m-Nitrotoluene
Synonyms: 3-Nitrotoluene
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
m-Nitrotoluene
Product Form
Substance
Catalogue No.
AL3315
CAS Number
99-08-1
EC Number
202-728-6
EC Index Number
-
Grade
99% For Synthesis
HSN Code
29042090
Molecular Formula
C7H7NO2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
m-Nitrotoluene
Catalogue No.
AL3315
Product form
Substance
CAS Number
99-08-1
EC Number
202-728-6
Grade
99% For Synthesis
EC Index Number
Not specified
Chemical Formula
C7H7NO2
HSN Code
29042090
Synonyms
3-Nitrotoluene
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used as a synthetic intermediate in dye and pharmaceutical chemistry.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute Tox. 3; Aquatic Chronic 2
Classification source
ECHA C&L Inventory via PubChem CID 7422 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Acute Toxic, Environmental Hazard
Signal word
Danger
Hazard statements
H301+H311+H331: Toxic if swallowed, in contact with skin or if inhaled; H301: Toxic if swallowed; H311: Toxic in contact with skin; H331: Toxic if inhaled; H411: Toxic to aquatic life with long lasting effects
2.3 Other hazards
Other hazards
Toxic; may cause harm to the nervous system.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
m-Nitrotoluene
CAS No.
99-08-1
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact
If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Headache, dizziness, nausea, and respiratory distress.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Toxic fumes may be released in a fire. Use water spray to cool containers.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and ventilate. Wear appropriate protective equipment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Evacuate danger area! Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Ventilation. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Handle with gloves and in a fume hood. Avoid contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Separated from strong oxidants, sulfuric acid and food and feedstuffs. Cool. Dry. Keep in a well-ventilated room.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Pale yellow
Odour
Weak, aromatic odor
Odour threshold
Not specified
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not specified
Melting point
15.5 °C
Freezing point
Not specified
Boiling point
232 °C at 760 mm Hg
Flash point
106 °C; 223 °F (Closed cup)
Auto-ignition temperature
Not specified
Decomposition temperature
Not specified
Flammability (solid, gas)
Not applicable
Vapour pressure
Vapor pressure: 1.0 mm Hg at 60 °C
Relative vapour density at 20°C
4.72 (Air = 1)
Density
1.1630 at 20 °C/4 °C
Solubility
In water, 500 mgL at 30 °C; 450 mgL at 20 °C
Log Pow
2.45
Viscosity, kinematic
Not specified
Viscosity, dynamic
Not specified
Explosive properties
Not explosive
Oxidising properties
Not oxidizing
Explosive limits
Not specified
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions. Reacts with strong oxidizing agents.
10.2 Chemical stability
Chemical stability
Heat contributes to instability.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Decomposes on burning. This produces toxic gases including carbon monoxide and nitrogen oxides. Reacts with strong oxidants and sulfuric acid.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, strong acids, and bases.
10.6 Hazardous decomposition products
Hazardous decomposition products
The substance decomposes on burning producing toxic gases, including carbon monoxide and nitrogen oxides.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Mouse oral 1231 mg/kg bw; LD50 Rat (female) oral 1784 mg/kg bw; LC50 Rat inhalation >2.417 mgL 1 hr
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 1664
UN-No. (IMDG)
UN 1664
UN-No. (IATA)
UN 1664
UN-No. (ADN)
UN 1664
UN-No. (RID)
UN 1664
14.2 UN proper shipping name
Proper Shipping Name (ADR)
m-Nitrotoluene
Proper Shipping Name (IMDG)
m-Nitrotoluene
Proper Shipping Name (IATA)
m-Nitrotoluene
Proper Shipping Name (ADN)
m-Nitrotoluene
Proper Shipping Name (RID)
m-Nitrotoluene
14.3 Transport hazard class(es)
Transport hazard class(es)
6.1
14.4 Packing group
Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.