Safety Data Sheet - 3-Picoline

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Chemical Name 3-Picoline

Product Form Substance

Catalogue No. AL3565

CAS Number 108-99-6

EC Number 203-636-9

EC Index Number -

Grade 98%

HSN Code 29333916

Molecular Formula C6H7N

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Chemical Name 3-Picoline

Catalogue No. AL3565

Product form Substance

CAS Number 108-99-6

EC Number 203-636-9

Grade 98%

EC Index Number Not specified

Chemical Formula C6H7N

HSN Code 29333916

Synonyms beta-Picoline, 3-Methylpyridine

Chemical Structure -

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture Synthetic intermediate in the production of nicotinic acid and nicotinamide.

Uses advised against Not specified

1.3 Details of the supplier of the safety data sheet

Company identification Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.

1.4 Emergency Contact Details

Phone / e-Mail Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Flam. Liq. 3; Acute Tox. 4; Acute Tox. 3; Skin Corr. 1B; Eye Dam. 1

Classification source ECHA C&L Inventory via PubChem CID 7970 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements

2.2 Label elements

Hazard pictograms Flammable, Corrosive, Acute Toxic

Signal word Danger

Hazard statements H226: Flammable liquid and vapor; H302: Harmful if swallowed; H311+H331: Toxic in contact with skin or if inhaled.; H311: Toxic in contact with skin; H314: Causes severe skin burns and eye damage; H318: Causes serious eye damage; H331: Toxic if inhaled

2.3 Other hazards

Other hazards Flammable liquid and vapor.

SECTION 3: Composition/information on ingredients

3.1 Substance

Name 3-Picoline

CAS No. 108-99-6

SECTION 4: First aid measures

4.1 Description of first aid measures

First-aid measures after inhalation Move to fresh air. If breathing is difficult, give oxygen and seek medical attention.

First-aid measures after skin contact IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water.

First-aid measures after eye contact First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.

First-aid measures after ingestion Do not induce vomiting. Rinse mouth and seek medical attention.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms relating to use Headache, dizziness, nausea, and irritation of the respiratory tract.

4.3 Indication of any immediate medical attention and special treatment needed

General information Treat symptomatically. Show this safety data sheet to the treating physician.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media Not specified

5.2 Special hazards arising from the substance or mixture

Special procedures Special hazards arising from the substance or mixture: Carbon oxides, nitrogen oxides (NOx).

5.3 Advice for firefighters

Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1.1 For non-emergency personnel

Emergency procedures Evacuate area. Remove sources of ignition. Contain spill and prevent entry into waterways.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up Personal protection: chemical protection suit including self-contained breathing apparatus. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

6.4 Reference to other sections

Reference Not specified

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Precautions for safe handling Avoid contact with skin and eyes. Use in a well-ventilated area. Keep away from heat and ignition sources.

Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions Fireproof. Separated from strong oxidants.

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Hand protection Handle with gloves.

Eye protection Tightly fitting safety goggles. Faceshield (8-inch minimum).

Skin and body protection Wear suitable protective clothing

Respiratory protection Use appropriate respiratory protection if ventilation is inadequate.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state Liquid

Colour Colorless to pale yellow

Odour Sweetish, not unpleasant odor

Odour threshold Not specified

pH value Not specified

Relative evaporation rate (butylacetate=1) Not specified

Melting point -18.1 °C

Freezing point Not specified

Boiling point 144.1 °C

Flash point 37 °C (99 °F) (Closed cup)

Auto-ignition temperature 488 °C (910 °F) at 1,009 hPa (757 mmHg)

Decomposition temperature Not specified

Flammability (solid, gas) Flammable liquid

Vapour pressure 6.05 mm Hg at 25 °C

Relative vapour density at 20°C Relative vapor density (air = 1): 3.2

Density 0.9566 at 20 °C/4 °C

Solubility Miscible with water at 20 °C

Log Pow 1.20

Viscosity, kinematic Not specified

Viscosity, dynamic Not specified

Explosive properties Not explosive

Oxidising properties Not oxidizing

Explosive limits 1.2 - 7.5% (v/v) in air

SECTION 10: Stability and reactivity

10.1 Reactivity

Reactivity Stable under normal conditions. Reacts with strong oxidizing agents.

10.2 Chemical stability

Chemical stability Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Possibility of hazardous reactions Decomposes on burning. This produces toxic fumes including nitrogen oxides. Reacts with oxidants.

10.4 Conditions to avoid

Conditions to avoid Avoid contact with incompatible materials and excessive heat.

10.5 Incompatible materials

Incompatible materials Strong oxidizing agents, strong acids.

10.6 Hazardous decomposition products

Hazardous decomposition products When heated to decomposition it emits toxic fumes of nitrogen oxides.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity LD50 Mouse iv >596 mg/kg; LD50 Rat i.p. 150 mg/kg

Skin corrosion/irritation H314: Causes severe skin burns and eye damage

Serious eye damage/irritation H318: Causes serious eye damage

Respiratory or skin sensitisation Not classified (based on available data)

Germ cell mutagenicity Not classified (based on available data)

Carcinogenicity Not classified (based on available data)

Specific target organ toxicity (single exposure) Not classified (based on available data)

Specific target organ toxicity (repeated exposure) Not classified (based on available data)

SECTION 12: Ecological information

12.1 Toxicity

Toxicity information Not specified

12.2 Persistence - degradability

Persistence - degradability Not specified

12.3 Bioaccumulative potential

Bioaccumulative potential Not specified

12.4 Mobility in soil

Mobility in soil Not specified

12.6 Other adverse effects

Environmental precautions Not specified

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Additional Info Dispose of contents/container in accordance with local, regional, national and international regulations.

SECTION 14: Transport information

14.1 UN number

UN-No. (ADR) 2313

UN-No. (IMDG) 2313

UN-No. (IATA) 2313

UN-No. (ADN) 2313

UN-No. (RID) 2313

14.2 UN proper shipping name

Proper Shipping Name (ADR) 3-Picoline

Proper Shipping Name (IMDG) 3-Picoline

Proper Shipping Name (IATA) 3-Picoline

Proper Shipping Name (ADN) 3-Picoline

Proper Shipping Name (RID) 3-Picoline

14.3 Transport hazard class(es)

Transport hazard class(es) 3

14.4 Packing group

Packing group (ADR) III

Packing group (IMDG) III

Packing group (IATA) III

Packing group (ADN) III

Packing group (RID) III

14.5 Environmental hazards

Dangerous for the environment Not specified

Marine pollutant Not specified

Other information No supplementary information available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1 EU-Regulations Not specified

SECTION 16: Other Information

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.