Nitrobenzene
Synonyms: Phenyl nitro, Nitrobenzol
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Nitrobenzene
Product Form
Substance
Catalogue No.
AL3278
CAS Number
98-95-3
EC Number
202-716-0
EC Index Number
611-005-00-9
Grade
98% For Synthesis
HSN Code
29042010
Molecular Formula
C6H5NO2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Nitrobenzene
Catalogue No.
AL3278
Product form
Substance
CAS Number
98-95-3
EC Number
202-716-0
Grade
98% For Synthesis
EC Index Number
611-005-00-9
Chemical Formula
C6H5NO2
HSN Code
29042010
Synonyms
Phenyl nitro, Nitrobenzol
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Precursor in the synthesis of aniline and other organic compounds.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute Tox. 3; Carc. 2; Repr. 1B; STOT RE 1; Aquatic Chronic 3
Classification source
ECHA C&L Inventory via PubChem CID 7416 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Acute Toxic, Health Hazard
Signal word
Danger
Hazard statements
H301: Toxic if swallowed; H311: Toxic in contact with skin; H331: Toxic if inhaled; H351: Suspected of causing cancer; H360: May damage fertility or the unborn child; H372: Causes damage to organs through prolonged or repeated exposure; H412: Harmful to aquatic life with long lasting effects
2.3 Other hazards
Other hazards
Suspected carcinogen, may cause reproductive toxicity.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Nitrobenzene
CAS No.
98-95-3
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact
If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Headache, dizziness, nausea, respiratory distress, skin irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Nitrobenzene is flammable and may produce toxic fumes in a fire.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area. Wear appropriate protective equipment. Contain spill and prevent entry into waterways.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use in a fume hood with appropriate PPE. Avoid contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Separated from combustible substances, reducing agents, strong oxidants, strong acids and food and feedstuffs. Store in an area without drain or sewer access.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use NIOSH-approved respirators if exposure limits are exceeded.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Pale yellow
Odour
Odor of volatile oil almond
Odour threshold
0.5 ppm
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
<1
Melting point
5.7 °C
Freezing point
-5.5 °C
Boiling point
210.8 °C
Flash point
190 °F (88 °C) (Closed cup)
Auto-ignition temperature
900 °F (482 °C)
Decomposition temperature
Not available
Flammability (solid, gas)
Not flammable
Vapour pressure
Vapor pressure: 1 mm Hg at 44.4 °C
Relative vapour density at 20°C
4.25 (Air = 1)
Density
1.2037 g/cu cm at 20 °C
Solubility
Slightly soluble in carbon tetrachloride; very soluble in ethanol, diethyl ether, acetone, benzene
Log Pow
1.85
Viscosity, kinematic
Not available
Viscosity, dynamic
Not available
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not applicable
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions, but reacts with strong oxidizing agents.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
On combustion, forms toxic and corrosive fumes including nitrogen oxides. Reacts violently with strong oxidants and reducing agents. This generates fire and explosion hazard.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, strong acids, bases.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomposition it emits toxic fumes of nitrogen oxides.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 600 mg/kg; LD50 Rat skin 2100 mg/kg
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
H351: Suspected of causing cancer
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
H372: Causes damage to organs through prolonged or repeated exposure
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 1662
UN-No. (IMDG)
UN 1662
UN-No. (IATA)
UN 1662
UN-No. (ADN)
UN 1662
UN-No. (RID)
UN 1662
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Nitrobenzene
Proper Shipping Name (IMDG)
Nitrobenzene
Proper Shipping Name (IATA)
Nitrobenzene
Proper Shipping Name (ADN)
Nitrobenzene
Proper Shipping Name (RID)
Nitrobenzene
14.3 Transport hazard class(es)
Transport hazard class(es)
6.1
14.4 Packing group
Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.