Red Phosphorus
Synonyms: Phosphorus (red), Phosphorus allotrope
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Red Phosphorus
Product Form
Substance
Catalogue No.
AL3545
CAS Number
7723-14-0
EC Number
231-768-7
EC Index Number
015-001-00-2
Grade
97%
HSN Code
28047020
Molecular Formula
P
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Red Phosphorus
Catalogue No.
AL3545
Product form
Substance
CAS Number
7723-14-0
EC Number
231-768-7
Grade
97%
EC Index Number
015-001-00-2
Chemical Formula
P
HSN Code
28047020
Synonyms
Phosphorus (red), Phosphorus allotrope
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Used in organic synthesis and match manufacturing.
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flam. Sol. 2; Aquatic Chronic 3
Classification source
ECHA C&L Inventory via PubChem CID 5462309 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Flammable
Signal word
Danger
Hazard statements
H228: Flammable solid; H412: Harmful to aquatic life with long lasting effects
2.3 Other hazards
Other hazards
May ignite spontaneously in air.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Red Phosphorus
CAS No.
7723-14-0
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If breathing is difficult, give oxygen and seek medical attention.
First-aid measures after skin contact
Wash with soap and water. Seek medical attention if irritation persists.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Irritation of eyes, skin, and respiratory tract; potential for burns.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
White phosphorus may be present as a contaminant or formed in fire situations. Fumes from phosphorus fires are highly irritating to lungs, skin, eyes.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and eliminate ignition sources. Use appropriate protective equipment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Collect and dispose of in accordance with local regulations; avoid water contact.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Avoid contact with skin and eyes; use in a well-ventilated area.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Separate from air, oxidizing materials, combustibles. Always keep container closed, with material under water or inert gas.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if dust is generated.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Solid
Colour
Dark red to violet
Odour
Garlic-like
Odour threshold
Not applicable
pH value
Not applicable
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
44.1 °C
Freezing point
Not applicable
Boiling point
280 °C
Flash point
Not applicable
Auto-ignition temperature
Red: 260 °C; White: 30 °C
Decomposition temperature
Not applicable
Flammability (solid, gas)
Flammable solid
Vapour pressure
0.026 mm Hg at 20 °C
Relative vapour density at 20°C
Red: 4.77; White: 4.42 (Air = 1)
Density
1.83 (alpha-form); 1.88 (beta form)
Solubility
Insoluble in water; soluble in carbon disulfide and other organic solvents
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive under normal conditions
Oxidising properties
Not oxidizing
Explosive limits
Not applicable
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions; reacts with strong oxidizers.
10.2 Chemical stability
Chemical stability
Black: Stable in air.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
- Phosphorus spontaneously ignites on contact with air, producing toxic fumes (phosphorus oxides). ; - Phosphorus reacts violently with oxidants, halogens, some metals, nitrites, sulfur, and many other compounds. This causes a fire and explosion hazard. ; - Phosphorus reacts with strong bases to produce toxic phosphine gas.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong oxidizers, halogens, and acids.
10.6 Hazardous decomposition products
Hazardous decomposition products
When heated to decomp emits toxic fumes of phosphorus oxides.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Rat (Charles-River, female) oral 3.03 mg/kg; LD50 Rat (Charles-River, male) oral 3.76 mg/kg; LD50 Mouse (Swiss, female) oral 4.82 mg/kg
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
Not classified (based on available data)
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
1338
UN-No. (IMDG)
1338
UN-No. (IATA)
1338
UN-No. (ADN)
1338
UN-No. (RID)
1338
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Red Phosphorus
Proper Shipping Name (IMDG)
Red Phosphorus
Proper Shipping Name (IATA)
Red Phosphorus
Proper Shipping Name (ADN)
Red Phosphorus
Proper Shipping Name (RID)
Red Phosphorus
14.3 Transport hazard class(es)
Transport hazard class(es)
4.1
14.4 Packing group
Packing group (ADR)
III
Packing group (IMDG)
III
Packing group (IATA)
III
Packing group (ADN)
III
Packing group (RID)
III
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.