Phenylhydrazine
Synonyms: Hydrazine, phenyl-; Phenylhydrazine hydrochloride
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Phenylhydrazine
Product Form
Substance
Catalogue No.
AL3507
CAS Number
100-63-0
EC Number
202-873-5
EC Index Number
611-059-00-0
Grade
97% For Synthesis
HSN Code
29280090
Molecular Formula
C6H8N2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Phenylhydrazine
Catalogue No.
AL3507
Product form
Substance
CAS Number
100-63-0
EC Number
202-873-5
Grade
97% For Synthesis
EC Index Number
611-059-00-0
Chemical Formula
C6H8N2
HSN Code
29280090
Synonyms
Hydrazine, phenyl-; Phenylhydrazine hydrochloride
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used in organic synthesis and as a reagent for the identification of carbonyl compounds.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute Tox. 3; Skin Irrit. 2; Skin Sens. 1; Eye Irrit. 2; Muta. 2; Carc. 1B; STOT RE 1; Aquatic Acute 1
Classification source
ECHA C&L Inventory via PubChem CID 7516 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Acute Toxic, Health Hazard, Environmental Hazard
Signal word
Danger
Hazard statements
H301: Toxic if swallowed; H311: Toxic in contact with skin; H315: Causes skin irritation; H317: May cause an allergic skin reaction; H319: Causes serious eye irritation; H331: Toxic if inhaled; H341: Suspected of causing genetic defects; H350: May cause cancer; H372: Causes damage to organs through prolonged or repeated exposure; H400: Very toxic to aquatic life
Precautionary statements
P203, P260, P261, P262, P264, P264+P265, P270, P271, P272, P273, P280, P301+P316, P302+P352, P304+P340, P305+P351+P338, P316, P318, P319, P321, P330, P332+P317, P333+P317, P337+P317, P361+P364, P362+P364, P391, P403+P233, P405, P501
2.3 Other hazards
Other hazards
Suspected carcinogen; may cause reproductive toxicity.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Phenylhydrazine
CAS No.
100-63-0
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
If this chemical has been inhaled, remove the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. Keep the person warm and at rest.
First-aid measures after skin contact
If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.
First-aid measures after eye contact
If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
First-aid measures after ingestion
If this chemical has been swallowed, get medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Headache, dizziness, nausea, skin irritation, respiratory distress.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Toxic fumes may be released in a fire. Use water spray to cool containers.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area. Wear appropriate protective equipment. Contain spill and prevent entry into waterways.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Evacuate danger area! Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. If liquid: collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Use only in a fume hood. Wear appropriate personal protective equipment (PPE). Avoid contact with skin and eyes.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Separated from strong oxidants and food and feedstuffs. Store in an area without drain or sewer access.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use a NIOSH-approved respirator if exposure limits are exceeded.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Liquid
Colour
Pale yellow to red-brown
Odour
Faint, aromatic odor.
Odour threshold
No data available
pH value
No data available
Relative evaporation rate (butylacetate=1)
No data available
Melting point
19.5 °C
Freezing point
No data available
Boiling point
243.5 °C, decomp (760 mm Hg); 173.5 °C at 100 mm Hg; 148.2 °C at 40 mm Hg;
Flash point
190 °F, 88 °C (closed cup)
Auto-ignition temperature
345 °F (173 °C)
Decomposition temperature
No data available
Flammability (solid, gas)
Flammable liquid
Vapour pressure
0.026 mm Hg at 25 °C
Relative vapour density at 20°C
3.7 (air= 1)
Density
1.0978 at 20 °C/4 °C
Solubility
Sparingly sol petroleum ether, sol in dil acids. Miscible in alcohol, ether, chloroform, and benzene
Log Pow
log Kow= 1.25
Viscosity, kinematic
No data available
Viscosity, dynamic
No data available
Explosive properties
No data available
Oxidising properties
No data available
Explosive limits
No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Reacts violently with strong oxidizers and acids.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Decomposes on burning. This produces toxic fumes including nitrogen oxides. Reacts with strong oxidants.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizing agents, strong acids, and bases.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomposition it emits highly toxic fumes of nitrogen oxides.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat oral 188 mg/kg; LD50 Mouse oral 175 mg/kg; LD50 Rabbit oral 80 mg/kg
Skin corrosion/irritation
H315: Causes skin irritation
Serious eye damage/irritation
H319: Causes serious eye irritation
Respiratory or skin sensitisation
H317: May cause an allergic skin reaction
Germ cell mutagenicity
H341: Suspected of causing genetic defects
Carcinogenicity
H350: May cause cancer
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
H372: Causes damage to organs through prolonged or repeated exposure
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
UN 2572
UN-No. (IMDG)
UN 2572
UN-No. (IATA)
UN 2572
UN-No. (ADN)
UN 2572
UN-No. (RID)
UN 2572
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Phenylhydrazine
Proper Shipping Name (IMDG)
Phenylhydrazine
Proper Shipping Name (IATA)
Phenylhydrazine
Proper Shipping Name (ADN)
Phenylhydrazine
Proper Shipping Name (RID)
Phenylhydrazine
14.3 Transport hazard class(es)
Transport hazard class(es)
6.1
14.4 Packing group
Packing group (ADR)
II
Packing group (IMDG)
II
Packing group (IATA)
II
Packing group (ADN)
II
Packing group (RID)
II
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.