Lithium
Synonyms: Lithium metal
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Lithium
Product Form
Substance
Catalogue No.
AL2753
CAS Number
7439-93-2
EC Number
231-102-5
EC Index Number
Lithium, metal
Grade
99% coated
HSN Code
28051900
Molecular Formula
Li
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Lithium
Catalogue No.
AL2753
Product form
Substance
CAS Number
7439-93-2
EC Number
231-102-5
Grade
99% coated
EC Index Number
Lithium, metal
Chemical Formula
Li
HSN Code
28051900
Synonyms
Lithium metal
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used in batteries and organolithium reagents.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Water-react. 1; Skin Corr. 1B
Classification source
ECHA C&L Inventory via PubChem CID 3028194 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Flammable, Corrosive
Signal word
Danger
Hazard statements
H260: In contact with water releases flammable gases which may ignite spontaneously; H314: Causes severe skin burns and eye damage
2.3 Other hazards
Other hazards
Reacts violently with water, producing flammable hydrogen gas.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Lithium
CAS No.
7439-93-2
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. Seek medical attention if symptoms persist.
First-aid measures after skin contact
Wash with soap and water. Seek medical attention if irritation occurs.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Irritation of skin, eyes, and respiratory tract; potential burns.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Corrosive Water reactive Evolves hydrogen and ignites on contact with water.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area. Use appropriate protective equipment. Contain spill and prevent entry into waterways.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Personal protection: complete protective clothing including self-contained breathing apparatus. Consult an expert! Do NOT wash away into sewer. Sweep spilled substance into covered dry, metallic, sealable containers. Carefully collect remainder.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Handle under inert atmosphere. Use appropriate PPE including gloves and goggles.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Fireproof. Separated from strong oxidants, acids, halons and other incompatible materials. See Chemical Dangers. Dry. Keep under mineral oil.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use a respirator if exposure limits are exceeded or if irritation occurs.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Solid
Colour
Silvery-white
Odour
ODORLESS
Odour threshold
Not applicable
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
180.54 °C
Freezing point
Not applicable
Boiling point
1342 °C
Flash point
Not applicable
Auto-ignition temperature
179 °C
Decomposition temperature
Not applicable
Flammability (solid, gas)
Flammable
Vapour pressure
Not applicable
Relative vapour density at 20°C
Not applicable
Density
0.534 g/cu cm at 25 °C
Solubility
Reacts with water
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive
Oxidising properties
Not oxidising
Explosive limits
Not applicable
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Highly reactive, especially with water and moisture.
10.2 Chemical stability
Chemical stability
Decomposes in water.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Heating may cause violent combustion or explosion. The substance , when finely dispersed, may ignite spontaneously on contact with air. Upon heating, toxic fumes are formed.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Water, acids, halogens, oxidizing agents.
10.6 Hazardous decomposition products
Hazardous decomposition products
Not specified
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Low toxicity; however, can cause burns and irritation.
Skin corrosion/irritation
H314: Causes severe skin burns and eye damage
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
1415
UN-No. (IMDG)
1415
UN-No. (IATA)
1415
UN-No. (ADN)
1415
UN-No. (RID)
1415
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Lithium, metal
Proper Shipping Name (IMDG)
Lithium, metal
Proper Shipping Name (IATA)
Lithium, metal
Proper Shipping Name (ADN)
Lithium, metal
Proper Shipping Name (RID)
Lithium, metal
14.3 Transport hazard class(es)
Transport hazard class(es)
4.3
14.4 Packing group
Packing group (ADR)
I
Packing group (IMDG)
I
Packing group (IATA)
I
Packing group (ADN)
I
Packing group (RID)
I
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.