Safety Data Sheet - Formic Acid

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Formic Acid

Product Form Substance

Catalogue No. AL2227

CAS Number 64-18-6

EC Number 200-579-1

EC Index Number 607-001-00-0

Grade 98% For Synthesis

HSN Code 29151100

Molecular Formula CH2O2

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Formic Acid

Catalogue No. AL2227

Product form Substance

CAS Number 64-18-6

EC Number 200-579-1

Grade 98% For Synthesis

EC Index Number 607-001-00-0

Chemical Formula CH2O2

HSN Code 29151100

Synonyms Methanoic acid, Formylic acid

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Used as a reducing agent and synthetic intermediate in organic chemistry.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Skin Corr. 1A

Classification source ECHA C&L Inventory via PubChem CID 284 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Corrosive

Signal word Danger

Hazard statements H314: Causes severe skin burns and eye damage

2.3 Other hazards

Other hazards Corrosive to metals; may cause skin burns and eye damage.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Formic Acid

CAS No. 64-18-6

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If symptoms persist, seek medical attention.

First-aid measures after skin contact IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.

First-aid measures after eye contact First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.

First-aid measures after ingestion Rinse mouth. Do NOT induce vomiting. Seek medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Burning sensation, coughing, shortness of breath, redness, and pain in case of skin contact.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Vapors may travel long distances to ignition sources and flashback. Vapors in confined areas may explode when exposed to fire.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and ventilate. Contain spill and absorb with inert material.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Remove all ignition sources. Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Cautiously neutralize spilled liquid with weak alkaline solution such as disodium carbonate.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Use personal protective equipment. Avoid contact with skin and eyes. Use in a fume hood.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Fireproof. Store only in original container. Well closed. Separated from strong oxidants, strong bases, strong acids and food and feedstuffs. See Chemical Dangers. Keep in a well-ventilated room. Store in an area without drain or sewer access.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless

Odour Pungent, penetrating odor

Odour threshold 0.5 ppm

pH value 2.0

Relative evaporation rate (butylacetate=1) 0.5

Melting point 8.3 °C

Freezing point -8 °C

Boiling point 101 °C

Flash point 156 °F (69 °C) (closed cup); 90% soln: 122 °F (50 °C) (closed cup)

Auto-ignition temperature 1004 °F (539 °C); 90% soln: 813 °F (434 °C)

Decomposition temperature > 200 °C

Flammability (solid, gas) Flammable liquid

Vapour pressure 42.59 mm Hg at 25 °C

Relative vapour density at 20°C 1.59 (Air = 1)

Density 1.220 at 20 °C/4 °C

Solubility Miscible with ether, acetone, ethyl acetate, methanol, ethanol; partially soluble in benzene, toluene, xylenes

Log Pow -0.54

Viscosity, kinematic 1.2 cSt at 20 °C

Viscosity, dynamic 1.5 mPa·s at 20 °C

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits 2.0 - 19.0% (v/v) in air

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Reacts with strong oxidizing agents and bases.

10.2 Chemical stability

Chemical stability May deteriorate in normal storage and cause hazard.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions The substance is a medium strong acid. Decomposes on heating. This produces toxic and flammable gases and formaldehyde (see ICSC 0275).

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizers, strong bases, and alkali metals.

10.6 Hazardous decomposition products

Hazardous decomposition products The substance decomposes on heating and on contact with strong acids (sulfuric acid) producing carbon monoxide.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Dog oral 4000 mg/kg; LD50 Dog iv 3000 mg/kg; LC50 Mouse inhalation 6200 mgcu m 15 min

Skin corrosion/irritation H314: Causes severe skin burns and eye damage

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) 1779

UN-No. (IMDG) 1779

UN-No. (IATA) 1779

UN-No. (ADN) 1779

UN-No. (RID) 1779

14.2 UN proper shipping name

Proper Shipping Name (ADR) Formic Acid

Proper Shipping Name (IMDG) Formic Acid

Proper Shipping Name (IATA) Formic Acid

Proper Shipping Name (ADN) Formic Acid

Proper Shipping Name (RID) Formic Acid

14.3 Transport hazard class(es)

Transport hazard class(es) 8 (3)

14.4 Packing group

Packing group (ADR) II

Packing group (IMDG) II

Packing group (IATA) II

Packing group (ADN) II

Packing group (RID) II

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.