Safety Data Sheet

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Iodine

Product Form Substance

Catalogue No. AL2570

CAS Number 7553-56-2

EC Number 231-442-4

EC Index Number Iodine

Grade 98.5% (resublimed)

HSN Code 28012000

Molecular Formula I2

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Iodine

Catalogue No. AL2570

Product form Substance

CAS Number 7553-56-2

EC Number 231-442-4

Grade 98.5% (resublimed)

EC Index Number Iodine

Chemical Formula I2

HSN Code 28012000

Synonyms Iodine crystals, I2

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Used as an oxidizing agent, antiseptic, and analytical titrant.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Acute Tox. 4; Skin Irrit. 2; Aquatic Acute 1

Classification source ECHA C&L Inventory via PubChem CID 807 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Irritant, Environmental Hazard

Signal word Warning

Hazard statements H312: Harmful in contact with skin; H315: Causes skin irritation; H332: Harmful if inhaled; H400: Very toxic to aquatic life

2.3 Other hazards

Other hazards May cause respiratory irritation; may be harmful if swallowed or inhaled.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Iodine

CAS No. 7553-56-2

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.

First-aid measures after eye contact If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion If this chemical has been swallowed, get medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Irritation of the respiratory tract, skin, and eyes; potential for systemic toxicity.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures The substance readily sublimes.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and ventilate. Wear appropriate protective equipment.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: filter respirator for inorganic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Do NOT absorb in saw-dust or other combustible absorbents. Sweep spilled substance into covered sealable containers.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Handle in a fume hood with gloves and eye protection; avoid inhalation and contact with skin.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Separated from incompatible materials. See Chemical Dangers. Well closed. Ventilation along the floor.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Solid

Colour Dark violet-black

Odour Sharp characteristic odor.

Odour threshold Not specified

pH value Not applicable

Relative evaporation rate (butylacetate=1) Not specified

Melting point 113.7 °C

Freezing point Not specified

Boiling point 184.4 °C

Flash point Not applicable

Auto-ignition temperature Not applicable

Decomposition temperature Not specified

Flammability (solid, gas) Not flammable

Vapour pressure 2.33X10-1 mm Hg at 25 °C

Relative vapour density at 20°C 6.75 g/L at 101.3 MPa, 185 °C

Density Sp gr = 4.93 (solid at 20 °C); density of the gas: 11.27 g/L

Solubility Dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide to form purple solns.

Log Pow 2.49

Viscosity, kinematic Not applicable

Viscosity, dynamic Not applicable

Explosive properties Not explosive

Oxidising properties Strong oxidizer

Explosive limits Not applicable

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Reacts with reducing agents and organic materials; may release toxic fumes when heated.

10.2 Chemical stability

Chemical stability Readily sublimes at room temperature, forming violet corrosive vapor.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on heating. This produces toxic fumes. The substance is a strong oxidant.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong reducing agents, alkalis, and organic materials.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomposition it emits toxic fumes of hydrogen iodide and various iodine compounds.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 14 g/kg; LD50 Mouse oral 22 g/kg; LD50 Rabbit oral 10 g/kg

Skin corrosion/irritation H315: Causes skin irritation

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 3495

UN-No. (IMDG) UN 3495

UN-No. (IATA) UN 3495

UN-No. (ADN) UN 3495

UN-No. (RID) UN 3495

14.2 UN proper shipping name

Proper Shipping Name (ADR) Iodine

Proper Shipping Name (IMDG) Iodine

Proper Shipping Name (IATA) Iodine

Proper Shipping Name (ADN) Iodine

Proper Shipping Name (RID) Iodine

14.3 Transport hazard class(es)

Transport hazard class(es) 8 (6.1)

14.4 Packing group

Packing group (ADR) III

Packing group (IMDG) III

Packing group (IATA) III

Packing group (ADN) III

Packing group (RID) III

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.