Fluoroboric Acid

Synonyms: Borofluoric acid

SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name Fluoroboric Acid
Product Form Substance
Catalogue No. AL2199
CAS Number 16872-11-0
EC Number 240-898-3
EC Index Number Boric acid, fluoroboric acid
Grade 40% For Synthesis
HSN Code 28111990
Molecular Formula HBF4
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name Fluoroboric Acid
Catalogue No. AL2199
Product form Substance
CAS Number 16872-11-0
EC Number 240-898-3
Grade 40% For Synthesis
EC Index Number Boric acid, fluoroboric acid
Chemical Formula HBF4
HSN Code 28111990
Synonyms Borofluoric acid
Chemical Structure -
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture Used as a catalyst and electrolyte in metal plating and organic synthesis.
Uses advised against Not specified
1.3 Details of the supplier of the safety data sheet
Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 Skin Corr. 1B; Eye Dam. 1
Classification source ECHA C&L Inventory via PubChem CID 28118 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms Corrosive
Signal word Danger
Hazard statements H314: Causes severe skin burns and eye damage; H318: Causes serious eye damage
2.3 Other hazards
Other hazards Corrosive to metals and tissue.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name Fluoroboric Acid
CAS No. 16872-11-0
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation Move to fresh air. Seek medical attention if symptoms persist.
First-aid measures after skin contact Wash with plenty of soap and water. Seek medical attention if irritation develops.
First-aid measures after eye contact Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention.
First-aid measures after ingestion Do not induce vomiting. Rinse mouth and seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use Corrosive effects may include burns, irritation, and respiratory distress.
4.3 Indication of any immediate medical attention and special treatment needed
General information Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures Non-flammable, but may emit toxic fumes in a fire.
5.3 Advice for firefighters
Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures Contain spill and neutralize with a suitable alkaline material.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up Personal protection: complete protective clothing including self-contained breathing apparatus. Consult an expert! Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
6.4 Reference to other sections
Reference Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling Use personal protective equipment. Avoid contact with skin and eyes.
Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions Separated from strong bases, metals and food and feedstuffs. Well closed. Ventilation along the floor. Store only in original container. Do NOT store or transport in containers made from metal or glass. Store in an area without drain or sewer access.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection Protective gloves (e.g. nitrile rubber)
Eye protection Chemical safety goggles or safety glasses
Skin and body protection Wear suitable protective clothing
Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state Liquid
Colour Colorless to pale yellow
Odour Odourless
Odour threshold Not applicable
pH value <1
Relative evaporation rate (butylacetate=1) Not applicable
Melting point -30 °C
Freezing point Not applicable
Boiling point 130 °C decomposes
Flash point Not applicable
Auto-ignition temperature Not applicable
Decomposition temperature Not applicable
Flammability (solid, gas) Not applicable
Vapour pressure Not specified
Relative vapour density at 20°C Not specified
Density Approximately 1.8 g/cu cm
Solubility Very soluble in water, ethanol
Log Pow Not specified
Viscosity, kinematic Not specified
Viscosity, dynamic Not specified
Explosive properties Not applicable
Oxidising properties Not applicable
Explosive limits Not applicable
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity Reacts violently with strong bases and may release toxic gases.
10.2 Chemical stability
Chemical stability Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions Decomposes on heating. This produces toxic and corrosive fumes including hydrogen fluoride and fluorine compounds. The solution in water is a strong acid.
10.4 Conditions to avoid
Conditions to avoid Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials Strong bases, metals, and oxidizing agents.
10.6 Hazardous decomposition products
Hazardous decomposition products When heated to decomposition it emits toxic vapors of boron and hydrogen fluoride.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity LD50 Rat oral 100-200 mg/kg bw; LD50 Rat oral 464-1000 mgkg bw 51% Tetrafluoroboric acid/; LD50 Mouse oral <50 mg/kg bw
Skin corrosion/irritation H314: Causes severe skin burns and eye damage
Serious eye damage/irritation H318: Causes serious eye damage
Respiratory or skin sensitisation Not classified (based on available data)
Germ cell mutagenicity Not classified (based on available data)
Carcinogenicity Not classified (based on available data)
Specific target organ toxicity (single exposure) Not classified (based on available data)
Specific target organ toxicity (repeated exposure) Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information Not specified
12.2 Persistence - degradability
Persistence - degradability Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential Not specified
12.4 Mobility in soil
Mobility in soil Not specified
12.6 Other adverse effects
Environmental precautions Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR) 1775
UN-No. (IMDG) 1775
UN-No. (IATA) 1775
UN-No. (ADN) 1775
UN-No. (RID) 1775
14.2 UN proper shipping name
Proper Shipping Name (ADR) Fluoroboric Acid
Proper Shipping Name (IMDG) Fluoroboric Acid
Proper Shipping Name (IATA) Fluoroboric Acid
Proper Shipping Name (ADN) Fluoroboric Acid
Proper Shipping Name (RID) Fluoroboric Acid
14.3 Transport hazard class(es)
Transport hazard class(es) 8
14.4 Packing group
Packing group (ADR) II
Packing group (IMDG) II
Packing group (IATA) II
Packing group (ADN) II
Packing group (RID) II
14.5 Environmental hazards
Dangerous for the environment Not specified
Marine pollutant Not specified
Other information No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations Not specified
SECTION 16: Other Information
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.