Methyl Chloroacetate
Synonyms: Chloroacetic acid methyl ester
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Methyl Chloroacetate
Product Form
Substance
Catalogue No.
AL3042
CAS Number
96-34-4
EC Number
202-501-1
EC Index Number
607-007-00-4
Grade
99% (mono)
HSN Code
29154010
Molecular Formula
C3H5ClO2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Methyl Chloroacetate
Catalogue No.
AL3042
Product form
Substance
CAS Number
96-34-4
EC Number
202-501-1
Grade
99% (mono)
EC Index Number
607-007-00-4
Chemical Formula
C3H5ClO2
HSN Code
29154010
Synonyms
Chloroacetic acid methyl ester
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Alkylating agent and synthetic intermediate in organic synthesis.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flam. Liq. 3; Acute Tox. 3; Acute Tox. 2; Skin Irrit. 2; Skin Sens. 1; Eye Dam. 1; STOT SE 3
Classification source
ECHA C&L Inventory via PubChem CID 7295 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Flammable, Corrosive, Acute Toxic
Signal word
Danger
Hazard statements
H226: Flammable liquid and vapor; H301: Toxic if swallowed; H310: Fatal in contact with skin; H315: Causes skin irritation; H317: May cause an allergic skin reaction; H318: Causes serious eye damage; H330: Fatal if inhaled; H335: May cause respiratory irritation
2.3 Other hazards
Other hazards
Lachrymator; may cause respiratory irritation.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Methyl Chloroacetate
CAS No.
96-34-4
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move victim to fresh air. If breathing has stopped, give artificial respiration.
First-aid measures after skin contact
Remove contaminated clothing and shoes. Flush affected areas with water for at least 15 minutes.
First-aid measures after eye contact
Hold eyelids open, flush with running water for at least 15 minutes.
First-aid measures after ingestion
Do nothing except keep victim warm. DO NOT INDUCE VOMITING.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Irritation of eyes, skin, and respiratory tract; headache; nausea.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Advice for firefighters: Wear self-contained breathing apparatus for firefighting if necessary. Further information: Use water spray to cool unopened containers.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
The vapour is heavier than air.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area. Ventilate and contain spill. Use appropriate protective equipment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Remove all ignition sources. Personal protection: chemical protection suit including self-contained breathing apparatus. Collect leaking and spilled liquid in covered plastic containers as far as possible. Absorb remaining liquid in sand or inert absorbent.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use in a fume hood with appropriate PPE including gloves and goggles.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Fireproof. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Handle with gloves.
Eye protection
Tightly fitting safety goggles. Faceshield (8-inch minimum).
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless
Odour
Sweet pungent odor
Odour threshold
Not established
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not established
Melting point
-32.3 °C
Freezing point
Not established
Boiling point
130 °C
Flash point
135 °F (57 °C) (open cup)
Auto-ignition temperature
465 °C
Decomposition temperature
Not established
Flammability (solid, gas)
Flammable liquid
Vapour pressure
7.63 mm Hg at 25 °C
Relative vapour density at 20°C
1.24 (Air = 1)
Density
1.236 g/cu cm at 20 °C
Solubility
In water, 4.6X10+4 mg/L at 20 °C
Log Pow
0.76 (calculated)
Viscosity, kinematic
Not established
Viscosity, dynamic
Not established
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not established
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Reacts with strong oxidizing agents and bases.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Decomposes on burning. This produces corrosive fumes including hydrogen chloride. Reacts with reducing agents and oxidants.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, strong bases, and amines.
10.6 Hazardous decomposition products
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions: Carbon oxides, hydrogen chloride gas.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 140 mg/kg bw; LD50 Mouse oral 240 mg/kg; LC50 Mouse inhalation 1 gcu m2 hr
Skin corrosion/irritation
H315: Causes skin irritation
Serious eye damage/irritation
H318: Causes serious eye damage
Respiratory or skin sensitisation
H317: May cause an allergic skin reaction
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
H335: May cause respiratory irritation
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 2295
UN-No. (IMDG)
UN 2295
UN-No. (IATA)
UN 2295
UN-No. (ADN)
UN 2295
UN-No. (RID)
UN 2295
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Methyl Chloroacetate
Proper Shipping Name (IMDG)
Methyl Chloroacetate
Proper Shipping Name (IATA)
Methyl Chloroacetate
Proper Shipping Name (ADN)
Methyl Chloroacetate
Proper Shipping Name (RID)
Methyl Chloroacetate
14.3 Transport hazard class(es)
Transport hazard class(es)
6.1 (3)
14.4 Packing group
Packing group (ADR)
I
Packing group (IMDG)
I
Packing group (IATA)
I
Packing group (ADN)
I
Packing group (RID)
I
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.