Safety Data Sheet - Perchloroethylene

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Perchloroethylene

Product Form Substance

Catalogue No. AL3450

CAS Number 127-18-4

EC Number 204-825-9

EC Index Number 602-004-00-3

Grade AR

HSN Code 29032300

Molecular Formula C2Cl4

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Perchloroethylene

Catalogue No. AL3450

Product form Substance

CAS Number 127-18-4

EC Number 204-825-9

Grade AR

EC Index Number 602-004-00-3

Chemical Formula C2Cl4

HSN Code 29032300

Synonyms Tetrachloroethylene, PERC

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Solvent in analytical chemistry and degreasing agent.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Carc. 2; Aquatic Chronic 2

Classification source ECHA C&L Inventory via PubChem CID 31373 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Health Hazard, Environmental Hazard

Signal word Warning

Hazard statements H351: Suspected of causing cancer; H411: Toxic to aquatic life with long lasting effects

2.3 Other hazards

Other hazards Suspected carcinogen; may cause damage to organs through prolonged or repeated exposure.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Perchloroethylene

CAS No. 127-18-4

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If symptoms persist, seek medical attention.

First-aid measures after skin contact IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.

First-aid measures after eye contact First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.

First-aid measures after ingestion Do not induce vomiting. Rinse mouth and seek medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Headache, dizziness, nausea, respiratory irritation.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Vapors are heavier than air and will collect in low areas. Storage containers and parts of containers may rocket great distances, in many directions.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area. Ventilate and contain spill. Use appropriate protective equipment.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance and complete protective clothing. Ventilation. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Use in a fume hood. Wear appropriate personal protective equipment (PPE).

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Separated from metals, ignition sources and food and feedstuffs. See Chemical Dangers. Keep in the dark. Keep in a well-ventilated room. Dry. Cool.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Handle with gloves.

Eye protection Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless

Odour Ether-like odor

Odour threshold Not specified

pH value Not applicable

Relative evaporation rate (butylacetate=1) <1

Melting point -22.2 °C

Freezing point Not specified

Boiling point 121.2 °C

Flash point Not applicable

Auto-ignition temperature > 650 °C

Decomposition temperature Not specified

Flammability (solid, gas) Not flammable

Vapour pressure 18.5 mm Hg at 25 °C

Relative vapour density at 20°C 5.83 (Air = 1)

Density 1.6230 g/cu cm at 20 °C

Solubility In water, 206 mg/L at 25 °C

Log Pow 3.40

Viscosity, kinematic Not specified

Viscosity, dynamic 0.89 mPa·s at 20 °C

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits Not specified

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions, but may react with strong oxidizing agents.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on contact with hot surfaces or flames. This produces toxic and corrosive fumes of hydrogen chloride, phosgene and chlorine. Decomposes slowly on contact with moisture.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizers, alkali metals, and reactive metals.

10.6 Hazardous decomposition products

Hazardous decomposition products Hazardous decomposition products formed under fire conditions - Carbon oxides, hydrogen chloride gas.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 2400-13000 mg/kg bw; LD50 Rat oral 2629 mg/kg; LD50 Rat ip 4678 mg/kg

Skin corrosion/irritation Not classified (based on available data)

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity H351: Suspected of causing cancer

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) UN 1897

UN-No. (IMDG) UN 1897

UN-No. (IATA) UN 1897

UN-No. (ADN) UN 1897

UN-No. (RID) UN 1897

14.2 UN proper shipping name

Proper Shipping Name (ADR) Perchloroethylene

Proper Shipping Name (IMDG) Perchloroethylene

Proper Shipping Name (IATA) Perchloroethylene

Proper Shipping Name (ADN) Perchloroethylene

Proper Shipping Name (RID) Perchloroethylene

14.3 Transport hazard class(es)

Transport hazard class(es) 6.1

14.4 Packing group

Packing group (ADR) III

Packing group (IMDG) III

Packing group (IATA) III

Packing group (ADN) III

Packing group (RID) III

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.