Hypophosphorous Acid
Synonyms: Phosphinic acid
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Hypophosphorous Acid
Product Form
Substance
Catalogue No.
AL2529
CAS Number
6303-21-5
EC Number
228-601-5
EC Index Number
phosphinic acid
Grade
30-32%
HSN Code
28111920
Molecular Formula
HPH2O2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Hypophosphorous Acid
Catalogue No.
AL2529
Product form
Substance
CAS Number
6303-21-5
EC Number
228-601-5
Grade
30-32%
EC Index Number
phosphinic acid
Chemical Formula
HPH2O2
HSN Code
28111920
Synonyms
Phosphinic acid
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Reducing agent, catalyst in organic synthesis
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Skin Corr. 1; Eye Dam. 1
Classification source
ECHA C&L Inventory via PubChem CID 4124402 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Corrosive
Signal word
Danger
Hazard statements
H314: Causes severe skin burns and eye damage; H318: Causes serious eye damage
2.3 Other hazards
Other hazards
Corrosive to metals
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Hypophosphorous Acid
CAS No.
6303-21-5
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with plenty of soap and water. Seek medical attention if irritation develops.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention.
First-aid measures after ingestion
Rinse mouth. Do NOT induce vomiting. Seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Burning sensation, redness, and pain on contact with skin or eyes.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
May emit toxic fumes under fire conditions.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Contain spill and absorb with inert material. Dispose of in accordance with local regulations.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Neutralize with a weak base and absorb with inert material.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use personal protective equipment. Avoid contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Handle with gloves.
Eye protection
Tightly fitting safety goggles. Faceshield (8-inch minimum).
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use in a well-ventilated area. If exposure limits are exceeded, use appropriate respiratory protection.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless to pale yellow
Odour
Slightly pungent
Odour threshold
No data available
pH value
1.5-2.0 (1% solution)
Relative evaporation rate (butylacetate=1)
No data available
Melting point
26.5 °C
Freezing point
No data available
Boiling point
Decomposes upon heating >133 °C
Flash point
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Flammability (solid, gas)
Not flammable
Vapour pressure
0.00323 mmg Hg at 25 °C (effusion method: vapor pressure balance)
Relative vapour density at 20°C
No data available
Density
Marketed in aqueous solutions of varying concentrations, 50% (density 1.274), 30-32% (density 1.13), 10% (density 1.04)
Solubility
Miscible with water
Log Pow
No data available
Viscosity, kinematic
No data available
Viscosity, dynamic
No data available
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Reacts with strong oxidizers and bases.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizing agents, strong bases, metals.
10.6 Hazardous decomposition products
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions - Oxides of phosphorus.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 (oral, rat) 2000 mg/kg
Skin corrosion/irritation
H314: Causes severe skin burns and eye damage
Serious eye damage/irritation
H318: Causes serious eye damage
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 3264
UN-No. (IMDG)
UN 3264
UN-No. (IATA)
UN 3264
UN-No. (ADN)
UN 3264
UN-No. (RID)
UN 3264
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Hypophosphorous acid
Proper Shipping Name (IMDG)
Hypophosphorous acid
Proper Shipping Name (IATA)
Hypophosphorous acid
Proper Shipping Name (ADN)
Hypophosphorous acid
Proper Shipping Name (RID)
Hypophosphorous acid
14.3 Transport hazard class(es)
Transport hazard class(es)
8
14.4 Packing group
Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.