2-Nitroanisole
Synonyms: 2-Nitro-1-methoxybenzene
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
2-Nitroanisole
Product Form
Substance
Catalogue No.
AL3274
CAS Number
91-23-6
EC Number
202-052-1
EC Index Number
609-007-00-0
Grade
98% For Synthesis
HSN Code
29093012
Molecular Formula
C7H7NO3
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
2-Nitroanisole
Catalogue No.
AL3274
Product form
Substance
CAS Number
91-23-6
EC Number
202-052-1
Grade
98% For Synthesis
EC Index Number
609-007-00-0
Chemical Formula
C7H7NO3
HSN Code
29093012
Synonyms
2-Nitro-1-methoxybenzene
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used as a synthetic intermediate in the production of dyes and agrochemicals.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute Tox. 4; Carc. 1B
Classification source
ECHA C&L Inventory via PubChem CID 7048 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Irritant, Health Hazard
Signal word
Danger
Hazard statements
H302: Harmful if swallowed; H350: May cause cancer
Precautionary statements
P203, P264, P270, P280, P301+P317, P318, P330, P405, P501
2.3 Other hazards
Other hazards
Toxic; may cause harm if inhaled or absorbed through the skin.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
2-Nitroanisole
CAS No.
91-23-6
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If breathing is difficult, give oxygen. Seek medical attention if symptoms persist.
First-aid measures after skin contact
Wash with soap and water. Remove contaminated clothing. Seek medical attention if irritation develops.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Seek medical attention if irritation persists.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth. Seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Symptoms of exposure may include headache, dizziness, nausea, and respiratory distress.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for fire-fighters: Wear self contained breathing apparatus for fire fighting if necessary.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
The vapour is heavier than air.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area. Wear appropriate protective equipment. Contain and collect spillage.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Personal protection: chemical protection suit and filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Handle under a fume hood. Use appropriate personal protective equipment, including gloves and goggles.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Well closed. Store only in original packaging. Ventilation along the floor. Dry.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Handle with gloves. Eye protection: Face shield and safety glasses Skin and body protection: Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use a NIOSH-approved respirator if exposure limits are exceeded.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Pale yellow
Odour
Characteristic
Odour threshold
Not specified
pH value
Not specified
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
10.5 °C
Freezing point
Not specified
Boiling point
277 °C; 144 °C at 4 mm Hg
Flash point
142 °C closed cup
Auto-ignition temperature
464 °C
Decomposition temperature
Not specified
Flammability (solid, gas)
Not applicable
Vapour pressure
3.6X10-3 mm Hg at 25 °C
Relative vapour density at 20°C
Relative vapor density (air = 1): 5.29
Density
1.2540 g/cu cm at 20 °C
Solubility
Miscible with ethanol, ethyl ether; soluble in carbon tetrachloride
Log Pow
1.73
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions. Avoid strong oxidizing agents.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
On combustion, forms toxic and corrosive fumes. Reacts violently with zinc and sodium hydroxide.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizing agents, strong acids.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomposition it emits toxic fumes of nitrogen oxide.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 1980 mg/kg; LD50 Rat oral 740 mg/kg; LD50 Rat oral 874 mg/kg bw
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
H350: May cause cancer
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 2730
UN-No. (IMDG)
UN 2730
UN-No. (IATA)
UN 2730
UN-No. (ADN)
UN 2730
UN-No. (RID)
UN 2730
14.2 UN proper shipping name
Proper Shipping Name (ADR)
2-Nitroanisole
Proper Shipping Name (IMDG)
2-Nitroanisole
Proper Shipping Name (IATA)
2-Nitroanisole
Proper Shipping Name (ADN)
2-Nitroanisole
Proper Shipping Name (RID)
2-Nitroanisole
14.3 Transport hazard class(es)
Transport hazard class(es)
6.1
14.4 Packing group
Packing group (ADR)
III
Packing group (IMDG)
III
Packing group (IATA)
III
Packing group (ADN)
III
Packing group (RID)
III
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.