Methacrylic Acid
Synonyms: 2-Methylprop-2-enoic acid
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Methacrylic Acid
Product Form
Substance
Catalogue No.
AL2974
CAS Number
79-41-4
EC Number
201-204-4
EC Index Number
607-095-00-7
Grade
99% For Synthesis
HSN Code
29161310
Molecular Formula
C4H6O2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Methacrylic Acid
Catalogue No.
AL2974
Product form
Substance
CAS Number
79-41-4
EC Number
201-204-4
Grade
99% For Synthesis
EC Index Number
607-095-00-7
Chemical Formula
C4H6O2
HSN Code
29161310
Synonyms
2-Methylprop-2-enoic acid
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used in the synthesis of polymers and resins.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute Tox. 4; Acute Tox. 3; Skin Corr. 1A; Eye Dam. 1; STOT SE 3
Classification source
ECHA C&L Inventory via PubChem CID 4093 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Corrosive, Acute Toxic
Signal word
Danger
Hazard statements
H302: Harmful if swallowed; H311: Toxic in contact with skin; H314: Causes severe skin burns and eye damage; H318: Causes serious eye damage; H332: Harmful if inhaled; H335: May cause respiratory irritation
2.3 Other hazards
Other hazards
Corrosive to metals.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Methacrylic Acid
CAS No.
79-41-4
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.
First-aid measures after eye contact
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Burning sensation, redness, and pain in contact areas.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Vapours are uninhibited and may polymerize, causing blockage of vents.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and ventilate. Wear appropriate protective equipment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Personal protection: complete protective clothing including self-contained breathing apparatus. Collect leaking and spilled liquid in sealable plastic containers as far as possible. Cautiously neutralize remainder with aqueous sodium carbonate or lime. Then wash away with plenty of water.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use gloves and goggles. Handle in a fume hood.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Separated from strong oxidants and food and feedstuffs. Cool. Keep in the dark. Keep in a well-ventilated room. Store only if stabilized. Store only in original container.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless
Odour
Acrid, repulsive odor
Odour threshold
Not specified
pH value
Not specified
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
16 °C
Freezing point
Not specified
Boiling point
163 °C at 760 mm Hg
Flash point
77 °C
Auto-ignition temperature
752 °F (400 °C)
Decomposition temperature
Not specified
Flammability (solid, gas)
Not flammable
Vapour pressure
0.65 mmHg at 68 °F ; 1 mmHg at 77 °F
Relative vapour density at 20°C
2.97 (Air = 1)
Density
1.0153 at 20 °C/4 °C
Solubility
Soluble in chloroform; miscible with ethanol, ether
Log Pow
0.93
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Reacts with strong oxidizing agents and bases.
10.2 Chemical stability
Chemical stability
Acrylic acid and methacrylic acid readily polymerize in the presence of light, heat and oxygen, and also under the action of oxidizing agents such as peroxides.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
The substance is a medium strong acid. The substance readily polymerizes due to heating or under the influence of light, oxidizing agents such as peroxides, or in the presence of traces of hydrochloric acid. This generates fire or explosion hazard.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, bases, and amines.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomposition it emits acrid smoke and irritating fumes.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 1060 mg/kg; LD50 MOUSE ORAL 1250 MG/KG; LD50 Mouse ip 48 mg/kg
Skin corrosion/irritation
H314: Causes severe skin burns and eye damage
Serious eye damage/irritation
H318: Causes serious eye damage
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
H335: May cause respiratory irritation
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 2531
UN-No. (IMDG)
UN 2531
UN-No. (IATA)
UN 2531
UN-No. (ADN)
UN 2531
UN-No. (RID)
UN 2531
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Methacrylic Acid
Proper Shipping Name (IMDG)
Methacrylic Acid
Proper Shipping Name (IATA)
Methacrylic Acid
Proper Shipping Name (ADN)
Methacrylic Acid
Proper Shipping Name (RID)
Methacrylic Acid
14.3 Transport hazard class(es)
Transport hazard class(es)
8
14.4 Packing group
Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.