Ethyl Chloroacetate
Synonyms: Ethyl 2-chloroacetate
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Ethyl Chloroacetate
Product Form
Substance
Catalogue No.
AL2064
CAS Number
105-39-5
EC Number
203-294-0
EC Index Number
607-007-00-4
Grade
99% For Synthesis
HSN Code
29153990
Molecular Formula
C4H7ClO2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Ethyl Chloroacetate
Catalogue No.
AL2064
Product form
Substance
CAS Number
105-39-5
EC Number
203-294-0
Grade
99% For Synthesis
EC Index Number
607-007-00-4
Chemical Formula
C4H7ClO2
HSN Code
29153990
Synonyms
Ethyl 2-chloroacetate
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used as an alkylating agent and synthetic intermediate in organic chemistry.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flam. Liq. 3; Acute Tox. 3; Acute Tox. 2; Skin Irrit. 2; Skin Sens. 1; Eye Dam. 1; Aquatic Acute 1
Classification source
ECHA C&L Inventory via PubChem CID 7751 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Flammable, Corrosive, Acute Toxic, Environmental Hazard
Signal word
Danger
Hazard statements
H226: Flammable liquid and vapor; H301: Toxic if swallowed; H310: Fatal in contact with skin; H315: Causes skin irritation; H317: May cause an allergic skin reaction; H318: Causes serious eye damage; H331: Toxic if inhaled; H400: Very toxic to aquatic life
2.3 Other hazards
Other hazards
Lachrymator; may cause respiratory irritation.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Ethyl Chloroacetate
CAS No.
105-39-5
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Remove patient to fresh air; get medical attention.
First-aid measures after skin contact
Wash with soap and water.
First-aid measures after eye contact
Flush with copious quantities of water for at least 15 min.; get medical attention if irritation persists.
First-aid measures after ingestion
Give large amount of water and induce vomiting; get medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
May cause irritation to skin, eyes, and respiratory tract. Symptoms may include coughing, shortness of breath, and skin irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
The vapour is heavier than air.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and ventilate. Use appropriate protective equipment. Contain and absorb spill with inert material.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Remove all ignition sources. Personal protection: chemical protection suit including self-contained breathing apparatus. Collect leaking and spilled liquid in covered plastic containers as far as possible. Absorb remaining liquid in dry sand or inert absorbent.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use in a fume hood. Wear appropriate personal protective equipment including gloves and goggles.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Fireproof. Separated from incompatible materials and food and feedstuffs. See Chemical Dangers. Dry.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless
Odour
Fruity pungent odor
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
-26 °C
Freezing point
Not specified
Boiling point
144-146 °C
Flash point
38 °C
Auto-ignition temperature
452 °C
Decomposition temperature
Not specified
Flammability (solid, gas)
Flammable liquid
Vapour pressure
Vapor pressure: 10 mm Hg @ 37.5 °C
Relative vapour density at 20°C
4.23-4.46
Density
1.1498 @ 20 °C/4 °C
Solubility
Insol in water; miscible with alc, ether
Log Pow
0.94
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Reacts with strong bases and oxidizing agents.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Decomposes on burning. This produces toxic and corrosive gases including hydrogen chloride and acetic acid fumes. Reacts with water, moist air and acids.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, strong bases, and amines.
10.6 Hazardous decomposition products
Hazardous decomposition products
Not specified
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Mouse sc 250 mg/kg; LD50 Rabbit skin 230 mg/kg
Skin corrosion/irritation
H315: Causes skin irritation
Serious eye damage/irritation
H318: Causes serious eye damage
Respiratory or skin sensitisation
H317: May cause an allergic skin reaction
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 1181
UN-No. (IMDG)
UN 1181
UN-No. (IATA)
UN 1181
UN-No. (ADN)
UN 1181
UN-No. (RID)
UN 1181
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Ethyl Chloroacetate
Proper Shipping Name (IMDG)
Ethyl Chloroacetate
Proper Shipping Name (IATA)
Ethyl Chloroacetate
Proper Shipping Name (ADN)
Ethyl Chloroacetate
Proper Shipping Name (RID)
Ethyl Chloroacetate
14.3 Transport hazard class(es)
Transport hazard class(es)
6.1 (3)
14.4 Packing group
Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.