Safety Data Sheet - alpha-Naphthylamine

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name alpha-Naphthylamine

Product Form Substance

Catalogue No. AL3182

CAS Number 134-32-7

EC Number 205-138-7

EC Index Number 612-002-00-7

Grade AR

HSN Code 29214511

Molecular Formula C10H9N

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name alpha-Naphthylamine

Catalogue No. AL3182

Product form Substance

CAS Number 134-32-7

EC Number 205-138-7

Grade AR

EC Index Number 612-002-00-7

Chemical Formula C10H9N

HSN Code 29214511

Synonyms 1-Naphthylamine, 1-Aminonaphthalene

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Intermediate in dye and pharmaceutical synthesis.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Acute Tox. 4; Aquatic Chronic 2

Classification source ECHA C&L Inventory via PubChem CID 8640 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Irritant, Environmental Hazard

Signal word Warning

Hazard statements H302: Harmful if swallowed; H411: Toxic to aquatic life with long lasting effects

2.3 Other hazards

Other hazards Carcinogenic; handle with extreme care.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name alpha-Naphthylamine

CAS No. 134-32-7

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.

First-aid measures after skin contact If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.

First-aid measures after eye contact If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.

First-aid measures after ingestion If this chemical has been swallowed, get medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Headache, dizziness, nausea, skin irritation, respiratory distress.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Toxic fumes may be released in a fire. Use water spray to cool containers.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and ventilate. Wear appropriate protective equipment.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Use personal protective equipment. Avoid contact with skin, eyes, and clothing.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Dry. Keep in the dark. Well closed.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respirator if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Solid

Colour White to pale tan

Odour Ammonia-like odor.

Odour threshold Not specified

pH value Not applicable

Relative evaporation rate (butylacetate=1) Not specified

Melting point 49.2 °C

Freezing point Not specified

Boiling point 300.7 °C

Flash point 157 °C, 315 °F, (closed cup)

Auto-ignition temperature Auto-ignition temperature: 460 °C

Decomposition temperature Not specified

Flammability (solid, gas) Not flammable under normal conditions

Vapour pressure 4.18X10-3 mm Hg @ 25 °C

Relative vapour density at 20°C 4.93 (Air= 1)

Density 1.114 g/cu cm

Solubility Crystal powder; becomes bluish on exposure to air and light. Sol in about 27 parts water; sol in alcohol and ether

Log Pow 2.25

Viscosity, kinematic Not specified

Viscosity, dynamic Not specified

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits Not specified

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions, but may react with strong oxidizing agents.

10.2 Chemical stability

Chemical stability Oxidizes in air.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on burning. This produces nitrogen oxides and carbon monoxide. The substance is a weak base.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizing agents, strong acids.

10.6 Hazardous decomposition products

Hazardous decomposition products The substance decomposes on burning producing nitrogen oxides and carbon monoxide.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 680 mg/kg bw; LC50 Rat inhalation >0.056 mg/L/4 hr; LD50 Rat (female) dermal 447 mg/kg bw

Skin corrosion/irritation Not classified (based on available data)

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) 2077

UN-No. (IMDG) 2077

UN-No. (IATA) 2077

UN-No. (ADN) 2077

UN-No. (RID) 2077

14.2 UN proper shipping name

Proper Shipping Name (ADR) alpha-Naphthylamine

Proper Shipping Name (IMDG) alpha-Naphthylamine

Proper Shipping Name (IATA) alpha-Naphthylamine

Proper Shipping Name (ADN) alpha-Naphthylamine

Proper Shipping Name (RID) alpha-Naphthylamine

14.3 Transport hazard class(es)

Transport hazard class(es) 6.1

14.4 Packing group

Packing group (ADR) III

Packing group (IMDG) III

Packing group (IATA) III

Packing group (ADN) III

Packing group (RID) III

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.