Iodine

Synonyms: Iodine crystals, resublimed iodine

SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name Iodine
Product Form Substance
Catalogue No. AL2571
CAS Number 7553-56-2
EC Number 231-442-4
EC Index Number 053-001-00-3
Grade AR grade
HSN Code 28012000
Molecular Formula I2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name Iodine
Catalogue No. AL2571
Product form Substance
CAS Number 7553-56-2
EC Number 231-442-4
Grade AR grade
EC Index Number 053-001-00-3
Chemical Formula I2
HSN Code 28012000
Synonyms Iodine crystals, resublimed iodine
Chemical Structure -
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture Analytical reagent, disinfectant, and antiseptic.
Uses advised against Not specified
1.3 Details of the supplier of the safety data sheet
Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 Acute Tox. 4; Skin Irrit. 2; Aquatic Acute 1
Classification source ECHA C&L Inventory via PubChem CID 807 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms Irritant, Environmental Hazard
Signal word Warning
Hazard statements H312: Harmful in contact with skin; H315: Causes skin irritation; H332: Harmful if inhaled; H400: Very toxic to aquatic life
2.3 Other hazards
Other hazards May cause respiratory irritation; may be harmful if inhaled.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name Iodine
CAS No. 7553-56-2
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.
First-aid measures after eye contact If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion If this chemical has been swallowed, get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use Irritation of the respiratory tract, skin, and eyes; potential for systemic toxicity with high exposure.
4.3 Indication of any immediate medical attention and special treatment needed
General information Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures The substance readily sublimes.
5.3 Advice for firefighters
Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures Evacuate area. Wear appropriate protective equipment. Contain and collect spillage.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up Personal protection: filter respirator for inorganic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Do NOT absorb in saw-dust or other combustible absorbents. Sweep spilled substance into covered sealable containers.
6.4 Reference to other sections
Reference Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling Handle in a fume hood. Use gloves and eye protection. Avoid inhalation and contact with skin.
Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions Separated from incompatible materials. See Chemical Dangers. Well closed. Ventilation along the floor.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection Protective gloves (e.g. nitrile rubber)
Eye protection Chemical safety goggles or safety glasses
Skin and body protection Wear suitable protective clothing
Respiratory protection Use a NIOSH-approved respirator if exposure limits are exceeded.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state Solid
Colour Dark violet-black
Odour Sharp characteristic odor.
Odour threshold No data available
pH value No data available
Relative evaporation rate (butylacetate=1) No data available
Melting point 113.7 °C
Freezing point No data available
Boiling point 184.4 °C
Flash point No data available
Auto-ignition temperature No data available
Decomposition temperature No data available
Flammability (solid, gas) Not flammable
Vapour pressure 2.33X10-1 mm Hg at 25 °C
Relative vapour density at 20°C 6.75 g/L at 101.3 MPa, 185 °C
Density Sp gr = 4.93 (solid at 20 °C); density of the gas: 11.27 g/L
Solubility Dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide to form purple solns.
Log Pow 2.49
Viscosity, kinematic No data available
Viscosity, dynamic No data available
Explosive properties Not explosive
Oxidising properties Strong oxidizer
Explosive limits No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity Reacts with reducing agents and organic materials.
10.2 Chemical stability
Chemical stability Readily sublimes at room temperature, forming violet corrosive vapor.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions Decomposes on heating. This produces toxic fumes. The substance is a strong oxidant.
10.4 Conditions to avoid
Conditions to avoid Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials Strong reducing agents, alkalis, and organic materials.
10.6 Hazardous decomposition products
Hazardous decomposition products When heated to decomposition it emits toxic fumes of hydrogen iodide and various iodine compounds.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity LD50 Rat oral 14 g/kg; LD50 Mouse oral 22 g/kg; LD50 Rabbit oral 10 g/kg
Skin corrosion/irritation H315: Causes skin irritation
Serious eye damage/irritation Not classified (based on available data)
Respiratory or skin sensitisation Not classified (based on available data)
Germ cell mutagenicity Not classified (based on available data)
Carcinogenicity Not classified (based on available data)
Specific target organ toxicity (single exposure) Not classified (based on available data)
Specific target organ toxicity (repeated exposure) Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information Not specified
12.2 Persistence - degradability
Persistence - degradability Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential Not specified
12.4 Mobility in soil
Mobility in soil Not specified
12.6 Other adverse effects
Environmental precautions Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR) 3495
UN-No. (IMDG) 3495
UN-No. (IATA) 3495
UN-No. (ADN) 3495
UN-No. (RID) 3495
14.2 UN proper shipping name
Proper Shipping Name (ADR) Iodine
Proper Shipping Name (IMDG) Iodine
Proper Shipping Name (IATA) Iodine
Proper Shipping Name (ADN) Iodine
Proper Shipping Name (RID) Iodine
14.3 Transport hazard class(es)
Transport hazard class(es) 8 (6.1)
14.4 Packing group
Packing group (ADR) III
Packing group (IMDG) III
Packing group (IATA) III
Packing group (ADN) III
Packing group (RID) III
14.5 Environmental hazards
Dangerous for the environment Not specified
Marine pollutant Not specified
Other information No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations Not specified
SECTION 16: Other Information
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.