Potassium Ferricyanide
Synonyms: Red Prussiate of Potash, Ferricyanide of Potassium
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chemical Name
Potassium Ferricyanide
Product Form
Substance
Catalogue No.
AL3694
CAS Number
13746-66-2
EC Number
237-323-3
EC Index Number
615-005-00-9
Grade
AR
HSN Code
28372020
Molecular Formula
K3Fe(CN)6
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name
Potassium Ferricyanide
Catalogue No.
AL3694
Product form
Substance
CAS Number
13746-66-2
EC Number
237-323-3
Grade
AR
EC Index Number
615-005-00-9
Chemical Formula
K3Fe(CN)6
HSN Code
28372020
Synonyms
Red Prussiate of Potash, Ferricyanide of Potassium
Chemical Structure
-
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Analytical reagent, oxidizing agent, colorimetric reagent
Uses advised against
Not specified
1.3 Details of the supplier of the safety data sheet
Company identification
Address:- 102, B wing, Savgan Heights, RTO Lane,Andheri (W), Mumbai-400 053Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail
Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Eye Irrit. 2
Classification source
ECHA C&L Inventory via PubChem CID 26250 - hazard classes notified by at least 50% of companies; pictograms and signal word derived from those statements
2.2 Label elements
Hazard pictograms
Irritant
Signal word
Warning
Hazard statements
H319: Causes serious eye irritation
2.3 Other hazards
Other hazards
Releases toxic hydrogen cyanide (HCN) when heated or acidified.
SECTION 3: Composition/information on ingredients
3.1 Substance
Name
Potassium Ferricyanide
CAS No.
13746-66-2
SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation
Move to fresh air. If symptoms persist, seek medical attention.
First-aid measures after skin contact
Wash with soap and water. If irritation occurs, seek medical attention.
First-aid measures after eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. If irritation persists, seek medical attention.
First-aid measures after ingestion
Do not induce vomiting. Rinse mouth and seek medical attention immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use
Symptoms of exposure may include headache, dizziness, nausea, and respiratory distress.
4.3 Indication of any immediate medical attention and special treatment needed
General information
Treat symptomatically. Show this safety data sheet to the treating physician.
SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray, carbon dioxide, dry chemical powder, foam.
Unsuitable extinguishing media
Not specified
5.2 Special hazards arising from the substance or mixture
Special procedures
Non-flammable, but may release toxic fumes in a fire.
5.3 Advice for firefighters
Protection during firefighting
Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1.1 For non-emergency personnel
Emergency procedures
Evacuate area and ventilate. Wear appropriate protective equipment. Contain and collect spillage.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
Personal protection: P2 filter respirator for harmful particles. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting.
6.4 Reference to other sections
Reference
Not specified
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling
Avoid contact with skin and eyes. Use personal protective equipment as required.
Hygiene measures
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Separated from acids. Dry.
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Hand protection
Protective gloves (e.g. nitrile rubber)
Eye protection
Chemical safety goggles or safety glasses
Skin and body protection
Wear suitable protective clothing
Respiratory protection
Use appropriate respiratory protection if ventilation is inadequate.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state
Solid
Colour
Bright red
Odour
Odourless
Odour threshold
Not applicable
pH value
5.0 (1% solution)
Relative evaporation rate (butylacetate=1)
Not applicable
Melting point
60 °C
Freezing point
Not applicable
Boiling point
Decomposes before boiling
Flash point
Not applicable
Auto-ignition temperature
Not applicable
Decomposition temperature
Above 60 °C
Flammability (solid, gas)
Non-flammable
Vapour pressure
Not applicable
Relative vapour density at 20°C
Not applicable
Density
1.89 g/cm³
Solubility
Solubility in water, g/100ml: 46
Log Pow
Not applicable
Viscosity, kinematic
Not applicable
Viscosity, dynamic
Not applicable
Explosive properties
Not explosive
Oxidising properties
Oxidizing agent
Explosive limits
Not applicable
SECTION 10: Stability and reactivity
10.1 Reactivity
Reactivity
Stable under normal conditions, but can react with strong acids to release toxic gases.
10.2 Chemical stability
Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Possibility of hazardous reactions
Decomposes on heating. This produces toxic gases including hydrogen cyanide. Reacts with acids.
10.4 Conditions to avoid
Conditions to avoid
Avoid contact with incompatible materials and excessive heat.
10.5 Incompatible materials
Incompatible materials
Strong acids, strong oxidizers.
10.6 Hazardous decomposition products
Hazardous decomposition products
Not specified
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 (oral, rat) > 2000 mg/kg.
Skin corrosion/irritation
Not classified (based on available data)
Serious eye damage/irritation
H319: Causes serious eye irritation
Respiratory or skin sensitisation
Not classified (based on available data)
Germ cell mutagenicity
Not classified (based on available data)
Carcinogenicity
Not classified (based on available data)
Specific target organ toxicity (single exposure)
Not classified (based on available data)
Specific target organ toxicity (repeated exposure)
Not classified (based on available data)
SECTION 12: Ecological information
12.1 Toxicity
Toxicity information
Not specified
12.2 Persistence - degradability
Persistence - degradability
Not specified
12.3 Bioaccumulative potential
Bioaccumulative potential
Not specified
12.4 Mobility in soil
Mobility in soil
Not specified
12.6 Other adverse effects
Environmental precautions
Not specified
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Additional Info
Dispose of contents/container in accordance with local, regional, national and international regulations.
SECTION 14: Transport information
14.1 UN number
UN-No. (ADR)
3077
UN-No. (IMDG)
3077
UN-No. (IATA)
3077
UN-No. (ADN)
3077
UN-No. (RID)
3077
14.2 UN proper shipping name
Proper Shipping Name (ADR)
Environmentally hazardous substance, solid, n.o.s. (Potassium Ferricyanide)
Proper Shipping Name (IMDG)
Environmentally hazardous substance, solid, n.o.s. (Potassium Ferricyanide)
Proper Shipping Name (IATA)
Environmentally hazardous substance, solid, n.o.s. (Potassium Ferricyanide)
Proper Shipping Name (ADN)
Environmentally hazardous substance, solid, n.o.s. (Potassium Ferricyanide)
Proper Shipping Name (RID)
Environmentally hazardous substance, solid, n.o.s. (Potassium Ferricyanide)
14.3 Transport hazard class(es)
Transport hazard class(es)
9
14.4 Packing group
Packing group (ADR)
III
Packing group (IMDG)
III
Packing group (IATA)
III
Packing group (ADN)
III
Packing group (RID)
III
14.5 Environmental hazards
Dangerous for the environment
Not specified
Marine pollutant
Not specified
Other information
No supplementary information available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations
Not specified
SECTION 16: Other Information
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a guarantee or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.