Safety Data Sheet - D-(+)-Limonene

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name D-(+)-Limonene

Product Form Substance

Catalogue No. AL2742A

CAS Number 5989-27-5

EC Number 227-813-5

EC Index Number 601-029-00-7

Grade For Synthesis

HSN Code 29021900

Molecular Formula C10H16

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name D-(+)-Limonene

Catalogue No. AL2742A

Product form Substance

CAS Number 5989-27-5

EC Number 227-813-5

Grade For Synthesis

EC Index Number 601-029-00-7

Chemical Formula C10H16

HSN Code 29021900

Synonyms Limonene, D-Limonene

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Fragrance and solvent in cleaning products

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Flam. Liq. 3; Skin Irrit. 2; Skin Sens. 1B; Aquatic Acute 1; Aquatic Chronic 1

Classification source ECHA C&L Inventory via PubChem CID 440917 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Flammable, Irritant, Environmental Hazard

Signal word Warning

Hazard statements H226: Flammable liquid and vapor; H315: Causes skin irritation; H317: May cause an allergic skin reaction; H400: Very toxic to aquatic life; H410: Very toxic to aquatic life with long lasting effects

2.3 Other hazards

Other hazards May cause skin irritation and sensitization.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name D-(+)-Limonene

CAS No. 5989-27-5

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If symptoms persist, seek medical attention.

First-aid measures after skin contact IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.

First-aid measures after eye contact First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.

First-aid measures after ingestion Do not induce vomiting. Rinse mouth and seek medical attention.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Headache, dizziness, skin irritation, respiratory irritation.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Flammable liquid; may produce toxic fumes in a fire.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and eliminate all ignition sources. Contain spill and absorb with inert material.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Avoid contact with skin and eyes. Use in a well-ventilated area.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Fireproof. Separated from strong oxidants. Store in an area without drain or sewer access.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless to pale yellow

Odour Citrus odor

Odour threshold Not specified

pH value Not applicable

Relative evaporation rate (butylacetate=1) Not specified

Melting point -74 °C

Freezing point Not specified

Boiling point 177.6 °C

Flash point 48 °C (closed cup)

Auto-ignition temperature 237 °C

Decomposition temperature Not specified

Flammability (solid, gas) Flammable liquid

Vapour pressure 1.98 mm Hg at 25 °C

Relative vapour density at 20°C 4.7 (Air = 1)

Density 0.8411 at 20 °C

Solubility In water, 13.8 mg/L at 25 °C

Log Pow 4.57

Viscosity, kinematic Not specified

Viscosity, dynamic Not specified

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits 0.7 - 6.1 vol%

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions, but may react with strong oxidizing agents.

10.2 Chemical stability

Chemical stability Oxidizes to a film in air, oxidation behavior similar to that of rubber or drying oils.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Reacts violently with a mixture of iodine pentafluoride and tetrafluoroethylene. This generates fire and explosion hazard. Reacts with oxidants.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizing agents, strong acids.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomp it emits acrid smoke and fumes.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 5 g/kg bw; LD50 Mouse oral 5.6-6.6 g/kg; LD50 Mouse ip 1.3 g/kg

Skin corrosion/irritation H315: Causes skin irritation

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation H317: May cause an allergic skin reaction

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) 2052

UN-No. (IMDG) 2052

UN-No. (IATA) 2052

UN-No. (ADN) 2052

UN-No. (RID) 2052

14.2 UN proper shipping name

Proper Shipping Name (ADR) Limonene

Proper Shipping Name (IMDG) Limonene

Proper Shipping Name (IATA) Limonene

Proper Shipping Name (ADN) Limonene

Proper Shipping Name (RID) Limonene

14.3 Transport hazard class(es)

Transport hazard class(es) 3

14.4 Packing group

Packing group (ADR) III

Packing group (IMDG) III

Packing group (IATA) III

Packing group (ADN) III

Packing group (RID) III

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.