Formic Acid
Synonyms: Methanoic acid, Formylic acid
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Formic Acid
Product Form
Substance
Catalogue No.
AL2226
CAS Number
64-18-6
EC Number
200-579-1
EC Index Number
607-001-00-0
Grade
85% For Synthesis
HSN Code
29151100
Molecular Formula
CH2O2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Formic Acid
Catalogue No.
AL2226
Product form
Substance
CAS Number
64-18-6
EC Number
200-579-1
Grade
85% For Synthesis
EC Index Number
607-001-00-0
Chemical Formula
CH2O2
HSN Code
29151100
Synonyms
Methanoic acid, Formylic acid
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Preservative, reducing agent, and synthetic intermediate
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Skin Corr. 1A
Classification source
ECHA C&L Inventory via PubChem CID 284 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Corrosive
Signal word
Danger
Hazard statements
H314: Causes severe skin burns and eye damage
2.3 Other hazards
Other hazards
Corrosive to metals, may cause skin burns and eye damage.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Formic Acid
CAS No.
64-18-6
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If breathing is difficult, give oxygen. Seek medical attention.
First-aid measures after skin contact
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.
First-aid measures after eye contact
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth. Seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Irritation of the respiratory tract, skin burns, eye damage.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Vapors may travel long distances to ignition sources and flashback. Vapors in confined areas may explode when exposed to fire.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area. Contain spill and absorb with inert material. Dispose of in accordance with local regulations.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Remove all ignition sources. Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Cautiously neutralize spilled liquid with weak alkaline solution such as disodium carbonate.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use personal protective equipment. Avoid contact with skin and eyes. Use in a fume hood.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Fireproof. Store only in original container. Well closed. Separated from strong oxidants, strong bases, strong acids and food and feedstuffs. See Chemical Dangers. Keep in a well-ventilated room. Store in an area without drain or sewer access.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless
Odour
Pungent, penetrating odor
Odour threshold
Not specified
pH value
Not specified
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
8.3 °C
Freezing point
-8.4 °C
Boiling point
101 °C
Flash point
156 °F (69 °C) (closed cup); 90% soln: 122 °F (50 °C) (closed cup)
Auto-ignition temperature
1004 °F (539 °C); 90% soln: 813 °F (434 °C)
Decomposition temperature
Not specified
Flammability (solid, gas)
Flammable liquid
Vapour pressure
42.59 mm Hg at 25 °C
Relative vapour density at 20°C
1.59 (Air = 1)
Density
1.220 at 20 °C/4 °C
Solubility
Miscible with ether, acetone, ethyl acetate, methanol, ethanol; partially soluble in benzene, toluene, xylenes
Log Pow
-0.54
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Reacts with strong oxidizing agents, bases, and alkali metals.
10.2 Chemical stability
Chemical stability
May deteriorate in normal storage and cause hazard.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
The substance is a medium strong acid. Decomposes on heating. This produces toxic and flammable gases and formaldehyde (see ICSC 0275).
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, strong bases, and alkali metals.
10.6 Hazardous decomposition products
Hazardous decomposition products
The substance decomposes on heating and on contact with strong acids (sulfuric acid) producing carbon monoxide.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Dog oral 4000 mg/kg; LD50 Dog iv 3000 mg/kg; LC50 Mouse inhalation 6200 mgcu m 15 min
Skin corrosion/irritation
H314: Causes severe skin burns and eye damage
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
1779
UN-No. (IMDG)
1779
UN-No. (IATA)
1779
UN-No. (ADN)
1779
UN-No. (RID)
1779
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Formic Acid
Proper Shipping Name (IMDG)
Formic Acid
Proper Shipping Name (IATA)
Formic Acid
Proper Shipping Name (ADN)
Formic Acid
Proper Shipping Name (RID)
Formic Acid
14.3 Transport hazard class(es)
Transport hazard class(es)
8 (3)
14.4 Packing group
Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.