Methyl Acrylate
Synonyms: Acrylic acid methyl ester, Methacrylic acid methyl ester
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Methyl Acrylate
Product Form
Substance
Catalogue No.
AL3014
CAS Number
96-33-3
EC Number
202-500-6
EC Index Number
607-036-00-7
Grade
99%
HSN Code
29161400
Molecular Formula
C4H6O2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Methyl Acrylate
Catalogue No.
AL3014
Product form
Substance
CAS Number
96-33-3
EC Number
202-500-6
Grade
99%
EC Index Number
607-036-00-7
Chemical Formula
C4H6O2
HSN Code
29161400
Synonyms
Acrylic acid methyl ester, Methacrylic acid methyl ester
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used as a monomer in the production of polymers and adhesives.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flam. Liq. 2; Acute Tox. 4; Skin Irrit. 2; Skin Sens. 1; Eye Irrit. 2A; Acute Tox. 3; STOT SE 3
Classification source
ECHA C&L Inventory via PubChem CID 7294 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Flammable, Acute Toxic
Signal word
Danger
Hazard statements
H225: Highly Flammable liquid and vapor; H302: Harmful if swallowed; H312: Harmful in contact with skin; H315: Causes skin irritation; H317: May cause an allergic skin reaction; H319: Causes serious eye irritation; H331: Toxic if inhaled; H335: May cause respiratory irritation
2.3 Other hazards
Other hazards
May cause respiratory irritation and skin sensitization.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Methyl Acrylate
CAS No.
96-33-3
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact
If this chemical contacts the skin, immediately flush the contaminated skin with water. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water. Get medical attention promptly.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Irritation of eyes, skin, and respiratory tract; headache; dizziness.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Vapors are heavier than air and may travel to a source of ignition and flash back. Liquid floats on water and may travel to a source of ignition and spread fire.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area. Remove all sources of ignition. Ventilate area.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Remove all ignition sources. Collect leaking and spilled liquid in covered containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use in a well-ventilated area. Avoid contact with skin and eyes. Keep away from heat and ignition sources.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Fireproof. See Chemical Dangers. Cooled. Keep in the dark. Well closed. Store only if stabilized.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166 (EU).
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless
Odour
Acrid odor
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
-75.6 °C
Freezing point
Not specified
Boiling point
80.1 °C
Flash point
-3 °C (27 °F) - closed cup
Auto-ignition temperature
875 °F (468 °C)
Decomposition temperature
Not specified
Flammability (solid, gas)
Flammable liquid
Vapour pressure
VP: 65 Torr at 20 °C
Relative vapour density at 20°C
2.97 (Air = 1)
Density
0.9535 g/cu cm at 20 °C
Solubility
In water, 4.94X10+4 mg/L at 25 °C
Log Pow
0.80
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Lower: 2.1 vol%, Upper: 12.5 vol%
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Reacts with strong oxidizing agents and bases.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions. Contains the following stabilizer(s): Mequinol (<=0.01 %).
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
The substance may spontaneously polymerize due to warming, under the influence of light and on contact with peroxides. Reacts violently with strong acids, strong bases and strong oxidants. This generates fire and explosion hazard.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, strong bases, and amines.
10.6 Hazardous decomposition products
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions: Carbon oxides.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 277 mg/kg; LD50 Rat oral 300 mg/kg; LD50 Rat ip 325 mg/kg
Skin corrosion/irritation
H315: Causes skin irritation
Serious eye damage/irritation
H319: Causes serious eye irritation
Respiratory or skin sensitisation
H317: May cause an allergic skin reaction
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
H335: May cause respiratory irritation
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 1919
UN-No. (IMDG)
UN 1919
UN-No. (IATA)
UN 1919
UN-No. (ADN)
UN 1919
UN-No. (RID)
UN 1919
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Methyl acrylate
Proper Shipping Name (IMDG)
Methyl acrylate
Proper Shipping Name (IATA)
Methyl acrylate
Proper Shipping Name (ADN)
Methyl acrylate
Proper Shipping Name (RID)
Methyl acrylate
14.3 Transport hazard class(es)
Transport hazard class(es)
3
14.4 Packing group
Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.