Safety Data Sheet - Diisopropyl Ether

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Diisopropyl Ether

Product Form Substance

Catalogue No. AL1797

CAS Number 108-20-3

EC Number 203-560-6

EC Index Number 603-103-00-4

Grade 99% For Synthesis

HSN Code 29091900

Molecular Formula C6H14O

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Diisopropyl Ether

Catalogue No. AL1797

Product form Substance

CAS Number 108-20-3

EC Number 203-560-6

Grade 99% For Synthesis

EC Index Number 603-103-00-4

Chemical Formula C6H14O

HSN Code 29091900

Synonyms 2-Propanol, ether; Diisopropyl oxide

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Solvent in organic synthesis and extraction processes.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Flam. Liq. 2; STOT SE 3

Classification source ECHA C&L Inventory via PubChem CID 7914 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Flammable, Irritant

Signal word Danger

Hazard statements H225: Highly Flammable liquid and vapor; H336: May cause drowsiness or dizziness

2.3 Other hazards

Other hazards Forms explosive peroxides upon prolonged storage.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Diisopropyl Ether

CAS No. 108-20-3

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing, promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.

First-aid measures after eye contact If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion If this chemical has been swallowed, get medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Headache, dizziness, nausea, and respiratory irritation.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures The vapour is heavier than air and may travel along the ground; distant ignition possible. As a result of flow, agitation, etc., electrostatic charges can be generated.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and eliminate all ignition sources. Ventilate area.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Evacuate danger area! Consult an expert! Personal protection: self-contained breathing apparatus. Ventilation. Collect leaking and spilled liquid in sealable metal containers as far as possible. Absorb remaining liquid in sand or inert absorbent.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Avoid contact with skin and eyes. Use in a well-ventilated area and keep away from heat and ignition sources.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Fireproof. Cool. Keep in the dark. Keep in a well-ventilated room. Store only if stabilized.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless

Odour Sweet, slightly sharp, pungent like camphor and ethyl ether

Odour threshold Not specified

pH value Not applicable

Relative evaporation rate (butylacetate=1) Not specified

Melting point -86.8 °C

Freezing point Not specified

Boiling point 68.5 °C

Flash point -18 °F (-28 °C) (closed cup)

Auto-ignition temperature 830 °F (443 °C)

Decomposition temperature Not specified

Flammability (solid, gas) Highly flammable liquid

Vapour pressure 149 mm Hg @ 25 °C from experimentally derived coefficients

Relative vapour density at 20°C 3.5 (air= 1)

Density 0.7258 @ 20 °C/4 °C

Solubility Sol of commercial grade in water, 1.71% @ 19 °C; miscible with most organic solvents.

Log Pow log Kow= 1.52

Viscosity, kinematic Not specified

Viscosity, dynamic Not specified

Explosive properties Forms explosive peroxides upon prolonged storage

Oxidising properties Not oxidizing

Explosive limits Lower: 1.1% vol, Upper: 7.5% vol

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions, but may react with strong oxidizing agents.

10.2 Chemical stability

Chemical stability Keeping ethers from becoming anhydrous plus the addition of antioxidants will help reduce this explosion hazard.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions The substance can readily form explosive peroxides if unstabilized and explode on shaking.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizers, acids, and bases.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomposition it emits acrid smoke and fumes.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 (oral, rat) > 5000 mg/kg.

Skin corrosion/irritation Not classified (based on available data)

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) H336: May cause drowsiness or dizziness

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 1159

UN-No. (IMDG) UN 1159

UN-No. (IATA) UN 1159

UN-No. (ADN) UN 1159

UN-No. (RID) UN 1159

14.2 UN proper shipping name

Proper Shipping Name (ADR) Diisopropyl ether

Proper Shipping Name (IMDG) Diisopropyl ether

Proper Shipping Name (IATA) Diisopropyl ether

Proper Shipping Name (ADN) Diisopropyl ether

Proper Shipping Name (RID) Diisopropyl ether

14.3 Transport hazard class(es)

Transport hazard class(es) 3

14.4 Packing group

Packing group (ADR) II

Packing group (IMDG) II

Packing group (IATA) II

Packing group (ADN) II

Packing group (RID) II

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.