density at 20°C
2.55 (Air = 1.0)
Density
0.7134 at 20 °C/4 °C
Solubility
Miscible with water, ethanol, and ether
Log Pow
log Kow= 0.89
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Forms explosive peroxides upon prolonged exposure to air
Oxidising properties
Not oxidizing
Explosive limits
1.2 - 48% (v/v) in air
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions. Reacts with strong oxidizing agents.
10.2 Chemical stability
Chemical stability
It is slowly oxidized by action of air, moisture, and light, with formation of peroxides.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
The substance can form explosive peroxides under the influence of light and air. Reacts violently with halogens, interhalogens, sulfur compounds and oxidants. This generates fire and explosion hazard.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, acids, and bases.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomposition it emits acrid smoke and irritating fumes.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Mouse iv 996 mg/kg bw; LD50 Mouse ip 2420 mg/kg bw; LC50 Mouse inhalation 186 mg/L/90 min
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
H336: May cause drowsiness or dizziness
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 1155
UN-No. (IMDG)
UN 1155
UN-No. (IATA)
UN 1155
UN-No. (ADN)
UN 1155
UN-No. (RID)
UN 1155
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Diethyl Ether
Proper Shipping Name (IMDG)
Diethyl Ether
Proper Shipping Name (IATA)
Diethyl Ether
Proper Shipping Name (ADN)
Diethyl Ether
Proper Shipping Name (RID)
Diethyl Ether
14.3 Transport hazard class(es)
Transport hazard class(es)
3
14.4 Packing group
Packing group (ADR)
I
Packing group (IMDG)
I
Packing group (IATA)
I
Packing group (ADN)
I
Packing group (RID)
I
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.