Safety Data Sheet - m-Dinitrobenzene

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name m-Dinitrobenzene

Product Form Substance

Catalogue No. AL1893

CAS Number 99-65-0

EC Number 202-776-8

EC Index Number 006-002-00-2

Grade AR

HSN Code 29042020

Molecular Formula C6H4N2O4

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name m-Dinitrobenzene

Catalogue No. AL1893

Product form Substance

CAS Number 99-65-0

EC Number 202-776-8

Grade AR

EC Index Number 006-002-00-2

Chemical Formula C6H4N2O4

HSN Code 29042020

Synonyms 1,3-Dinitrobenzene; 3-Nitro-1,4-benzenediamine

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Reagent for analytical chemistry and organic synthesis.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Acute Tox. 2; Acute Tox. 1; STOT RE 2; Aquatic Acute 1; Aquatic Chronic 1

Classification source ECHA C&L Inventory via PubChem CID 7452 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Acute Toxic, Health Hazard, Environmental Hazard

Signal word Danger

Hazard statements H300: Fatal if swallowed; H310: Fatal in contact with skin; H330: Fatal if inhaled; H373: May causes damage to organs through prolonged or repeated exposure; H400: Very toxic to aquatic life; H410: Very toxic to aquatic life with long lasting effects

Precautionary statements P260, P262, P264, P270, P271, P273, P280, P284, P301+P316, P302+P352, P304+P340, P316, P319, P320, P321, P330, P361+P364, P391, P403+P233, P405, P501

2.3 Other hazards

Other hazards May cause harm to the unborn child. Suspected of causing cancer.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name m-Dinitrobenzene

CAS No. 99-65-0

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.

First-aid measures after eye contact If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion If this chemical has been swallowed, get medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Headache, dizziness, nausea, and skin irritation upon exposure.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Dust explosion possible if in powder or granular form, mixed with air.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and ventilate. Wear appropriate protective equipment. Contain spill and collect for disposal.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Consult an expert! Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Avoid contact with skin and eyes. Use in a fume hood with appropriate PPE.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Separated from strong oxidants, strong bases and food and feedstuffs. See Chemical Dangers.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respirator if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Solid

Colour Pale yellow

Odour Slightly aromatic

Odour threshold No data available

pH value No data available

Relative evaporation rate (butylacetate=1) No data available

Melting point 89-90 °C

Freezing point No data available

Boiling point 302.8 °C @ 770 mm Hg

Flash point 150 °C

Auto-ignition temperature No data available

Decomposition temperature No data available

Flammability (solid, gas) Not flammable under normal conditions

Vapour pressure 2X10-4 mm Hg @ 25 °C

Relative vapour density at 20°C 5.8 (air= 1 at boiling point of dinitrobenzene)

Density 1.575 @ 18 °C/4 °C

Solubility Slightly soluble in water, soluble in organic solvents

Log Pow log Kow= 1.49

Viscosity, kinematic No data available

Viscosity, dynamic No data available

Explosive properties No data available

Oxidising properties No data available

Explosive limits No data available

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions. Reacts with strong oxidizing agents.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions May explode on heating even in the absence of air. On combustion, forms toxic gases and fumes including nitrogen oxides. Reacts violently with strong oxidants, strong bases and reducing metals (tin and zinc).

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizers, strong acids, and bases.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomposition it emits toxic fumes of nitrogen oxides.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral as a 1% suspension in corn oil 83 mgkg with fiducial limits 56-124 mgkg; LD50 Rat ip 28 mg/kg; LD50 Dog iv 10 mg/kg

Skin corrosion/irritation Not classified (based on available data)

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) H373: May causes damage to organs through prolonged or repeated exposure

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) 3443

UN-No. (IMDG) 3443

UN-No. (IATA) 3443

UN-No. (ADN) 3443

UN-No. (RID) 3443

14.2 UN proper shipping name

Proper Shipping Name (ADR) m-Dinitrobenzene

Proper Shipping Name (IMDG) m-Dinitrobenzene

Proper Shipping Name (IATA) m-Dinitrobenzene

Proper Shipping Name (ADN) m-Dinitrobenzene

Proper Shipping Name (RID) m-Dinitrobenzene

14.3 Transport hazard class(es)

Transport hazard class(es) 6.1

14.4 Packing group

Packing group (ADR) II

Packing group (IMDG) II

Packing group (IATA) II

Packing group (ADN) II

Packing group (RID) II

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.