Nitromethane
Synonyms: Methyl nitrite
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Nitromethane
Product Form
Substance
Catalogue No.
AL3294
CAS Number
75-52-5
EC Number
200-876-6
EC Index Number
607-007-00-0
Grade
98% For Synthesis
HSN Code
29042090
Molecular Formula
CH3NO2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Nitromethane
Catalogue No.
AL3294
Product form
Substance
CAS Number
75-52-5
EC Number
200-876-6
Grade
98% For Synthesis
EC Index Number
607-007-00-0
Chemical Formula
CH3NO2
HSN Code
29042090
Synonyms
Methyl nitrite
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Solvent, fuel additive, and synthetic intermediate.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flam. Liq. 3; Acute Tox. 4
Classification source
ECHA C&L Inventory via PubChem CID 6375 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Flammable, Irritant
Signal word
Warning
Hazard statements
H226: Flammable liquid and vapor; H302: Harmful if swallowed
2.3 Other hazards
Other hazards
May form explosive peroxides upon prolonged storage.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Nitromethane
CAS No.
75-52-5
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact
If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing, promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Headache, dizziness, nausea, and respiratory irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Special hazards arising from the substance or mixture: Carbon oxides, nitrogen oxides (NOx).
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and eliminate all ignition sources. Contain spill and absorb with inert material.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Evacuate danger area! Consult an expert! Personal protection: filter respirator for organic gases and particulates adapted to the airborne concentration of the substance. Remove all ignition sources. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Avoid contact with skin and eyes. Use in a well-ventilated area and avoid inhalation of vapors.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Fireproof. Separated from incompatible materials. See Chemical Dangers.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Colorless to pale yellow
Odour
Moderately strong, somewhat disagreeable odor
Odour threshold
No data available
pH value
No data available
Relative evaporation rate (butylacetate=1)
No data available
Melting point
-28.7 °C
Freezing point
-29 °C
Boiling point
101.1 °C
Flash point
95 °F (35 °C) (Closed Cup)
Auto-ignition temperature
785 °F (418 °C)
Decomposition temperature
No data available
Flammability (solid, gas)
Flammable liquid
Vapour pressure
3.58X10+1 mm Hg at 25 °C
Relative vapour density at 20°C
2.11 (Air = 1)
Density
1.1371 g/cu cm at 20 °C
Solubility
Solubility of water in nitromethane: 2.1% at 25 °C
Log Pow
low Kow = -0.35
Viscosity, kinematic
0.9 cSt at 20 °C
Viscosity, dynamic
No data available
Explosive properties
May form explosive mixtures with air under certain conditions
Oxidising properties
Not oxidizing
Explosive limits
Lower: 2.3% vol, Upper: 36% vol
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions; avoid heat, sparks, and open flames.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
May decompose explosively on shock, friction or concussion. May explode on heating. Decomposes on burning.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizing agents, strong acids, and bases.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomposition it emits toxic fumes of nitrogen oxides.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 940 mg/kg; LD50 Mouse oral 950 mg/kg; LD50 Mouse ip 110 mg/kg
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
1261
UN-No. (IMDG)
1261
UN-No. (IATA)
1261
UN-No. (ADN)
1261
UN-No. (RID)
1261
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Nitromethane
Proper Shipping Name (IMDG)
Nitromethane
Proper Shipping Name (IATA)
Nitromethane
Proper Shipping Name (ADN)
Nitromethane
Proper Shipping Name (RID)
Nitromethane
14.3 Transport hazard class(es)
Transport hazard class(es)
3
14.4 Packing group
Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.