Paraldehyde

Synonyms: 2,4,6-trimethyl-1,3,5-trioxane

SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name Paraldehyde
Product Form Substance
Catalogue No. AL3416
CAS Number 123-63-7
EC Number 204-639-8
EC Index Number 605-001-00-0
Grade 98% For Synthesis
HSN Code 29125000
Molecular Formula C6H12O3
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name Paraldehyde
Catalogue No. AL3416
Product form Substance
CAS Number 123-63-7
EC Number 204-639-8
Grade 98% For Synthesis
EC Index Number 605-001-00-0
Chemical Formula C6H12O3
HSN Code 29125000
Synonyms 2,4,6-trimethyl-1,3,5-trioxane
Chemical Structure -
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture Synthetic intermediate in organic synthesis
Uses advised against Not specified
1.3 Details of the supplier of the safety data sheet
Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 Flam. Liq. 3
Classification source ECHA C&L Inventory via PubChem CID 31264 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms Flammable
Signal word Warning
Hazard statements H226: Flammable liquid and vapor
Precautionary statements P210, P233, P240, P241, P242, P243, P280, P303+P361+P353, P370+P378, P403+P235, P501
2.3 Other hazards
Other hazards May cause respiratory irritation.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name Paraldehyde
CAS No. 123-63-7
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.
First-aid measures after eye contact First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
First-aid measures after ingestion Do not induce vomiting. Rinse mouth and seek medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use Headache, dizziness, nausea, and irritation of the respiratory tract.
4.3 Indication of any immediate medical attention and special treatment needed
General information Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures Vapors are heavier than air and may travel to a source of ignition and flash back.
5.3 Advice for firefighters
Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures Evacuate area and eliminate all ignition sources. Use appropriate protective equipment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up Remove all ignition sources. Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking and spilled liquid in sealable non-plastic containers as far as possible. Absorb remaining liquid in sand or inert absorbent.
6.4 Reference to other sections
Reference Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling Avoid contact with skin and eyes. Use in a well-ventilated area.
Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions Fireproof. Separated from food and feedstuffs, bases and oxidants.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection Protective gloves (e.g. nitrile rubber)
Eye protection Chemical safety goggles or safety glasses
Skin and body protection Wear suitable protective clothing
Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state Liquid
Colour Colorless
Odour Agreeable odor
Odour threshold Not specified
pH value Not specified
Relative evaporation rate (butylacetate=1) Not specified
Melting point 12.6 °C
Freezing point Not specified
Boiling point 124.5 °C
Flash point 24 °C c.c.
Auto-ignition temperature 235 °C
Decomposition temperature Not specified
Flammability (solid, gas) Flammable liquid
Vapour pressure 25.3 mm Hg at 20 °C
Relative vapour density at 20°C 4.5
Density 0.9923 @ 20 °C/4 °C
Solubility Sparingly soluble
Log Pow Log Kow = 0.67
Viscosity, kinematic Not specified
Viscosity, dynamic Not specified
Explosive properties Not explosive
Oxidising properties Not oxidizing
Explosive limits Not specified
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity Stable under normal conditions, but may react with strong oxidizing agents.
10.2 Chemical stability
Chemical stability Preparations of paraldehyde that have a brownish color or a sharp penetrating odor of acetic acid should not be used.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions Decomposes on heating. This produces toxic fumes. Decomposes under the influence of air and light.
10.4 Conditions to avoid
Conditions to avoid Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials Strong oxidizing agents, acids, and bases.
10.6 Hazardous decomposition products
Hazardous decomposition products Not specified
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity LD50 Dog oral (acute) 3.0 to 4.0 g/kg
Skin corrosion/irritation Not classified (based on available data)
Serious eye damage/irritation Not classified (based on available data)
Respiratory or skin sensitisation Not classified (based on available data)
Germ cell mutagenicity Not classified (based on available data)
Carcinogenicity Not classified (based on available data)
Specific target organ toxicity (single exposure) Not classified (based on available data)
Specific target organ toxicity (repeated exposure) Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information Not specified
12.2 Persistence - degradability
Persistence - degradability Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential Not specified
12.4 Mobility in soil
Mobility in soil Not specified
12.6 Other adverse effects
Environmental precautions Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR) 1264
UN-No. (IMDG) 1264
UN-No. (IATA) 1264
UN-No. (ADN) 1264
UN-No. (RID) 1264
14.2 UN proper shipping name
Proper Shipping Name (ADR) Paraldehyde
Proper Shipping Name (IMDG) Paraldehyde
Proper Shipping Name (IATA) Paraldehyde
Proper Shipping Name (ADN) Paraldehyde
Proper Shipping Name (RID) Paraldehyde
14.3 Transport hazard class(es)
Transport hazard class(es) 3
14.4 Packing group
Packing group (ADR) III
Packing group (IMDG) III
Packing group (IATA) III
Packing group (ADN) III
Packing group (RID) III
14.5 Environmental hazards
Dangerous for the environment Not specified
Marine pollutant Not specified
Other information No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations Not specified
SECTION 16: Other Information
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.