Safety Data Sheet

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name Phenol

Product Form Substance

Catalogue No. AL3464

CAS Number 108-95-2

EC Number 203-632-7

EC Index Number 604-001-00-2

Grade AR grade

HSN Code 29071110

Molecular Formula C6H6O

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name Phenol

Catalogue No. AL3464

Product form Substance

CAS Number 108-95-2

EC Number 203-632-7

Grade AR grade

EC Index Number 604-001-00-2

Chemical Formula C6H6O

HSN Code 29071110

Synonyms Carbolic acid, Hydroxybenzene

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Used in laboratories for analytical purposes and in the synthesis of various chemical compounds.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Acute Tox. 3; Skin Corr. 1B; Muta. 2; STOT RE 2

Classification source ECHA C&L Inventory via PubChem CID 996 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Corrosive, Acute Toxic, Health Hazard

Signal word Danger

Hazard statements H301: Toxic if swallowed; H311: Toxic in contact with skin; H314: Causes severe skin burns and eye damage; H331: Toxic if inhaled; H341: Suspected of causing genetic defects; H373: May causes damage to organs through prolonged or repeated exposure

2.3 Other hazards

Other hazards Corrosive to skin and eyes; may cause respiratory irritation.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name Phenol

CAS No. 108-95-2

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If breathing is difficult, give oxygen. Seek medical attention.

First-aid measures after skin contact IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.

First-aid measures after eye contact First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.

First-aid measures after ingestion Do not induce vomiting. Rinse mouth. Seek medical attention immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Symptoms of exposure may include headache, dizziness, nausea, and skin irritation.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Water spray, carbon dioxide, dry chemical powder, foam.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Combustible material; may produce toxic fumes when burned.

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area and ventilate. Wear appropriate protective equipment. Contain spill and prevent entry into waterways.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Use only in a fume hood. Wear appropriate personal protective equipment (PPE) including gloves and goggles.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Provision to contain effluent from fire extinguishing. Separated from strong oxidants and food and feedstuffs. Dry. Well closed. Store only in original container. Keep in a well-ventilated room. Store in an area without drain or sewer access.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Protective gloves (e.g. nitrile rubber)

Eye protection Chemical safety goggles or safety glasses

Skin and body protection Wear suitable protective clothing

Respiratory protection Use a NIOSH-approved respirator if exposure limits are exceeded.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Solid

Colour White to pink

Odour Distinct aromatic, somewhat sickening sweet and acrid odor, discernable at 0.5 to 5 ppm

Odour threshold Not specified

pH value Not applicable

Relative evaporation rate (butylacetate=1) Not specified

Melting point 43 °C

Freezing point Not specified

Boiling point 182 °C at 760 mmHg

Flash point 79 °C

Auto-ignition temperature 1319 °F (715 °C)

Decomposition temperature Not specified

Flammability (solid, gas) Flammable solid

Vapour pressure 0.2 mmHg at 68 °F ; 0.35 mmHg at 77 °F

Relative vapour density at 20°C 3.24 (Air= 1)

Density 1.04 at 105.8 °F - Denser than water; will sink

Solubility 50 to 100 mg/mL at 66 °F

Log Pow Log Kow = 1.46

Viscosity, kinematic Not specified

Viscosity, dynamic Not specified

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits Not specified

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Reacts with strong oxidizing agents and bases.

10.2 Chemical stability

Chemical stability Prone to redden on exposure to air and light, hastened by presence of alkalinity.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions The solution in water is a weak acid. Reacts with oxidants. This generates fire and explosion hazard.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizers, strong acids, and bases.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomposition it emits acrid smoke and irritating fumes.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Rat oral 530 mg/kg; LD50 Cat oral 0.1 g/kg; LD50 Dog oral 0.5 g/kg

Skin corrosion/irritation H314: Causes severe skin burns and eye damage

Serious eye damage/irritation Not classified (based on available data)

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity H341: Suspected of causing genetic defects

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) H373: May causes damage to organs through prolonged or repeated exposure

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) 1671

UN-No. (IMDG) 1671

UN-No. (IATA) 1671

UN-No. (ADN) 1671

UN-No. (RID) 1671

14.2 UN proper shipping name

Proper Shipping Name (ADR) Phenol

Proper Shipping Name (IMDG) Phenol

Proper Shipping Name (IATA) Phenol

Proper Shipping Name (ADN) Phenol

Proper Shipping Name (RID) Phenol

14.3 Transport hazard class(es)

Transport hazard class(es) 6.1

14.4 Packing group

Packing group (ADR) II

Packing group (IMDG) II

Packing group (IATA) II

Packing group (ADN) II

Packing group (RID) II

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.