Safety Data Sheet - Diethyl ketone

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Diethyl ketone

Product Form Substance

Catalogue No. AL1767A

CAS Number 96-22-0

EC Number 202-490-3

EC Index Number 606-022-00-7

Grade 99% For Synthesis

HSN Code 29141990

Molecular Formula C5H10O

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Diethyl ketone

Catalogue No. AL1767A

Product form Substance

CAS Number 96-22-0

EC Number 202-490-3

Grade 99% For Synthesis

EC Index Number 606-022-00-7

Chemical Formula C5H10O

HSN Code 29141990

Synonyms 3-Pentanone

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Solvent and synthetic intermediate in organic synthesis.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Flam. Liq. 2; STOT SE 3

Classification source ECHA C&L Inventory via PubChem CID 7288 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Flammable, Irritant

Signal word Danger

Hazard statements H225: Highly Flammable liquid and vapor; H335: May cause respiratory irritation; H336: May cause drowsiness or dizziness

Precautionary statements P210, P233, P240, P241, P242, P243, P261, P271, P280, P303+P361+P353, P304+P340, P319, P370+P378, P403+P233, P403+P235, P405, P501

2.3 Other hazards

Other hazards Vapor may cause drowsiness or dizziness.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Diethyl ketone

CAS No. 96-22-0

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact If this chemical contacts the skin, wash the contaminated skin with soap and water.

First-aid measures after eye contact If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion If this chemical has been swallowed, get medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Headache, dizziness, nausea, irritation of eyes and skin.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures The vapour is heavier than air and may travel along the ground; distant ignition possible. The vapour mixes well with air, explosive mixtures are easily formed.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area. Remove all sources of ignition. Ventilate area.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Evacuate danger area! Remove all ignition sources. Consult an expert! Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Ventilation. Collect leaking and spilled liquid in sealable metal (mild steel) containers as far as possible.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Avoid contact with skin and eyes. Use in a well-ventilated area.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Fireproof. Well closed. Separated from oxidants. Ventilation along the floor. Store in an area without drain or sewer access.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless

Odour Acetone odor

Odour threshold Not specified

pH value Not applicable

Relative evaporation rate (butylacetate=1) 0.6

Melting point -39 °C

Freezing point Not specified

Boiling point 101.7 °C

Flash point 13 °C (open cup)

Auto-ignition temperature 842 °F (450 °C)

Decomposition temperature Not specified

Flammability (solid, gas) Flammable liquid

Vapour pressure 37.7 mm Hg at 25 °C

Relative vapour density at 20°C 3.0 (Air = 1)

Density 0.8098 g/cu cm at 25 °C

Solubility Solubility at 20 °C: 2.6 wt% water in 3-pentanone

Log Pow 0.99

Viscosity, kinematic 0.9 cSt at 20 °C

Viscosity, dynamic Not specified

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits 1.1 - 7.0 % (v/v) in air

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions. Avoid strong oxidizing agents.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Reacts violently with oxidants. This generates fire and explosion hazard. Attacks many plastics.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizing agents, strong acids, and bases.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomposition it emits acrid smoke and irritating fumes.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Mouse iv 513 mg/kg bw; LD50 Mouse ip 810 mg/kg bw; LD50 Rabbit dermal >5000 mg/kg

Skin corrosion/irritation Not classified (based on available data)

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) H335: May cause respiratory irritation; H336: May cause drowsiness or dizziness

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) 1156

UN-No. (IMDG) 1156

UN-No. (IATA) 1156

UN-No. (ADN) 1156

UN-No. (RID) 1156

14.2 UN proper shipping name

Proper Shipping Name (ADR) Diethyl ketone

Proper Shipping Name (IMDG) Diethyl ketone

Proper Shipping Name (IATA) Diethyl ketone

Proper Shipping Name (ADN) Diethyl ketone

Proper Shipping Name (RID) Diethyl ketone

14.3 Transport hazard class(es)

Transport hazard class(es) 3

14.4 Packing group

Packing group (ADR) II

Packing group (IMDG) II

Packing group (IATA) II

Packing group (ADN) II

Packing group (RID) II

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.